23 February 2026, Volume 39 Issue 1
    

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  • ZHU Sheng, WANG Xiaoming, HAN Guofeng, DU Wenbo, ZHAO Yang
    China Surface Engineering. 2026, 39(1): 2-8. https://doi.org/10.11933/CSE2026001
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    Mobile additive repair and remanufacturing in complex on-site environments face three overarching challenges: the multi-constrained nature of operational conditions and repair targets, discrete and highly variable quality domains of service-degraded materials, and demand for precise control and reliable assessment of repair quality in dynamically changing field scenarios. To address these challenges, this review examines the connotations, technical characteristics, and intrinsic difficulties associated with mobile additive repair and remanufacturing, with particular emphasis on the unique requirements of on-site operations. Drawing on recent developments and practical application cases, this article outlines the system composition, core modules, and functional architecture of mobile additive repair systems, including mobile deployment platforms, digital modeling and reconstruction tools, adaptive material-process subsystems, and multidimensional sensing and evaluation frameworks. By analyzing advances in design, materials, processes, and equipment, this review highlights the emergence of integrated mobile systems capable of operating in constrained spaces, interacting with heterogeneous surface states, and maintaining deposition stability under fluctuating environmental conditions. This study further analyses the main research directions and representative technical routes that shape the development of mobile additive repair technologies. These include environment-aware process planning strategies that consider geometric limitations, thermal boundary shifts, and accessibility constraints; material adaptation methodologies designed to accommodate substrate degradation, oxidation, or microstructural heterogeneity; and intelligent thermal and shielding control approaches that stabilize melt-pool behavior and improve layer quality in open or partially confined environments. Substantial progress has also been made in real-time monitoring and multiscale quality evaluation, where optical, infrared, acoustic, and laser-based sensing are increasingly combined to track dilution, defect initiation, interfacial bonding, and microstructure evolution during deposition. Based on these developments, this review identifies several key enabling technologies that enable reliable onsite additive repair of components located in special environments or within large-scale equipment that cannot be disassembled. Representative advances include portable and modular mobile repair platforms with enhanced environmental adaptability, digital twin-assisted repair workflow designs that link defect characterization with predictive simulation, and adaptive process control frameworks responsive to real-time disturbances. These innovations collectively form a new technical system that unifies design methodologies, material strategies, process optimization, equipment engineering, and closed-loop quality assurance. Across multiple industrial case studies, such integrated technical systems have demonstrated strong potential for delivering high-quality and efficient on-site repair of damaged components, ranging from turbine casings and reactor vessels to heavy machinery parts and aerospace structures. Commonly reported improvements include enhanced deposition uniformity in restricted or variable environments, stronger metallurgical bonding to service-degraded substrates, reduced incidence of common defects such as porosity or microcracks, and more predictable dimensional restoration with lower post-processing requirements. By consolidating these advances and mapping their interconnections, this review provides a coherent perspective on the evolution of mobile additive repair and remanufacturing technologies. Simultaneously, it identifies persistent scientific and engineering challenges—such as robust material-process matching for severely degraded substrates, more reliable prediction of repaired-component lifecycle performance, and further miniaturization and intelligent control of mobile platforms—that are likely to drive future research. Overall, this review summarizes the progress in establishing a new generation of mobile additive repair systems capable of providing high-quality, efficient, and reliable on-site restoration of critical components for the energy and chemical industries, heavy-duty equipment, and aerospace applications, and outlines the technological foundations required for continued advancement in this rapidly developing field.
  • WANG Huipeng, LI Weisheng, KONG Pengfei, DONG Lihong, LI Kaixuan, LIU Huizhong
    China Surface Engineering. 2026, 39(1): 9-22. https://doi.org/10.11933/CSE2026002
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    Remanufacturing has emerged as a critical strategy for resource recycling and promoting sustainable industrial production. In this context, microcrack detection in remanufactured blanks constitutes an essential aspect of quality control throughout the remanufacturing process, directly influencing the integrity, reliability, and service life of recycled components. This paper presents a systematic review of recent advances in active infrared thermography (IRT) as a nondestructive testing method for microcrack detection in remanufactured blanks. The fundamental principles of active IRT are introduced, emphasizing its capability for rapid, full-field, and noncontact inspection. The paper also provides a detailed analysis of the three predominant excitation mechanisms, namely eddy current, ultrasonic, and laser-based approaches, highlighting their respective physical principles, advantages, and limitations in the context of remanufacturing. Eddy current thermography is particularly effective for conductive materials, enabling high-speed scanning and surface crack detection; ultrasonic thermography excels in detecting subsurface defects through vibrothermal effects; and laser-based thermography offers superior resolution for precise characterization of fine surface cracks. In addition to excitation mechanisms, this review thoroughly examines advanced signal-processing techniques that are essential for enhancing defect visibility and interpretation. These include conventional image processing methods (e.g., Fourier transform and pulsed-phase thermography), data decomposition and dimensionality reduction approaches (such as principal component analysis and tensor decomposition), and emerging deep-learning-enabled intelligent recognition algorithms that improve automated flaw identification and classification. The performance of these techniques is discussed in terms of signal-to-noise ratio enhancement, defect contrast improvement, and computational efficiency. A comprehensive summary of applications and performance evaluations demonstrates the effectiveness of active IRT across various case studies involving remanufactured components. This paper further addresses persistent challenges that limit wider industrial adoption, including limited detection accuracy for microscale cracks, poor adaptability to complex and curved surfaces, susceptibility to environmental interference, and difficulties in achieving reliable quantitative characterization of crack dimensions and morphology. Several future research directions are proposed to address these challenges. Emphasis is placed on the development of intelligent signal processing frameworks that integrate real-time deep learning, multisensor data fusion, and adaptive noise suppression. The design of high-efficiency excitation sources aimed at improving the thermal contrast while reducing energy consumption is also discussed. Other promising research avenues include multiphysics coupling methodologies that combine thermal, ultrasonic, and electromagnetic stimulations for enhanced defect detectability, as well as digital-twin integration for virtual-physical system interoperability and predictive maintenance. Finally, the development of portable, cost-effective, and robust inspection systems tailored for in-situ remanufacturing environments is highlighted as a critical step toward field deployment. The results of this review demonstrate that active IRT offers considerable advantages and holds promise for accurate and efficient microcrack assessment in remanufactured components. With continued innovation and system integration, active infrared thermography is expected to provide robust technical support for quality enhancement and sustainable transformation in the remanufacturing industry.
  • LIN Jianjun, XIE Yiming, SUN Zhe, LIU Yuxin, LÜ Yaohui
    China Surface Engineering. 2026, 39(1): 23-31. https://doi.org/10.11933/CSE2026003
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    Additive remanufacturing technology can be applied to directly form titanium alloy components. However, the mechanical properties of the as - deposited remanufactured components are either inferior to or only comparable to those of cast parts. This technology struggles to meet the emergency demand for direct deposition and immediate use in additive remanufacturing. A method of using pulsed plasma arc additive remanufacturing is studied to repair the surface of titanium alloys. To investigate the influence of different pulse frequencies on the microstructure and properties of deposited layers with different thicknesses, deposition experiments were conducted using pulse frequencies ranging from 1 to 100 Hz at intervals of 10 Hz. Single - pass single - layer and single - pass multi - layer specimens were deposited, and their microstructures and mechanical properties were analyzed. The influence of different thicknesses of pulsed plasma arc surface deposits on the microstructure and mechanical properties of remanufactured titanium alloy components was studied. The research results indicate that the surface roughness and hardness of the titanium alloy deposited by pulsed plasma arc are related to the cooling rate during deposition. A higher microhardness corresponds to a greater cooling rate, and the change rule of larger surface roughness is consistent with a higher cooling rate during deposition and solidification. Additionally, the distribution of hardness values at the bottom and top in the deposition direction is that the microhardness of the martensite structure > the grain boundary > the Widmanstätten structure with basket - weave characteristics. It can be inferred that the disturbing effect of the arc and droplet transfer enhances the cooling gradient during the solidification process, thereby affecting the surface roughness and microhardness. The microstructure of titanium alloy parts fabricated through pulsed plasma arc deposition is characterized by a composite structure composed of acicular martensite and Widmanstätten structure. During the deposition process, the perturbation effect of pulse frequency on droplet transfer plays a crucial role in promoting grain refinement. This is clearly demonstrated by the equiaxed grain structure observed in the first deposited layer. Pulsed plasma arc deposition was employed to fabricate multi - layer components. Subsequently, electron backscatter diffraction (EBSD) was utilized for phase analysis. The research results show that in the multi-deposited layer structure, the proportion of the α phase is 99.9%, and the proportion of grain size ≤ 15 μm reaches 86%. It can be seen that under the multi - layer thermal cycle, the decomposition of the metastable martensite structure in the deposition layer promotes the precipitation of secondary nano - α phase, further improving the interface strength of the mechanical properties of the titanium alloy repaired by plasma arc additive remanufacturing. Comparing the specimens with the substrate interface and the deposited layers, the former has higher tensile properties than the latter, and the mechanical properties under the 70Hz process reach the forging level, which is the best. Moreover, when comparing titanium alloy parts deposited at different pulse frequencies, the tensile strength of the as - deposited parts from high to low is 70 Hz > 50 Hz > 90 Hz. The reason is that the thermal cycle input of the 70Hz pulsed plasma is most conducive to maximizing the disturbing effect on the droplet transfer, resulting in the largest cooling gradient in the deposition layer of the pulsed plasma arc - deposited titanium alloy. Furthermore, due to the promotion of secondary nano-α phase precipitation by multiple thermal cycles, the mechanical properties of the components processed under this regime have been further enhanced. The research on the pulse plasma arc additive remanufacturing method for titanium alloys can effectively improve the mechanical properties of the as-deposited state of components during online repair. This provides a theoretical and technical foundation for the repair of advanced equipment.
  • CHEN Zhijian, LIU Bin, WANG Xiaohe
    China Surface Engineering. 2026, 39(1): 32-40. https://doi.org/10.11933/CSE2026004
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    Nonlinear ultrasonic techniques exhibit exceptional sensitivity to microdefects and demonstrate unique advantages in defect assessment. However, the quantitative relationship between the size of defects and characteristic ultrasonic parameters has not been established, and the mechanisms of Rayleigh scattering and size response thresholds of microdefects have not been examined in detail through numerical simulations. In this study, a complicated 2D-FEM model was constructed to study the interaction between ultrasonic waves and corrosion damage in structures made of aluminum alloy. Focusing on the quantification of defect sizing, a longitudinal wave was simulated that propagated at 5 MHz through an aluminum plate containing defects with specified sizes. Two types of corrosion morphology were modeled, including a circular hole representing pitting corrosion and an ellipse simulating stress-corrosion cracking. The numerical scheme in the ABAQUS / Explicit solver included the properties of aluminum (density = 2 700 kg / m³, Young’s modulus = 70 GPa, Poisson’s ratio = 0.33), with a carefully divided mesh for both efficiency and accuracy (a 0.1 mm fine mesh was applied near the defect, while a 0.5mm coarse mesh was used in remote areas), which satisfied the necessary requirement of over 10 elements per calculated wavelength of 1.275 mm. Four-node plane stress (CPS4R) quadrilateral elements were also included to model stress waves while suppressing numerical instability using reduced integration and viscous hourglass control. Wave excitation was performed in a 10-cycle 5-MHz Hanning-windowed sinusoidal pulse at the excitation boundary of the models. Transient dynamic simulations captured the full-wavefield interaction with defects and assessed received signals at the opposite boundary. For holes with radii ranging from 0.1-3.0 mm, three different ultrasonic amplitude response regimes were observed. First, a low-sensitivity zone was identified below 0.6 mm in which amplitudes fluctuated minimally between 0.710 and 0.823. Second, a highly nonlinear transition phase between 0.6 and 1.1 mm was identified in which amplitudes rapidly escalated with a fitted slope approaching 3.0. Third, a saturation regime above 1.1 mm was identified in which growth diminished with a slope near 0.3 because of dominant scattering mechanisms. Fourier spectral analysis confirmed that these variations in amplitude occurred precisely at the 5-MHz frequency excitation. Elliptical cracks with a fixed minor axis 0.1 mm long and lengths along their major axes of 0.5-6.0 mm showed completely different amplitude-length correlations. In particular, they exhibited continuous parabolic amplitude growth with initial linear progression up to a crack length of 1.5 mm transitioning into sublinear growth with increasingly declining rates with greater crack lengths, which reflects changing energy scattering and mode conversion efficiencies based on increasing aspect ratios of the cracks. The von Mises stresses were visualized to provide insight into reflection and transmission phenomena at defect interfaces, and time-displacement histories were taken to illustrate signal attenuation. The key contribution of this work is that of establishing physics-based mathematical relationships between the dimensions of defects and normalized signal amplitudes. Piecewise modeling revealed a sensitivity limit with a 0.6-mm threshold as well as size predictability when amplitudes exceed baseline noise levels for round defects. The dimensions of the observed cracks were correlated to amplitudes, which yielded determination coefficients exceeding 0.95 and allowed accurate estimation of their lengths. These empirical equations overcome the qualitative limitations of conventional ultrasonic testing and enable metrological quantification of defects. The computational efficiencies gained from adaptive meshing allowed extensive parametric studies that would be infeasible to perform through physical experiments. This work provides three major achievements for assessing corrosion damage. First, geometry-specific ultrasonic scattering effects were decoupled via controlled numerical experiments. Second, quantifiable detection limits for incipient corrosion are defined to establish that pinholes below 0.6 mm require alternate nondestructive evaluation methods. Third, the obtained correlation between amplitude and the size of defects provides fundamental algorithms for automatically sizing defects in structural health monitoring systems. These findings are particularly pertinent for aerospace and marine applications in which aluminum alloys are widely adopted.
  • ZHENG Handong, WANG Luyao, LIU Bohai, LI Kai, ZHANG Qiang, CHEN Yi
    China Surface Engineering. 2026, 39(1): 41-49. https://doi.org/10.11933/CSE2026005
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    High-end equipment, such as aero-engines, gas turbines, and advanced CNC machine tools, plays a critical role in national defense and industrial sectors. These systems are characterized by their high technological complexity, long development cycles, diverse structural and functional requirements, and stringent service conditions. The development and iterative upgrading of such equipment are crucial for maintaining national strategic capabilities and require extensive interdisciplinary, inter-industry, and inter-regional collaboration. As a core aspect of full life-cycle management, remanufacturing high-end equipment offers significant economic and strategic benefits. It effectively reduces costs, extends service life, and facilitates generational equipment upgrades, capabilities essential for keeping pace with technological advancements and maintaining competitive advantage across industries. In this study, aero-engines are used as a representative case to analyze the value chain activities involved in high-end equipment remanufacturing. The research identifies several key challenges, including complex coupling between design and manufacturing interfaces, insufficient information sharing, and a disconnect between knowledge accumulated during remanufacturing and its integration into the development of new models. These issues hinder the effective functioning of the remanufacturing value chain and limit its potential in terms of cost reduction, technological advancement, and sustainability. To address these challenges, this study proposes a comprehensive value-chain framework for high-end equipment remanufacturing, organized across four dimensions: “value chain entities, value activities, full life cycle of development, key technology support”. This framework offers a systematic approach to organizing and optimizing collaboration among stakeholders, including design institutes, manufacturers, suppliers, users, research institutions, and remanufacturing enterprises, across different stages of the equipment life cycle, spanning from design and manufacturing to maintenance and remanufacturing. The framework is supported by four key technology pillars: data intelligence, process intelligence, platform intelligence, and agile intelligent systems engineering. Data intelligence ensures continuous data flow and accurate feedback throughout the equipment life cycle. Constructing a multimodal closed-loop data system enables the creation of a high-fidelity digital twin, thereby facilitating real-time decision-making and information sharing. Process intelligence enhances this process by enabling the reconstruction and dynamic optimization of business processes through cross-stage modeling and self-learning algorithms. This allows for the continuous improvement of processes throughout the life cycle of the equipment, moving beyond simple repair and towards a more comprehensive system optimization. Platform intelligence, supported by the Industrial Internet, optimizes multi-stakeholder collaboration by enabling role allocation, dynamic incentives, and seamless resource and data sharing. It provides a common platform for all participants to interact and share resources and data, ensuring efficient coordination and collaboration among manufacturers, suppliers, users, and research institutions. Agile intelligent systems engineering ensures that the system can dynamically adapt to evolving conditions through interdisciplinary simulation and iterative optimization, enabling rapid responses to unforeseen challenges and technological demands. Implementing this remanufacturing value chain framework reduces total life-cycle costs, extends equipment service life, and enables the restoration of equipment to better than new condition. It also facilitates generational upgrades of high-end equipment, thereby enhancing resilience and self-controllability across the industrial chain. The integration of artificial intelligence with high-end equipment remanufacturing is expected to drive the development of advanced, adaptive, and sustainable manufacturing systems. Despite these benefits, several challenges remain, including limitations in organizational incentive mechanisms, barriers to data interconnection and sharing, and insufficient model interoperability across different stages and sectors. Future research should focus on developing demonstrative cross-domain collaboration models, standardizing data-sharing protocols, and improving organizational structures to promote high-quality development in the high-end equipment remanufacturing industry. Addressing these challenges will help fully realize the potential of the proposed value chain framework and advance global manufacturing technology.
  • KANG Jiajie, MA Guozheng, ZHU Lina, DA Qiang, WANG Haidou
    China Surface Engineering. 2026, 39(1): 50-60. https://doi.org/10.11933/CSE2026006
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    Most of the current research on improving the long-term protection capability of key components of drilling tools under complex coupled working conditions, such as high load, high frequency and high wear, focuses on traditional alloy coatings. However, the significant high-entropy and cocktail effects of high-entropy alloy coatings have been less studied in the research on the use of high-entropy alloy coatings for surface protection of drilling tools. Therefore, this study uses the high velocity oxygen fuel (HVOF) spraying technology to prepare an AlCoCrFeNiB high-entropy alloy coating on a 40CrMnMoA alloy steel surface, which is commonly used material in drilling tools. Using scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS), the microstructure of the AlCoCrFeNiB high-entropy alloy coating and morphology and elemental distribution of the wear scratches under different loads and sliding frequencies are analyzed. The phase structure of the AlCoCrFeNiB high-entropy alloy coating is detected using X-ray diffraction, and the microhardness of the substrate material 40CrMnMoA alloy steel and AlCoCrFeNiB high-entropy alloy coating is measured using a Vickers microhardness tester. The nanohardness and elastic modulus of the substrate material 40CrMnMoA alloy steel and AlCoCrFeNiB high-entropy alloy coating are measured using a nanoindentation instrument. The friction and wear mechanisms of the AlCoCrFeNiB high-entropy alloy coating under different loads (5, 10, and 15 N) and sliding frequencies (2 Hz, 4 Hz, and 6 Hz) are studied using an Rtec multifunctional friction and wear testing machine. The wear volume and wear rate of the AlCoCrFeNiB high-entropy alloy coating are calculated based on the white light interference principle. The research results show that the interface between the high velocity oxygen fuel-sprayed AlCoCrFeNiB high-entropy alloy coating and substrate material 40CrMnMoA alloy steel is clear. The microstructure of the AlCoCrFeNiB high-entropy alloy coating is dense, and the phase structure mainly consists of body-centered cubic (BCC) and Cr2B phases. Compared with the microhardness of the substrate material 40CrMnMoA alloy steel (200.7 HV0.2), the microhardness of the AlCoCrFeNiB high-entropy alloy coating is 879.6 HV0.2, which is approximately 4.4 times higher. The nanohardness from the substrate material 40CrMnMoA alloy steel to the AlCoCrFeNiB high-entropy alloy coating is 12.65 GPa, which is approximately 2.2 times higher. The elastic modulus of the AlCoCrFeNiB high-entropy alloy coating is 231.2 GPa, which is approximately 1.5 times higher than that the substrate material 40CrMnMoA alloy steel. The H / E value increases from 0.038 66 for the substrate material 40CrMnMoA alloy steel to 0.054 71 for the AlCoCrFeNiB high-entropy alloy coating. H3 / E2 increases from 0.009 87 for the substrate material 40CrMnMoA alloy steel to 0.037 87 for the AlCoCrFeNiB high-entropy alloy coating. This indicates that the high-entropy alloy coating can significantly enhance the elastic deformation recovery ability and antiplastic deformation ability of the surface of the 40CrMnMoA substrate material. With the increase in the load and sliding frequency, the coefficient of friction and wear rate of the AlCoCrFeNiB high-entropy alloy coating gradually increase. When the load is 15 N, the coating friction and wear reaction are the most severe, and the wear rate is as high as 49.2×10-6 mm3·N-1·m-1. When the sliding frequency is 2 Hz, the coating friction and wear reaction are the least, and the wear rate is only 7.14×10-6 mm3·N-1·m-1. From the analysis and summary, it can be concluded that the wear mechanism of the AlCoCrFeNiB high-entropy alloy coating is mainly slight abrasive wear and slight adhesion wear at low frequencies (2 Hz and 4 Hz). As the sliding frequency and load increase, the wear reaction of the AlCoCrFeNiB high entropy alloy coating intensifies and the wear mechanism transforms into severe adhesive wear and severe oxidative wear. This has significant reference value for the surface protection of drilling tools and wide application of high-entropy alloy coatings.
  • SONG Mingyu, JING Zhiyuan, XU Zhigang, ZHANG Zhibin, YUAN Haichao, HU Zhenfeng, LIANG Xiubing
    China Surface Engineering. 2026, 39(1): 61-73. https://doi.org/10.11933/CSE2026007
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    The development of advanced wear-resistant coatings is of paramount importance for enhancing the service life and reliability of mechanical components in demanding aerospace and precision engineering applications. Transition metal alloys based on refractory elements like Ta (Group VB), Hf (Group IVB), and W (Group VIB) are promising candidates due to their inherent high strength and stability. However, their wear resistance is often intrinsically limited by the propensity for plastic deformation and adhesive wear associated with their body-centered cubic (BCC) crystal structure. Nitrogen doping is widely recognized as an effective strategy for performance enhancement, capable of forming interstitial solid solutions and hard nitride phases, which significantly improve hardness and resistance to wear. While the individual binary nitrides of Ta, Hf, and W are well-studied, the systematic investigation of their multi-principal element alloy nitride system, specifically Ta-Hf-W-N, remains largely unexplored. The relationship between nitrogen content, evolving microstructure, and the resulting tribological properties in this novel system is not yet established, presenting a significant knowledge gap.This study is designed to comprehensively address this gap by fabricating and characterizing a series of Ta-Hf-W (-N) films with precisely controlled nitrogen content. The primary objective is to elucidate the correlation between nitrogen doping, microstructural evolution, mechanical properties, and tribological performance. The Ta-Hf-W-N films are synthesized using a direct current magnetron sputtering system, with high-purity argon and nitrogen gases serving as the working and reactive atmospheres, respectively. A critical aspect of the experimental design involves the systematic gradient control of the nitrogen flow rate, specifically at values of RN = 0%, 10%, 20%, and 30%, to precisely tune the chemical composition and phase formation within the films. A multi-faceted characterization approach is employed to construct a complete picture of the structure-property relationships. The phase composition and crystal structure are determined by X-ray diffraction (XRD). The surface morphology, cross-sectional microstructure, and coating thickness are meticulously examined using scanning electron microscopy (SEM) and atomic force microscopy (AFM), the latter providing quantitative data on surface roughness. The mechanical properties, including nanohardness (H) and elastic modulus (E), are accurately measured using a nanoindentation tester. The tribological behavior, namely the coefficient of friction and wear rate, is evaluated under dry sliding conditions using a ball-on-disk tribometer. Subsequent wear track analysis is conducted using white light interferometry to determine wear volume and SEM to observe wear mechanisms and surface damage. The results demonstrate a non-monotonic dependence of the film properties on the nitrogen flow rate, revealing a distinct optimum. The film synthesized at RN = 20% exhibits the most superior combination of properties. It possesses the highest nanohardness of 36.2 GPa and elastic modulus of 357.2 GPa, attributable to a dense, fine-columnar microstructure and effective solid solution strengthening. Concurrently, this film achieves the lowest surface roughness (1.85 nm Ra), which is crucial for friction reduction. In tribological tests, this optimal film outperforms all others, showing a stable friction coefficient and a wear rate that is reduced by two-thirds compared to the un-doped Ta-Hf-W alloy film (RN = 0%). Analysis of its wear mechanism identifies a mild, self-renewing cycle of oxidative wear coupled with minimal abrasive grooving. In contrast, deviations from this optimal nitrogen content lead to performance degradation. An insufficient nitrogen flow (RN= 10%) results in a relatively softer film with a thicker amorphous base layer and less pronounced strengthening. Conversely, an excessive nitrogen flow (RN = 30%) induces microstructural coarsening, increased surface roughness, and a potential rise in brittleness, which collectively elevate the friction coefficient and accelerate material removal. The fundamental innovation of this work lies in the systematic gradient investigation that successfully establishes the intricate linkages between nitrogen content, the transition from amorphous-to-columnar growth morphology, and the resulting mechanical and tribological responses within the novel Ta-Hf-W-N system. It is conclusively demonstrated that precise control of nitrogen incorporation is the key to unlocking the high-performance potential of this material system. The findings provide robust theoretical guidance and a reliable technical pathway for developing next-generation, high-performance wear-resistant coatings for critical applications in spacecraft and other advanced engineering systems.
  • SONG Peisong, ZHANG Zhibin, SHAO Liliang, XUE Lin, LIANG Xiubing, CHENG Jiangbo
    China Surface Engineering. 2026, 39(1): 74-83. https://doi.org/10.11933/CSE2026008
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    Wear is one of the most common failure modes of engineering materials. The surface modification of key mechanical components operating under severe frictional conditions is an effective approach for enhancing the operational safety and service reliability of equipment. Owing to their high hardness and excellent wear resistance, high-entropy amorphous alloys (HEAAs) have been recognized as a new class of materials with broad application potential. However, most existing studies on HEAA coatings have primarily focused on composition design and performance characterization. However, systematic investigations on the influence of heat input on the wear resistance of plasma-sprayed HEAA coatings remain insufficient. Moreover, the mechanism by which the heat input alters the microstructure and mechanical properties of the coating, thus affecting its wear behavior, has not yet been fully elucidated. In this study, (FeCoCrNi)75B15Si10 HEAA coatings were prepared under different heat inputs using plasma spraying (PS), and the effects of heat input on the microstructure, mechanical properties, and wear resistance of the coatings were systematically studied. The HEAA coatings prepared using PS exhibited completely amorphous structures. The extremely rapid cooling rate combined with the high glass-forming ability (GFA) of the alloy system resulted in the transformation of the crystalline powder into a fully amorphous coating during the rapid solidification process of PS. The PS process imparts high kinetic energy to molten powder particles, enabling rapid cooling upon contact with the substrate surface and the formation of a strong mechanical bond. The high-speed impact of the heated particles on the substrate or deposited particles causes significant deformation, leading to the transformation of the particles from spherical to flattened shapes, forming a layered structure in the cross-sectional view. The hardness of the HEAA coatings increased with heat input. The hardness of the HEAA coatings prepared under low, medium, and high heat inputs were 6.8, 8.15, and 8.43 GPa, respectively, whereas the hardness of the EQ 70 steel substrate was 3.20 GPa. The mechanical properties of the materials were closely related to their microstructures. The HEAA coatings exhibited a higher hardness than the substrate owing to their reduced defects and dense structure. The hardnesses of the coatings prepared with medium and high heat inputs were significantly higher than those of the coatings prepared with low heat inputs. This was primarily owing to the more complete melting of the powder at a higher heat input, which resulted in a stronger bond between the molten particles and a higher coating density. Excessively high heat input led to the formation of trace oxides in the coating, further enhancing its hardness. The HEAA coating prepared under a medium heat input exhibited both high hardness and the highest elastic modulus, showing superior wear resistance and energy absorption properties. Under identical dry sliding conditions, the thermal input exerted a decisive influence on the microstructure of the coating, thereby governing its wear mechanism and performance. A low thermal input resulted in a porous structure, leading to failure dominated by brittle spallation. Moderate thermal input produced a dense microstructure, achieving a favorable balance between abrasive and oxidative wear, and thus exhibited the optimal wear resistance, with the lowest wear rate of 3.19×10-5 mm3·N-1·m-1. Although a high thermal input further enhanced the coating density, the formation of hard oxide phases intensified abrasive wear, thereby deteriorating the overall wear resistance. Further investigation into the effect of load on the tribological behavior of the C2 HEAA coating at a medium heat input revealed that the wear rate initially decreased and then increased with increasing load. The minimum wear rate of 4.53×10-5 mm3·N-1·m-1 was observed under an external load of 30 N, with the wear failure mechanisms being abrasive wear, oxidation wear, and slight brittle spallation. This study revealed the influence of heat input on the wear behavior of HEAA coatings, providing important insights for the design and optimization of high-performance wear-resistant coatings.
  • NIU Xiaoyan, LIU Mingze, NIU Binbin, MA Qingyan, WANG Yujiang
    China Surface Engineering. 2026, 39(1): 84-95. https://doi.org/10.11933/CSE2026009
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    The pulse duty cycle in high-power impulse magnetron sputtering (HiPIMS) serves as a pivotal process parameter that critically governs plasma characteristics and energetic particle flux, thereby exerting multiscale control over the coating microstructure and performance characteristics. This study systematically investigated the evolution of the mechanical and tribological properties of TiAlTaN coatings with pulse duty cycles. The coatings were fabricated using a hybrid deposition technique that combined direct-current magnetron sputtering (dcMS) and HiPIMS. The effects of pulse duty cycles on the microstructure, phase composition, mechanical properties, and tribological behavior of the coatings were comprehensively characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), nanoindentation, and tribological testing. All the deposited TiAlTaN coatings featured smooth, dense surfaces with minimal particulate defects. Microstructural analysis revealed a distinct trend in columnar grain growth as the pulse duty cycle varied. As the duty cycle increased from 1:10 to 1:2, the grains first refined and then coarsened. Optimal structural characteristics were achieved at a duty cycle of 1:6, with the highest density and smallest grain size (29.2 nm), which can be attributed to the enhanced ion bombardment effects at this intermediate duty cycle. However, when the duty cycle exceeded 1:6, the peak current density decreased, weakening the particle migration capability and causing gradual surface loosening. Notably, at a duty cycle of 1:2, the formation of particle clusters was reduced, leading to lower surface densification. Concurrently, the ionization efficiency of the target decreased, which diminished the kinetic energy and surface mobility of the deposited particles. According to the kinetic mechanisms of physical vapor deposition, restricted atomic migration promotes lateral grain growth to minimize the total surface energy, resulting in an increase in the grain size. Phase analysis indicated that the pulse duty cycle had no significant influence on the preferred orientation of the coatings. All the coatings exhibited primary diffraction peaks between the standard peaks of TiN, AlN, and TaN, with no peak splitting, confirming the formation of a solid solution phase dominated by the cubic B1 structure. They consistently displayed a strong (111) preferred orientation, corresponding to a diffraction angle of 2θ=36.9°. The highest diffraction peak intensity and most pronounced grain refinement were observed at a 1:6 duty cycle. TEM characterization further verified this preferred growth orientation and the formation of a homogeneous TiAlTaN solid solution with a uniform elemental distribution over the coating thickness. Mechanical testing showed that the coating prepared at a 1:6 duty cycle exhibited peak performance, including the maximum hardness (18.4 GPa) and optimal H / E(0.038) and H³ / E²(0.026 4) ratios, which indicate its superior elastic recovery and resistance to plastic deformation to those of the other coatings. These enhancements stem from the synergistic effects of grain refinement, solid solution strengthening, and optimized cross-sectional density. Tribological evaluation revealed corresponding improvements, with the 1:6 coating showing the smallest friction coefficient (0.69) and lowest wear rate. No delamination or spalling was observed during the testing, confirming excellent coating integrity. By contrast, the coatings deposited at lower duty cycles (1:10-1:8) exhibited increased surface oxidation, and during friction testing, the oxide layers underwent repeated spallation, exacerbating surface damage. Notably, the hybrid dcMS / HiPIMS process demonstrated significant practical advantages, achieving deposition rates 2-3 times higher than those of conventional HiPIMS while maintaining superior coating quality. Overall, a pulse duty cycle of 1:6 represents the optimal processing window for hybrid dcMS / HiPIMS deposition of high-performance TiAlTaN coatings. Under this condition, the synergistic “structure-property” relationship reaches its peak, significantly enhancing the potential of the coating for application in extreme service environments. This study elucidates the fine-tuning mechanism of the duty cycle in hybrid deposition, providing critical theoretical insights and practical guidance for the efficient and controllable fabrication of advanced protective coatings.
  • YANG Sitong, LIU Jinna, ZHANG Xinyi, SUN Youran, WANG Guogang, LI Weipeng, CUI Xiufang, JIN Guo
    China Surface Engineering. 2026, 39(1): 96-108. https://doi.org/10.11933/CSE2026010
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    Owing to their high hardness, high-temperature structural stability, and wear resistance, laser cladding of refractory medium-and high-entropy alloy coatings has become a new research hotspot in the surface strengthening and protection of aerospace components. However, the single body-centered cubic structure of refractory medium-and high-entropy alloy coatings results in relatively low toughness and high friction coefficients, which, to some extent, limit their application on the surfaces of friction pairs. Currently, to simultaneously enhance the strength and toughness of refractory medium-and high-entropy alloys, researchers are attempting to enhance the grain size or phase distribution of materials through the design of alloy composition and structure optimization. Among these, lattice distortion strengthening, which can enhance the mechanical properties of a material without altering its crystal structure, has received extensive attention in the design of alloy compositions. In this study, three elements, Ti, Nb, and Mo were selected and mixed in an equal molar ratio as the basic component. A TiNbMo-refractory medium-entropy alloy coating was fabricated using laser-cladding technology. Ti has a hexagonal close-packed structure with dense packing and fewer slip planes and is prone to cylindrical slip, which is beneficial for enhancing the tribological properties of the coating. Two refractory metal elements, Nb and Mo, can be used as solid solution-strengthening elements to enhance the mechanical properties. Furthermore, to further reduce the cracks and unmelted particles in the coating, ensure a uniform phase distribution, enhance the toughness of the coating, and improve the anti-friction effect, the coating was subjected to a remelting treatment under a half-melting power of 1 kW and a melting power of 2 kW. This study systematically investigated the phase composition and interface characteristics, as well as the biphasic formation mechanism of a TiNbMo medium-entropy alloy coating. The influencing laws of laser remelting power on the hardness of the coating, as well as the friction and wear properties at room temperature and 600℃ were also studied. The results show that laser-clad TiNbMo medium-entropy alloy coatings are mainly composed of a solid-solution phase with a body-centered cubic structure and a dendritic phase with a Laves phase structure. After the remelting treatment, as the remelting power increases, the Laves phase content in the TiNbMo medium entropy alloy coating increases, degree of lattice distortion increases, and grain size becomes significantly finer. Owing to the significant lattice distortion, solid solution strengthening occurs, and a high cooling rate increases the grain boundary density, leading to grain boundary strengthening. Consequently, the microhardness of the remelted TiNbMo medium-entropy alloy coatings increases. The hardness values of the non-remelted coatings, 1 kW-remelted coatings and 2 kW-remelted coatings were 835.10, 815.10 and 864.25 HV0.3, respectively, which were approximately 2.30 to 2.40 times that of the microhardness of the substrate surface (363.08 HV0.3). The frictional properties of the coating were tested at both room temperature and 600℃. At room temperature, as the remelting power increased, the average friction coefficient of the coating decreased. The friction coefficient of the coating after 2 kW-remelting treatment was 0.45, which is 26% lower than that of the untreated coating. After remelting, the wear mechanism of the coating was mainly abrasive wear, accompanied by slight adhesive wear. At 600℃, the friction coefficient of the coating after 2 kW-remelting treatment was 0.52, which was approximately 30% lower than that of the untreated coating, and the wear rate of the coatings was 5.2×10-4 mm3 / (N·m). Compared with those of the unremelted coating (5.87×10-4 mm3 / (N·m)) and 1 kW-remelted coating (5.42×10-4 mm3 /(N·m)), it had a lower wear rate and exhibited superior friction-reducing and wear-resistant properties. This study analyzed the relationship between the phase composition and degree of lattice distortion of a medium-entropy alloy coating and its tribological properties. The influencing law of the laser remelting power on the mechanical properties of the medium-entropy alloy coating was obtained, which will provide theoretical support for the optimization design of high-performance medium-entropy alloy coatings.
  • JING Jiannong, LI Jing, LIU Hongge, CUI Xiangzhong, JIN Guo
    China Surface Engineering. 2026, 39(1): 109-118. https://doi.org/10.11933/CSE2026011
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    With the escalating severity of service temperatures for mechanical components in high-tech equipment, friction and wear arising from high-speed relative motion under high temperatures have become core factors restricting equipment reliability and service life. High-temperature lubricating and wear-resistant coatings thus emerge as a key solution to this issue. Yttria-stabilized zirconia (YSZ) coatings possess excellent high-temperature stability, yet their high friction coefficient and wear rate at elevated temperatures hinder direct application for lubrication. Existing research on high-temperature lubricating coatings mostly focuses on temperatures below 800 ℃, with scarce studies on extreme conditions above 1 000 ℃, leaving a significant research gap. Moreover, common lubricating phases like Ag-Mo are costly and prone to rapid consumption at high temperatures, while calcium fluoride (CaF₂), a low-cost alternative with a wider temperature range, suffers from oxidation, decomposition, and volatilization during plasma spraying (due to 10 000-15 000 ℃ plasma jets), reducing efficiency and increasing costs. To address these challenges, this study aimed to enhance YSZ coatings’ high-temperature lubrication performance and reduce CaF₂ loss during spraying. First, YSZ-coated CaF₂ powders were prepared via coprecipitation to improve powder wettability and minimize CaF₂ degradation. Then, using atmospheric plasma spraying (APS), YSZ + 6% CaF2 (wt%) coatings were fabricated on GH5188 superalloy substrates, with a NiCrAlY bond coat (50 μm thick) applied to boost adhesion. Spraying parameters were optimized: for NiCrAlY, Ar flow rate 40 L / min, H₂ flow rate 7.5 L / min, current 550 A, power 41 kW, gun distance 120 mm, and powder feeding rate 40 g / min; for the YSZ top coat (230 μm thick), Ar flow rate 40 L / min, H2 flow rate 8.5 L / min, current 600 A, power 45 kW, gun distance 100 mm, and powder feeding rate 40 g / min. Tribological properties were tested from room temperature to 1100°C using an HT-1000 tester (IC21 alloy ball as friction pair: 10 N load, 30 r / min, 5 mm friction radius, 30 min duration). Microstructural, elemental, mechanical, and phase analyses were conducted via SEM-EDS, Vickers hardness testing, tensile bonding strength measurement, XRD, and profilometry (for wear rate calculation).Results showed the coatings had good quality: porosity of 2.518%, average room-temperature Vickers hardness of 476.4 HV0.5 (standard deviation 58.9), 1 100 ℃ hardness of 169.3 HV0.5 (standard deviation 2.9), and average bonding strength of 55.08 MPa. Cross-sectional SEM-EDS revealed a lamellar structure: the YSZ-CaF2 top coat (220-240 μm) with dark CaF2 lamellae, and the 40-60 μm NiCrAlY bond coat, with uniform elemental distribution. Tribological behavior varied with temperature: room temperature (friction coefficient 0.25-0.45, wear rate 4.7×10⁻5 mm³ / (N·m)) relied on sheared IC21 material filling coating pits; 200 ℃ (0.15-0.2, 8.14×10⁻6 mm3 / (N·m)) formed a protective film from IC21 material; 400 ℃ (peaking at 0.7, 1.78×10⁻4 mm3 / (N·m)) saw abrasive wear due to coating strength loss; 600 ℃ (0.35, 1.28×10⁻5 mm3 / (N·m)) used IC21 oxide films for protection; 800 ℃ (0.4, 1.28×10⁻4 mm3 / (N·m)) involved CaF2’s ductile-brittle transition; 1 100 ℃ (0.2, 6.11×10⁻⁴ mm3 / (N·m)) generated CaCrO4 / CaZrO3 ternary oxides (from CaF2 reactions) for lubrication, confirmed by XRD (disappeared CaF2 peaks, new CaZrO3 peaks).This study innovatively used YSZ-coated CaF2 powders to reduce spraying loss and improve coating performance, clarifying temperature-dependent wear mechanisms and CaF2’s high-temperature role. It fills the gap in extreme high-temperature coating research, providing data support for coating design under >1 000 ℃ conditions. Limitations include a sharp friction coefficient increase at 400 ℃ and high 1 100 ℃ wear rate, guiding future optimization of composition and processes.
  • ZHU Shuaishuai, ZHANG Baosen, SUN Ran, XIE Caidong, ZHANG Chao, SHAN Dongwen
    China Surface Engineering. 2026, 39(1): 119-130. https://doi.org/10.11933/CSE2026012
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    High-entropy amorphous alloys are a new type of material that features both disordered atomic stacking structure and multi-principal component characteristics. It exhibits macroscopic isotropy, simple structure, uniform chemical composition, and no crystal defects such as grains and grain boundaries. Consequently, they possess outstanding mechanical qualities, resistance to corrosion and wear, and a wide range of potential applications in the protective coating industry. High-velocity air fuel (HVAF) spraying technology is a new type of thermal spraying technology that employs compressed air as a combustion-supporting agent, producing a flame stream with a velocity exceeding 1 100 m / s and a temperature of approximately 1 900 ℃. Amorphous alloy coatings prepared by HVAF exhibit a higher amorphous content, lower porosity, and reduced oxide content, resulting in superior corrosion and wear resistance. In this study, (Co0.34Ni0.33Cr0.23Mo0.1)76Nb4(B0.7Si0.3)20 high-entropy amorphous alloy feedstock powders and coatings were fabricated using gas-atomized powders and HVAF spraying. The evolution of the microstructure of the CoNiCrMo-based high-entropy amorphous alloy coatings after heat treatment at different temperatures was systematically investigated. However, there is limited research on the effects of annealing on the microstructure and performance evolution of high-entropy amorphous coatings. The effect of annealing on the microstructure of high-entropy amorphous alloy coatings was characterized and analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy-dispersive X-ray spectroscopy (EDS), among other techniques. The influence of annealing on the nanomechanical properties and tribological behavior of the coatings was studied and analyzed using a nanoindentation instrument and a friction and wear testing machine. The experimental results indicate that the prepared CoNiCrMo-based high-entropy amorphous alloy powders and the as-sprayed coatings presented a fully amorphous structure. Crystallization of the coating commenced upon annealing at 600 ℃, while an amorphous content of 47.94% was still retained. The coating became fully crystallized when the annealing temperature reached 800 ℃. As the annealing temperature increased from 600 ℃ to 1 000 ℃, the grain size of the crystalline phases increased gradually. After annealing at 600 ℃, 800 ℃, and 1 000 ℃, the grain size of the coating crystalline phase became 5-20 nm, 20-35 nm, and 250-350 nm, respectively. The fully crystallized coating was primarily composed of FCC, MoCoB, Cr5B3, and Nb3Ni2Si phases. The nanomechanical properties of the coating, including its hardness and resistance to plastic deformation (characterized by H / E and H³ / E² ratios), initially enhanced and then deteriorated with increasing annealing temperature. The coating annealed at 800 °C exhibited a peak hardness of 14.16 GPa, representing a significant increase of 32.46% compared to the as-sprayed coating. The friction process of sprayed and annealed coatings was divided into an early running-in stage and a later stable wear stage; the steady-state friction coefficient of all coatings ranged between 0.55 and 0.70 in a stable manner. The wear rate of the coating exhibited a similar trend, first decreasing and then increasing with increasing annealing temperature. The minimum wear rate of 6.55 ×10-6 mm3·N-1·m-1 was achieved after annealing at 800 ℃, which is 64.78% lower than that of the as-sprayed coating. The wear mechanisms of both the as-sprayed and annealed coatings were identified as abrasive, fatigue, oxidative, and adhesive. However, when the annealing temperature reached 1 000 ℃, the load-bearing capacity of the coating decreased, and the wear process was predominantly controlled by abrasive wear. This study reveals the influence of microstructural evolution on the tribological behavior of coatings, thereby providing valuable insights for the application of CoNiCrMo-based high-entropy amorphous alloy coatings with excellent wear resistance.
  • WANG Xiaohe, CHEN Zhijian, WEI Shicheng, WANG Yujiang, XU Yang
    China Surface Engineering. 2026, 39(1): 131-141. https://doi.org/10.11933/CSE2026013
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    Brush plating technique is extensively used; however, there is a lack of research on the voltage regulation process for zinc sulfate-nickel citrate bath systems. Aimed at the practical requirements of marine environment corrosion protection for high-strength steel surfaces, zinc-nickel alloy coatings are fabricated on 40Cr steel substrates using brush plating technique. The effects of 6-10 V working voltage on the deposition behavior, microstructures, compositions, and corrosion resistance of the coatings are studied. The coatings are prepared using electrodeposition assisted by a sulfate electrolyte with a special formula containing zinc sulfate heptahydrate, nickel sulfate hexahydrate, ammonium citrate, sodium citrate dihydrate, and ammonia water, whose molar fraction of nickel is set to 40%. After brush plating, all the coatings are immersed in a commercial trivalent chromium passivation solution for 1 min to improve the stability of the coating surfaces. There is a direct relation between the cathode current density and working voltage during the brush plating process. By quantitative analysis, it is found that there is a very pronounced nonmonotonic relation between the voltage and growth kinetics of the coating. When the voltage is relatively low, the thickness of the coating remains at a relatively low level. At 6 V, the measured thickness of the coating is 19.02 µm. When the voltage is increased to 7 V, the measured thickness is 18.37 µm. When the voltage is increased to 8 V, the thickness of the coating increases significantly by 15% to reach 37.79 µm. At 9 V, the thickness of the coating is maximum, reaching 56.61 µm. However, when the voltage is increased to 10 V, the thickness of the coating decreases significantly by 23.5% to become 43.35 µm. This thickness reversal at the highest voltage is mainly attributed to the synergistic effect resulting from the enhanced cathodic hydrogen evolution reaction and the diffusion of zinc and nickel cations toward the cathode surface at a limited speed. In addition, owing to the abrasive effect resulting from the moving graphite brush anode under excessive current density, part of the newly formed coating is abraded away, thereby leading to mechanical degradation. The nickel content increases systematically from 4.88wt.% at 6 V, to 6.77wt.% at 7 V, 9.2wt.% at 8 V, and 9.1wt.% at 9 V, reaching a maximum value of 10.44% when the voltage is 10 V. This tendency agrees with the electrochemical principle that, under higher voltage conditions, increasing the cathodic polarization favorably promotes the reduction in low-purity nickel ions. After conducting an energy dispersive X-ray spectroscopy comparative analysis of the coating surfaces and cross-sections, it is confirmed that a functional chromium-based passivation layer is successfully formed, and the concentrations of oxygen and chromium increase significantly from the surface. By characterizing the microstructure, a clear correlation between the voltage and coating morphology is established. The coatings produced at relatively low voltages exhibit less-than-ideal characteristics. These characteristics include a rough particle structure that is not distinct, inherent porosity, a relatively loose microstructure, and an uneven terrain of the coatings with visible brush marks. These disadvantages result from insufficient cathodic polarization, which hinders the nucleation process and also favors the dominant deposition of zinc. By contrast, the coatings within the voltage range of 8-9 V exhibite a relatively ideal microstructure. This microstructure has a high density, is highly uniform, and forms typical cauliflower-like agglomerates, forming a beneficial gamma-phase intermetallic structure. Moreover, the surfaces of the coatings are apparently smooth. Most importantly, the coating deposited at 10 V exhibits severe structural degradation. This degradation manifests as ubiquitous microcracks, which are observed in cross-sectional scanning electron microscopy images transmitted from the substrate to the coating interface. These cracks are caused by hydrogen entrapment owing to intense hydrogen evolution, potential local Joule heating, increased internal stress due to rapid disordered deposition, and lattice distortion due to high nickel inclusions. In 5wt.% sodium chloride solution, the most crucial functional performance of the coatings, i.e., corrosion resistance, is rigorously evaluated by potentiodynamic polarization and electrochemical impedance spectroscopy. The coatings prepared at 8 V and 9 V demonstrate extremely excellent performance with the lowest corrosion current density, which is 4.47 µA / cm2 for the coating prepared at 8 V and 3.39 µA / cm2 for that prepared at 9 V. Their negative corrosion potentials are also the lowest. This superior protective effect is directly attributed to the relatively thick coating. An optimal nickel content of approximately 9% promotes the formation of the gamma phase, which can play a protective role. The microstructure is very dense with high integrity and minimized defects, which can serve as an effective barrier to chloride ion penetration. In sharp contrast, the coating prepared at 10 V suffers very serious degradation. Its corrosion potential shifts very negatively to - 1295 mV and corrosion current density is 19.5 µA / cm2, which is more than five times higher than that of the coating prepared at 9 V. This deterioration is evidently associated with widespread microcracks, which offer a very convenient route for electrolyte ingress. It also accelerates the galvanic corrosion of the underlying steel. The coatings produced at lower voltages exhibit significantly poorer corrosion resistance with corrosion current densities of 12.5 µA / cm2 and 7.4 µA / cm2, respectively. The inherent porosity of the coatings is high, and the compositions mainly consist of zinc and lack the gamma-phase structure, which can play a protective role.
  • DONG Yuqi, CUI Xiufang, JIN Guo, LI Dayan, SONG Haoyu, WANG Chongrui
    China Surface Engineering. 2026, 39(1): 142-154. https://doi.org/10.11933/CSE2026014
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    The demand for corrosion protection of high-strength steels in marine environments is increasing, and the development of high-performance coating materials is an effective approach to broadening their application prospects for high-strength steels. Electrodeposited Cr and Cd coatings are commonly used in various engineering fields to protect high-strength steels. However, the carcinogenicity and toxicity associated with their preparation processes significantly limit their applicability. Electrodeposited Zn-Ni alloy coatings are progressively replacing Cd coatings as highly promising candidates for protecting high-strength steel in marine environments because of their high corrosion resistance and environmentally friendly characteristics. Notably, when Zn-Ni alloy coatings exhibit a single γ-(Zn, Ni) phase structure, they can deliver the most excellent corrosion protection for high-strength steel substrates. Although many studies have been conducted to explore the preparation process and corrosion resistance of Zn-Ni alloy coatings, insufficient attention has been given to the dynamic corrosion behavior characteristics and fundamental formation mechanisms of critical corrosion product layers in marine environments. For enhanced large-scale application of Zn-Ni alloy coatings in marine engineering, an in-depth analysis of their corrosion behavior should be conducted and the formation mechanisms of essential corrosion product layers in complex marine environments elucidated. This study aimed to reveal the corrosion mechanism and protection mechanism of γ-(Zn, Ni) single-phase Zn-Ni alloy coatings and systematically evaluate the influence of grain size on their corrosion resistance. γ-(Zn, Ni) single-phase Zn-Ni alloy coatings were prepared using direct current electrodeposition at three distinct cathodic current densities, and the coating thicknesses were in the range of 12.94-18.05 μm. The microstructure, phase composition, and corrosion resistance of the materials were investigated using scanning electron microscopy, X-ray diffraction, and electrochemical tests. The corrosion behavior of the coatings and evolution of the corrosion products in 3.5 wt.% NaCl solution were characterized and systematically investigated using immersion tests and X-ray photoelectron spectroscopy. The results demonstrate that with an increase in current density, the nucleation rate on the cathode surface during electrodeposition increases exponentially, which is conducive to the formation of a large number of crystal nuclei and restricts the growth of grains. This results in a significant refinement of the grain size of the coating. The change in grain size directly enhanced the coating corrosion resistance, and the potentiodynamic polarization curves showed that the coating with the finest grain size (electrodeposition cathodic current density of 2.0 A / dm2) exhibited the lowest corrosion current density (1.90×10-6 A / cm2), which demonstrated the optimal corrosion resistance. The passivation film formation and corrosion mechanisms were analyzed after the immersion test. A Zn-Ni alloy coating was used as a sacrificial protective layer, and the coating preferentially underwent uniform corrosion in 3.5wt.% NaCl solution to form a passivation film that includes Zn(OH)2, ZnO, Zn5(OH)8Cl2, and Zn5(CO3)2(OH)6 as corrosion products. The refined grains provided more nucleation sites for the nucleation and growth of corrosion products, which helped the corrosion product layer spread uniformly into a passivation film on the coating surface and provide a barrier effect on the corrosive medium. However, Zn5(OH)8Cl2 has a lamellar structure, which is prone to form pores by growing perpendicularly on the surface of the coating at the late stage of corrosion and causes microcracks in the passivation film to emerge as a result of the volume expansion. However, it still maintains macroscopic integrity and can cover the surface of the coating to a certain extent. The coating and substrate play a better protective role, effectively delay the further deterioration of corrosion, and significantly enhance the corrosion resistance of Zn-Ni alloy coatings life. This enables long-term synergistic protection of the coating and substrate for the long-lasting protection of high-strength steel components in complex marine environments. Thus, this paper provides an important theoretical basis.
  • YIN Shuo, WANG Ze, CHENG Jiangbo, HONG Sheng
    China Surface Engineering. 2026, 39(1): 155-165. https://doi.org/10.11933/CSE2026015
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    Atmospheric plasma spray has been widely adopted to fabricate ceramic coatings owing to its high efficiency. However, sprayed coatings typically exhibit high porosities, which significantly compromises their protective performance in marine environments. Therefore, reducing the coating porosity and enhancing the corrosion resistance are critical issues that require urgent resolution. In this study, multiple sealing treatments were applied to enhance the corrosion resistance of plasma-sprayed coatings because the sealing agent can penetrate and fill the surface microcracks and pores. Two types of sealants were selected: inorganic sealant aluminum phosphate and organic sealant silicone resin. Inorganic sealants exhibit low adhesion but good heat resistance. Organic sealants have better surface tension and viscosity but poorer heat resistance. For the two sealants, sealing treatments of the coatings were performed using two distinct methods: atmospheric immersion sealing (CIS) and vacuum immersion sealing (VIS). Scanning electron microscopy (SEM) was used to characterize the microstructures of the original powders and coatings before and after spraying. X-ray diffraction (XRD) was used to analyze the phase compositions of the powders and sprayed coatings. The corrosion resistance of the coatings after sealing was assessed using electrochemical impedance spectroscopy (EIS), polarization curves, and equivalent circuit modeling. The results indicated that prior to spraying, the coating primarily comprised α-Al2O3, γ-Al2O3, and rutile-type TiO2. After spraying, the coating contained only the rutile TiO2 phase, with abundant microcracks and pores visible in the cross-section. The sealed coatings were then subjected to seawater immersion corrosion tests. The coatings were sealed with either silicone resin or aluminum phosphate. In all cases, the main phase diffraction peak intensities revealed that vacuum treatment was better than conventional treatment. The results showed that the vacuum impregnation sealing process can fill the microcracks and pores in the coating more effectively. Moreover, vacuum treatment improved the effectiveness of inorganic sealants more than organic sealants. The polarization curves in 3.5 wt.% NaCl solution revealed that the corrosion resistance of the coatings followed this order: VIS-SR > CIS-SR > VIS-AP > CIS-AP > AT13. Therefore, with regard to sealing materials, silicone resin outperformed aluminum phosphate in terms of sealing effectiveness. This is because the evaporation of moisture from the aluminum phosphate sol during drying generates internal stress, which leads to the formation of new microcracks. To further study the corrosion resistance of the coatings following the sealing treatment, we employed EIS to analyze equivalent circuit fitting in conjunction with Nyquist and Bode plots. The results showed that VIS-AP, VIS-SR, and CIS-SR coatings had higher low-frequency impedances and similar capacitive arc radii, whereas the CIS-AP coating exhibited the lowest capacitive arc radius and low-frequency impedance. The fitting results showed that the coatings sealed with the organic sealants exhibited higher R1 values. The larger the R1 value, the lower the current in the equivalent circuit, suggesting an enhanced current-blocking capacity of the protective film. This also indicated that organic sealants have a more significant effect on improving the corrosion resistance of the coatings. Microscopic analysis before and after corrosion revealed that the unsealed coating surface contained large pores. After sealing, the sealant filled the defects on the coating surface, effectively providing protection. After the corrosion test, the unsealed coatings exhibited large corrosion pits, whereas the sealed coatings exhibited higher corrosion resistance. However, owing to the influence of corrosion stress, numerous microcracks still appeared on the coating surface. The residual stress in atmospheric plasma-sprayed coatings further promoted crack propagation, accelerating the corrosion process and causing earlier coating failure. This study indicated that all four sealing processes enhanced the corrosion resistance of the coatings. Among the four sealing methods, coatings sealed with silicone resin under vacuum exhibited the highest charge-transfer resistance (Rct) and polarization resistance (Rp), as well as the largest capacitive arc radius and impedance magnitude. Consequently, the coatings processed using this sealing technique demonstrate superior comprehensive corrosion resistance.
  • MA Cong, ZHANG Enhao, JING Zhiyuan, YUAN Jiachi, HONG Sheng, ZHANG Zhibin
    China Surface Engineering. 2026, 39(1): 166-178. https://doi.org/10.11933/CSE2026016
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    With the increasing demand for surface protection in marine engineering equipment, conventional Al coatings have encountered significant limitations in complex corrosive environments due to their inherently low hardness and poor wear resistance. In this study, we used high-velocity arc spraying (HVAS) technology to fabricate an aluminum-based amorphous / nanocrystalline composite coating with a nominal composition of Al80Ni12Nb5Fe3 (at.%). Systematic investigations of its microstructure, mechanical properties, and corrosion behavior provide novel insights into methods to protect steel structures from corrosion in marine environments. X-ray diffraction (XRD) and transmission electron microscopy (TEM) revealed that the amorphous / nanocrystalline AlNiNbFe coating exhibited an amorphous-phase volume fraction as high as 72%, alongside precipitated phases such as α-Al nanocrystals. The microstructure featured a dispersed distribution of crystalline phases, with the amorphous phase effectively encapsulating them and forming a continuous amorphous network structure. Differential scanning calorimetry (DSC) analysis revealed excellent thermal stability, with a glass transition temperature of approximately 397 ℃, which surpasses that of comparable aluminum-based amorphous / nanocrystalline coatings. Microhardness testing indicated that the hardness of the AlNiNbFe amorphous / nanocrystalline coating (HV0.1 370) was 9.5 times higher than that of the pure aluminum coating (HV0.1 39). This enhancement is primarily attributed to the high amorphous content, the uniform and dense internal structure, and the dispersion-strengthening effect of the α-Al nanocrystals. Electrochemical testing revealed that the coating exhibited outstanding corrosion resistance. In a 3.5wt.% NaCl solution, its polarization resistance (Rp = 32.91 kΩ·cm2) increased by a factor of 24 compared to the 45 steel substrate (Rp = 1.37 kΩ·cm2), while the corrosion current density (Icorr = 1.22 μA·cm-2) was only 1 / 32nd that of the substrate (Icorr = 39.81 μA·cm-2). Scanning Kelvin probe force microscopy (SKPFM) analysis further revealed that the amorphous phase exhibited a uniform composition without grain boundaries and a higher surface potential difference, which made it less susceptible to initial corrosion. Conversely, the crystallized phase exhibited a lower surface potential, which rendered it more susceptible to corrosion. Long-term immersion tests demonstrated that after 24 h, the coating formed a passivation film primarily composed of Al, Ni, Nb, and Fe oxides, which effectively inhibited the penetration of corrosive media. When the immersion time was extended to 72 h, the density of the passivation film increased further, with no significant corrosion pitting observed on the surface of the coating. X-ray photoelectron spectroscopy (XPS) analysis confirmed that the Ni, Nb, and Fe oxides exhibited structural stability during corrosion, whereas the oxide film formed by Al exhibited dynamic generation and dissolution behaviors. This dynamic equilibrium facilitated a ‘self-healing’ effect for corrosion products, which enabled the passivation film to sustain its protective performance. This study innovatively employed high-velocity arc spraying to fabricate an amorphous / nanocrystalline AlNiNbFe coating with a high amorphous content (72%). Compared to conventional aluminum coatings, the AlNiNbFe amorphous / nanocrystalline coating not only exhibited significantly enhanced hardness (by a factor of 9.5), but also showed substantially improved corrosion resistance (polarization resistance increased by a factor of 24, corrosion current density reduced to 1 / 32nd), which overcomes the limitations of low hardness and poor wear resistance inherent in traditional aluminum coatings. The process of preparing the coating obviates the need to synthesize an amorphous precursor by forming the amorphous / nanocrystalline composite coating in situ. This avoids the energy-intensive preparation of amorphous powders, which offers some notable advantages such as higher efficiency, better cost-effectiveness, and the absence of complex pretreatments. Thus, a novel approach is provided to protect the surfaces of marine engineering equipment. This research not only establishes a method to prepare aluminum-based amorphous coatings but also elucidates the mechanism of corrosion of amorphous / nanocrystalline composite coatings. The results pose some significant theoretical and practical implications for advancing the application of high-performance aluminum-based amorphous coatings in marine engineering. The AlNiNbFe amorphous / nanocrystalline coating produced via high-velocity arc spraying shows promise for significant applications in severely corrosive environments, such as marine engineering, shipbuilding, and petrochemical industries. Thus, this work provides a new approach to enhance the service life and safety of marine engineering equipment.
  • WANG Haodong, DA Qiang, ZHOU Yongkuan, KANG Jiajie, YUE Wen
    China Surface Engineering. 2026, 39(1): 179-188. https://doi.org/10.11933/CSE2026017
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    To enhance the erosion resistance of turbine blades, a FeCrMoCBY iron-based amorphous alloy coating was fabricated on the surface of the turbine drill tool blade substrate using cold spraying technology. The microstructure and damage morphology of the coating after cavitation and erosion tests were analyzed and characterized using field emission scanning electron microscopy (FESEM); the phase composition of the FeCrMoCBY iron-based amorphous alloy coating was analyzed using X-ray diffraction (XRD); the microhardness of the FeCrMoCBY iron-based amorphous alloy coating was measured using a microhardness tester. The cavitation erosion performance of the FeCrMoCBY iron-based amorphous alloy coating was evaluated using an ultrasonic vibration cavitation erosion test machine, testing the cavitation erosion performance under different pH values (9, 10, 11) and different drilling fluid temperatures (30 ℃, 50 ℃, 70 ℃); the erosion performance of the FeCrMoCBY iron-based amorphous alloy coating was tested using a dynamic load abrasive wear tester, investigating the effects of different drilling fluid temperatures (30 ℃, 50 ℃, 70 ℃), erosion angles (30°, 45°, 60°, 90°), sand content (20%, 30%, 50%), and pH values (9, 10, 11) on the erosion resistance of the FeCrMoCBY iron-based amorphous alloy coating. The research results show that the FeCrMoCBY iron-based amorphous alloy coating fabricated on the turbine drill tool blade substrate surface has good bonding with the substrate, and the microstructure of the coating is dense. The XRD results indicate that the non-crystalline phase content of the FeCrMoCBY iron-based amorphous alloy coating is 85.4%. The microhardness of the FeCrMoCBY iron-based amorphous alloy coating is approximately 600 HV0.5, which is about 2.5 times that of the base material 304 stainless steel. In terms of cavitation erosion performance, as the drilling fluid temperature increases, the hydration effect of bentonite in the drilling fluid is weakened, resulting in the disruption of the stability of the anti-filtering agent CMC-Na in the drilling fluid, causing a decrease in the viscosity of the drilling fluid, and a more significant cavitation effect on the surface of the FeCrMoCBY iron-based amorphous alloy coating. This leads to an increase in the cavitation weight loss rate of the coating. As the pH value of the drilling fluid increases, the cavitation weight loss rate of the FeCrMoCBY iron-based amorphous alloy coating shows a trend of first decreasing and then increasing. When the pH value of the drilling fluid is 10, the weight loss rate of the FeCrMoCBY iron-based amorphous alloy coating reaches the minimum value, indicating that the FeCrMoCBY iron-based amorphous alloy coating surface undergoes the strongest passivation effect under this condition, and its cavitation erosion resistance is the best. In terms of erosion resistance, as the pH value of the drilling fluid increases, the erosion weight loss rate of the FeCrMoCBY iron-based amorphous alloy coating also shows a trend of first decreasing and then increasing. The increase in the erosion angle leads to an increase in the normal velocity component of the abrasive and enhanced erosion energy, resulting in a more severe loss of the FeCrMoCBY iron-based amorphous alloy coating material. The increase in sand content leads to an increase in the collision probability between particles, and the degree of erosion wear of the coating increases. In terms of temperature effects, when the drilling fluid temperature is less than 50 ℃, the erosion weight loss rate of the FeCrMoCBY iron-based amorphous alloy coating remains stable. When the drilling fluid temperature increases to 70 ℃, the anti-filtering agent CMC-Na in the drilling fluid degrades, the viscosity of the drilling fluid decreases, and the impact kinetic energy of quartz sand particles on the surface of the FeCrMoCBY iron-based amorphous alloy coating increases, leading to a significant increase in the erosion wear of the FeCrMoCBY iron-based amorphous alloy coating surface.
  • MOU Honglin, MA Guozheng, CAI Zhihai, ZHU Xianyong, LIU Ming, WANG Haidou
    China Surface Engineering. 2026, 39(1): 189-214. https://doi.org/10.11933/CSE2026018
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    Thermal barrier coatings (TBCs) are a core technology for protecting hot-end components in the aerospace, aviation, and energy sectors and play a critical role in ensuring the safe and stable operation of these high-temperature systems. Since the concept of TBCs was proposed by NASA in the 1950s, this vital technology has gone through nearly 80 years of continuous development and evolution. During this period, several researchers worldwide devoted tremendous time, energy, and expertise to advancing its material systems, preparation processes, and overall performance, laying a solid foundation for its widespread application in key industries. With the rapid development of high-entropy alloys (HEAs) and high-entropy ceramics (HECs) in recent years, high-entropy materials engineering has emerged as a crucial and promising development direction for TBC material systems. This shift toward high entropy has created new avenues for overcoming the performance limitations of traditional TBC materials. However, systematic reviews that comprehensively discuss the structural evolution of coatings, their damage mechanisms, and innovation directions in the context of high-entropy engineering remain relatively scarce. This limitation makes providing effective theoretical and technical support for collaboration between research and practical applications in the TBC field difficult, hindering the translation of lab-based achievements into industrial practice. To address this gap, this paper systematically sorts out the changes in TBC demand driven by the continuous advancements in industrial production (such as energy equipment upgrades) and aerospace transportation (including aircraft and spacecraft development) from the perspective of the need for heat management and control. It shows that the operating conditions of hot-end components (such as gas turbine blades and aero-engine parts) are gradually breaking through the 1200 ℃ temperature resistance limit of traditional TBCs, making it urgent to research and develop new types of ultra-high-temperature TBCs that can withstand more extreme thermal environments. Subsequently, this paper explains the core service mechanism of these advanced TBCs, which achieve synergy through two key approaches: reducing the thermal conductivity through phonon scattering and improving the thermal emissivity. It also analyzes the key damage mechanisms that threaten TBC longevity, including the growth of thermally grown oxide (TGO) at the coating interface, coupled corrosion caused by multiple factors, erosion-induced spallation, and sintering densification. This elaborates the innovation directions of high-entropy TBCs: the focus is moving toward multi-layered, gradient, and complex designs of the coating surface; the bond coat alloy is becoming more diversified and highly entropic through doping and dissolving refractory elements (such as W, Mo, and Ta) into its structure (to enhance high-temperature stability); and the top ceramic layer is undergoing structural diversification and high-entropy engineering based on classic structures such as fluorite, pyrochlore, and perovskite (to balance thermal insulation and corrosion resistance). Additionally, this review examines the application prospects of multi-principal component coating design driven by computational materials science, represented by machine learning, first-principles calculations, and phase diagram calculations, as well as the use of refractory high-entropy coatings under extreme operating conditions (such as hypersonic flight and nuclear energy systems). Finally, this paper proposes that developing new coating preparation technologies and combining them with existing mature ones while focusing on the efficient and low-cost preparation of high-entropy TBCs is the key path to the wide application of high-entropy coatings in hot-end component protection. This paper is expected to provide clear guidance for the development of high-performance coatings and contribute to the collaborative advancement of coating research and applications under harsh working conditions.
  • JU Jinchi, HE Pengfei, HU Shujun, SUN Chuan, MENG Hong, DUAN Ximing, HU Zhenfeng, LIANG Xiubing
    China Surface Engineering. 2026, 39(1): 215-241. https://doi.org/10.11933/CSE2026019
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    Ultrahigh-temperature boride-silicon carbide-based ceramics are highly promising thermal-protection materials for the thermal components of high-speed aircraft owing to their high melting point, excellent thermal conductivity, and superior ablation resistance. This review systematically summarizes recent studies pertaining to the oxidation and ablation resistance of ultrahigh-temperature boride-silicon carbide coating materials. It focuses on the enhancement mechanisms achieved by incorporating various modification phases, including refractory metal silicides, rare-earth oxides, and other additives, such as borides, carbides, oxides, and metallic / non-metallic elements. The incorporation of SiC as a second phase significantly enhances the oxidation and ablation resistance of ZrB2 and HfB2 ceramics. The formation of a SiO2-rich glassy phase effectively prevents oxygen diffusion. However, in high-temperature environments exceeding 1 800  ℃, SiC undergoes active oxidation. This results in the formation of a porous SiC depletion layer, which severely degrades the oxidation and ablation resistance of the ultrahigh-temperature boride-silicon carbide coating material. To suppress this phenomenon, researchers have introduced various modification phases to improve the oxidation and ablation resistance by regulating the structure of the oxide scale, increasing the viscosity of the glass phase, and inhibiting oxygen diffusion. Refractory metal silicides (e.g., MoSi2, WSi2, TaSi2, ZrSi2, and HfSi2) enhance the oxidation and ablation resistance by providing an additional Si source, thereby resulting in complex glass phases and promoting densification. MoSi2 and WSi2 form volatile MoO3 and WO3 during oxidation, thus reducing the surface temperature; however, their excessive addition increases porosity. The modifying effect of TaSi2 exhibits significant temperature dependence. At an intermediate temperature (approximately 1 600 ℃), TaSi2 effectively inhibits the formation of a SiC depletion layer. The oxidation product Ta2O5 dissolves in the glass phase or reacts with ZrO2 / HfO2, thus resulting in a denser oxide scale. At ultrahigh temperatures (>1 900 ℃), Ta-containing oxidation products have relatively low melting points and tend to form low-melting eutectic phases, thus reducing the stability of the oxide scale. ZrSi2 and HfSi2 enhance the stability of the oxide scale by forming (Zr,Hf)O2 solid solutions, which inhibit oxygen diffusion. Rare-earth compounds (e.g., La2O3, Y2O3, Sm2O3, and Yb2O3) improve the oxidation and ablation resistance of coatings by refining grains, stabilizing ZrO2 / HfO2 structures, increasing the viscosity of the glass phase, and enhancing material emissivity. Rare-earth cations dissolve in the ZrO2 / HfO2 lattice, thus suppressing volume changes during phase transition. Additionally, La2O3 and LaB6 facilitate the formation of a stable La-Si-O glass layer. Y2O3 can react with SiO2 to form silicate nanocrystals, such as Y2Si2O7 or Y2SiO5, which disperse in the glass phase and increase the viscosity. Sm2O3 significantly enhances the emissivity of the coatings, strengthens thermal radiation, and reduces the surface temperature. Yb2O3 effectively increases the viscosity of the glass phase owing to its small ionic radius and high field strength. However, excessive addition of rare-earth elements may weaken the glass-phase structure and increase the oxygen-vacancy concentration, thus weakening the oxidation and ablation resistance of the coatings. Other modification phases, such as borides (TaB and WB), carbides (ZrC, WC, and TaC), oxides (MgO and Al2O3), and metallic / non-metallic elements (W, Si, and C), can enhance oxidation and ablation resistance through different mechanisms. ZrC can occupy the pores by forming ZrO2, which inhibits the formation of the SiC depletion layer. The oxidation of WC forms WO3, which promotes the liquid-phase sintering of ZrO2. Graphene modification significantly improves the thermal conductivity and reduces the surface temperature of the coatings. The introduction of elemental Si directly increases the Si content and suppresses the active oxidation of SiC. Currently, the thermal-protection performance of ultrahigh-temperature boride-silicon carbide coating materials is limited to 2 300 ℃. Future studies should focus on the following aspects: first, the dynamic evolution mechanisms and quantitative evaluation methods for oxide scales should be investigated comprehensively. Second, data-driven approaches can be used to screen for modification phases and predict material performance. Finally, new active-passive synergistic thermal-protection mechanisms must be identified.
  • HUANG Zhi, WU Shengfu, HE Mengjia, ZHANG Shu’ai, ZHOU Kaixuan, JIN Guo
    China Surface Engineering. 2026, 39(1): 242-250. https://doi.org/10.11933/CSE2026020
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    Polyimide resin matrix composites are used in aero-engine bypass casings, effectively reducing engine weight. However, these composites are susceptible to thermal damage during service. Preparing an anti-ablation coating on the surface of polyimide resin matrix composites improves their high-temperature performance. Previous studies have shown that adding a single ablation phase to yttria-stabilized zirconia (YSZ) coating can enhance its ablation resistance, although certain limitations remain. Resin matrix composites are widely used in aero-engines, but the limited heat resistance of the resin matrix makes them vulnerable to thermal damage at high temperatures. In this study, three types of Cu / Al / Zn composite ablation phases were added to an existing YSZ coating to investigate their synergistic effect on the ablation resistance of sweating thermal barrier coatings. Four types of Al / Zn / Cu composite ablative powders (YSZ1-YSZ4) were prepared using a solid-phase mixing method. A three-layer sweating thermal barrier coating—Al / Zn / Cu-doped YSZ (sweating layer) + NiCrAlY (metal transition layer) + Al (bottom layer)—was fabricated on polyimide resin matrix composites by explosive spraying, followed by ablation testing. A thermal synchronous analyzer was used to measure the heat absorption and release behavior of the four powders. The surface and cross-sectional morphologies of the powders and coatings before and after ablation were characterized using scanning electron microscopy. Based on the ablation results, the influence of the Cu / Al / Zn ablation phases on YSZ coating performance and the synergistic enhancement mechanism were analyzed. The results showed that the four composite ablative phase powders with different ratios exhibited the structure of YSZ ceramic particles coated with Cu, Al, and Zn ablative phases. The first endothermic peak temperatures of YSZ1, YSZ2, and YSZ4 powders were 417 °C, 418 °C, and 417 °C, respectively. The second endothermic peak temperatures of YSZ1, YSZ3, and YSZ4 powders were 656 °C, 653 °C, and 654 °C, respectively. The ablative phases in the coating were distributed in strip-like regions with micron-scale thickness and appeared as ablative-phase-coated, unmelted YSZ particles. After ablation testing, significant surface cracking and internal structural damage occurred in YSZ2, YSZ3, and YSZ4 coatings. The sweating layer of the YSZ1 coating exhibited vertical cracks but no deeper structural degradation. Zn and Al influenced the first and second endothermic peak temperatures of the powders, respectively. The transpiration-cooling effect of the coating was primarily governed by the melting and heat absorption of the Zn and Al ablative phases, while the Cu phase indirectly enhanced the overall cooling effect. Among the coatings, YSZ1 demonstrated the best ablation resistance. The synergistic mechanism of the three Cu / Al / Zn composite ablation phases was attributed to the low melting point of Zn, which reduced coating temperature through endothermic evaporation; the strong heat absorption capacity of Al, which melted and filled coating pores; and the high thermal conductivity of Cu, which diffused heat to the lower-melting point phases of Zn and Al, thereby indirectly improving cooling efficiency. This study establishes a new multi-component modified anti-ablation protection system and provides a novel modification pathway for coating protection of aero-engine bypass casings.
  • WANG Liang, LIU Rongrong, ZHANG Shu’ai, GUAN Xiqiao, FAN Yuxing
    China Surface Engineering. 2026, 39(1): 251-261. https://doi.org/10.11933/CSE2026021
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    Aero-engine bypass casings are vulnerable to thermal damage during service. An yttria-stabilized zirconia (YSZ) coating doped with an ablative phase provides effective thermal protection. In this study, CuZn and CuAl ablation phases were doped with YSZ coatings, and ablation experiments were performed. The thermal protection effects of the two ablation phases were compared, and the mechanism of the ablation effect on the coating performance was explored. Five types of single-ablative-phase sweating powders with different composition ratios were prepared using the mechanical mixing method. Because polyimide resin matrix composites are susceptible to thermal damage during wire cutting, Q235 steel was used in this study. Double-layer sweating thermal barrier coatings of YSZ (sweating layer) and NiCrAlY (transition layer) were prepared on a Q235 metal substrate using plasma spraying. We focused on the effects of the different ablation contents on the ablation resistance of sweating thermal barrier coatings. Ablation experiments were performed to test the ablation resistances of the five coatings. The heat absorption and release processes and the melting point temperature of the ablative phase were detected using a thermal synchronous analyzer to analyze the experimental feasibility of the two ablative phases. The surface roughness of the coating was determined using a three-dimensional topography analyzer to analyze the effect of adding the ablation phase on the porosity of the coating. The surface and cross-sectional morphologies of the coatings were characterized using scanning electron microscopy. Combined with the microstructural changes in the coating, the anti-ablation performance of the coating and mechanism of the ablation phase were determined. The experimental results showed that the effective endothermic temperatures of CuZn and CuAl ablative phases were 1 070 and 550 °C, respectively. The melting point temperature of the two ablative phases was much lower than that of YSZ at 2 500 °C. Both ablative phases could melt and absorb heat at high temperatures to achieve cooling without destroying the structural stability of YSZ. The surface roughness of pure YSZ coating was 5.832 μm, whereas that of the coating doped with four types of ablation phases ranged from 6.683 to 10.38 μm. The porosity of the coating doped with the four ablation phases decreased from 12.65% to approximately 9%. YSZ + 5% CuAl had the highest mass and linear ablation rates, which were 1.46 × 10-4 g / s and 1.3 × 10-4 mm / s, respectively, showing the best ablation performance. Because the melting point of the ablation phase differed from that of YSZ, the coating with the CuZn / CuAl ablation phase had a higher surface roughness. Additionally, during thermal spray deposition, the CuZn / CuAl ablative phase filled the pores of the YSZ coating, thereby reducing the porosity of the YSZ ceramic layer. The coatings with more ablation phases exerted a cooling effect. The high content of the single-ablative-phase sweating thermal barrier coating resulted in better ablation resistance. The melting point of the CuAl ablation phase was lower, and the cooling effect was better. During the entire ablation process, the ablation phase gradually absorbed heat, melted, and then diffused outward under the impact of the ablation flame flow. The ablation phase inside the coating expanded upon heating, increasing the number of bottom-up microcracks inside the coating. The ablation phase melted after reaching a certain temperature and overflowed from the pores and microcracks in the coating. Finally, the internal ablation phase replaced the surface ablation phase to achieve a top-down continuous sweating cooling effect. This paper provides a reference for the modification of ablation-resistant coatings. The research results provide theoretical support and technical paths for the design and optimization of bypass casing thermal protection coatings.
  • WANG Zhi, DONG Shiyun, YAN Shixing, LI Liwei, LIU Xiaoting, XIA Dan
    China Surface Engineering. 2026, 39(1): 262-274. https://doi.org/10.11933/CSE2026022
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    Selective laser melting (SLM) enables efficient fabrication of complex-structured Fe-Ni-Cr-based alloy steel components, which are vital to aerospace, national defense, shipbuilding, power generation, and petroleum engineering. It directly produces parts with intricate geometries, overcoming limitations of traditional casting (e.g., long cycles, degraded mechanical properties from elemental segregation). However, SLM-fabricated parts have inherently high surface roughness (initial Sa: 4-40 μm), impairing fatigue performance and assembly accuracy, making post-process surface finishing essential for reliable engineering application. Conventional polishing (mechanical, chemical) fails to balance adaptability to complex structures and environmental requirements, often causing pollution or altering surface chemistry. In contrast, femtosecond laser polishing (FLP) has become a focus for additively manufactured (AM) metal post-processing due to advantages: selective material removal, minimal heat-affected zone (HAZ), non-contact flexible processing, and no residual slag/microcracks. While existing studies explored individual FLP parameters (single-pulse energy, scanning speed, etc.) on SLM metal surface quality, systematic investigation of multi-parameter synergistic coupling effects remains insufficient, hindering FLP’s industrial adoption for efficient, uniform, low-damage polishing.
    In this study, Fe-Ni-Cr-based alloy steel fabricated via SLM is used as the target material, with a primary focus on elucidating the coupling mechanism between single-pulse energy (1-6 μJ) and spot overlap rate (50%-90%) in the FLP process, as well as the regulatory role of this mechanism in governing surface integrity. A 1 030 nm femtosecond laser system (pulse duration: 350 fs; repetition rate: 1 MHz) is employed, and a vertical cross-polishing strategy under the constraint of equal spot overlap rates in dual directions is adopted. This strategy strictly ensures that the spot overlap rates in the two perpendicular scanning directions (e.g., x-axis and y-axis) remain consistent, thereby fundamentally eliminating the interference of asymmetric overlap rates induced by scanning orientation on polishing uniformity. For the comprehensive characterization of polished surfaces, a combination of advanced techniques is utilized: field-emission scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (FE-SEM/EDS) for analyzing surface microtopography and elemental composition; laser confocal microscopy (LCM) for quantifying key surface roughness parameters (including Sa and Sz); and ImageJ image analysis for measuring the periodicity of micro-and nano-scale surface structures.
    The results show that single-pulse energy plays a decisive role in the evolution of surface topography: when the single-pulse energy ranges from 1 to 2 μJ, the surface is dominated by micron-scale periodic ripple structures; when it is between 3 and 4 μJ, the ripples weaken, the nano-agglomerated structures strengthen, and the surface tends to be flat overall; when the energy is 5 to 6 μJ, the surface forms a periodic ripple structure mainly composed of inhomogeneous nano-agglomerates, and Sa increases accordingly. Thus, the optimal single-pulse energy is determined to be 4 μJ. The influence law of the spot overlap rate is as follows: when the overlap rate is 50%-60%, the surface is dominated by micron-scale periodic ripple structures; when it is 70%-80%, the periodic ripple structures are significantly weakened, the distribution of nano-particles is more uniform, and the surface uniformity reaches the optimal level; when the overlap rate exceeds 90%, the surface uniformity deteriorates obviously. Therefore, the optimal spot overlap rate is 70%. Under the synergistically optimized parameter combination of 4 μJ single-pulse energy and 70% spot overlap rate, a single FLP process can reduce Sa from 14.18 μm to 11.89 μm (a relative reduction of 16.15%). Moreover, FE-SEM/EDS characterization further confirms that the polished surface is free of obvious microcracks and molten slag residues, the elemental composition remains essentially unchanged, and the overall surface integrity is excellent.
    This study systematically clarifies the coupling effect between single-pulse energy and spot overlap rate in the FLP process, and verifies that efficient, uniform, and low-damage surface polishing of SLM-fabricated Fe-Ni-Cr-based alloy steel can be achieved through multi-parameter synergistic optimization. The underlying mechanism of this polishing effect can be attributed to the selective ablation and vaporization of surface asperities under the optimized parameters—this process not only effectively reduces the peak-to-valley height difference of the surface (reflected in the synchronous improvement of Sa and Sz) but also minimizes the risk of thermal damage by precisely controlling the thermal input and avoiding localized energy accumulation (enabled by the equal overlap rate constraint in dual directions). These findings not only provide critical experimental evidence and theoretical references for deepening the understanding of parameter coupling effects and material removal mechanisms in the FLP of AM metallic materials but also offer essential parameter optimization strategies and preliminary technical support for the engineering application of FLP technology in two key areas: the surface treatment of high-performance alloys (e.g., Fe-Ni-Cr-based alloy steels) and the post-processing of complex AM components. Future research will build on this work to further explore the coupling optimization of additional parameters (e.g., scanning strategy, laser incident angle) and integrate numerical simulation methods (e.g., finite element analysis of laser-material interaction) to gain a more in-depth understanding of the FLP mechanism. Furthermore, the results of this study hold broad application prospects in the surface post-processing of laser-based high-energy beam metal processing, particularly in the on-site in-situ repair and surface polishing of non-detachable or difficult-to-detach components, and are expected to generate significant social and economic benefits.
  • HUANG Zhiquan, LI Changjiu, HE Dingyong, CHEN Xi, ZHAO Junjun, GAO Zhanqi, WANG Chongyang
    China Surface Engineering. 2026, 39(1): 275-297. https://doi.org/10.11933/CSE2026023
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    Overlaying and thermal spraying, core technologies in modern material surface engineering, have been indispensable in industrial manufacturing and equipment restoration since the 20th century. However, accelerated industrialization has imposed increasingly stringent demands on material surface properties—such as wear resistance, corrosion resistance, and high-temperature resistance—in sectors including machinery, energy infrastructure, and aerospace, exposing the limitations of conventional overlaying and thermal spraying techniques in addressing material protection and functional enhancement under complex operational conditions. By reviewing the integration and evolution of overlaying technology within surface engineering, this article highlights key advancements and applications in both fields over the past decade while outlining their developmental trajectories. Technological advancements in materials, processes, and equipment in the field of overlaying technology have been systematically summarized using various methods. These include arc surfacing techniques, such as shielded metal arc surfacing, submerged arc surfacing, gas metal arc surfacing, self-shielded arc surfacing, tungsten inert gas surfacing, and cold metal transfer surfacing; high-energy beam surfacing approaches like plasma arc surfacing and laser cladding; and specialized surfacing technologies such as oxy-acetylene surfacing. Although traditional high-chromium iron-based wear-resistant flux-cored wires remain mature for engineering applications, recent efforts have prioritized cost-effective high-boron iron-based alternatives. Nickel-based, cobalt-based, and metal-ceramic composites continue to dominate material research, with high-entropy alloys (HEAs) emerging as focal points in laser cladding. Process studies emphasize the optimization of parameters such as current, speed, and powder / wire feeding rates, along with auxiliary techniques such as ultrasound, magnetic fields, and heat treatment, to enhance the layer microstructure and performance. Advancements in overlaying equipment have primarily focused on enhancing the efficiency, quality, and precision of the surfacing processes. Additionally, the article provides a detailed overview of the practical implementation of surfacing technology across industries such as petrochemicals, cement and mining, metallurgical and power generation, agricultural and forestry machinery, aerospace, medical devices, and nuclear energy. Current research in the field of thermal spraying focuses on technologies such as cold spraying, plasma spray-physical vapor deposition, suspension plasma spraying, and detonation spraying, each with distinct priorities. Cold spraying focuses on theoretical research, development of high-performance equipment, standardization of raw materials, and optimization of coating performance. Plasma spray physical vapor deposition concentrates on optimizing process parameters, such as powder feeding rate, plasma gas composition, and spraying distance, to regulate coating growth patterns and microstructures with the aim of achieving high-performance coatings. Suspension plasma spraying explores the fabrication of high-performance thermal barrier oxide ceramic coatings. The development of high-frequency focused-energy detonation spraying technology has resulted in an order-of-magnitude improvement in efficiency and significantly enhanced coating quality. Additionally, the applications of thermal spray coatings, including wear resistance, thermal barriers, corrosion resistance, and functional coatings, are summarized. Regarding the future development trends of overlaying and thermal spraying technologies, it points out that high-end equipment overlaying materials, composite overlaying technology, as well as the automation, intelligence, and flexibility of overlaying processes will be the future development directions for overlaying technology. For thermal spraying technology, the development of new materials, novel processes, and improvements in the coating density remain key advancement priorities. These findings provide theoretical support and directional guidance for the technological evolution and industrial applications of overlaying and thermal spraying technologies.
  • DUAN Junbiao, GUO Weiling, MA Guozheng, JIN Guo, TIAN Haoliang, WANG Haidou
    China Surface Engineering. 2026, 39(1): 298-312. https://doi.org/10.11933/CSE2026024
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    Components in high-end equipment fields (such as aerospace, energy and power, and marine engineering) face high-temperature oxidation, corrosion wear, particle erosion, and other composite failure mechanisms. Traditional thermal spraying and laser cladding technologies significantly reduce the bonding strength and service life of coatings owing to phase transformation, oxidation, and residual stress problems caused by the high heat input. Although cold spraying technology can reduce thermal damage, it is difficult to achieve effective kinetic energy deposition of high-melting-point materials and its cost is high, which restricts its industrial application. Laser-assisted cold spraying (LACS) is an advanced material deposition technology that innovatively integrates laser and cold spraying systems. This technology utilizes the synergistic effect of the heat input of a laser and kinetic energy of cold spraying, in which a laser beam preheats the substrate to the critical temperature of plastic transformation and reduces the yield strength of the material. Cold-sprayed particles impact and soften the substrate under the acceleration of a supersonic airflow and achieve plastic deformation through adiabatic shear instability. This leads to the formation of dense metallurgical bonding, which significantly improves the deposition efficiency and coating quality of the material and meets its multifunctional application requirements. In this paper, the review of the research progress of LACS is presented in terms of the principle, advantages, and spraying material range of this technology. The application of LACS in the preparation of multifunctional coatings is considered, including high-thermal conductivity / electrical conductivity material, high-strength / high-hardness metal material, metal matrix composite coatings, and biomedical material coatings. In the paper, the composition of a LACS system and synergistic mechanism of the sprayed particles and heated gas are clarified. Using LACS, a stable and controllable phase structure is obtained by adjusting the laser power, cold-spraying gas pressure, temperature, and type, which avoids the oxidation, heat input, and composition segregation caused by traditional thermal spraying and laser cladding technologies. Simultaneously, the heating softening effect of the laser promotes secondary compaction of the deposited layer by the subsequent spraying of particles, effectively eliminates the interlayer pores, and improves the compactness of the coating. Compared with cold spraying technology, the introduction of a laser reduces the critical deposition rate of the sprayed particles, and compressed air and nitrogen can be used to replace the more expensive helium, which significantly reduces the system cost. LACS technology can overcome the limitations of high-hardness and low-plasticity materials deposited by cold spraying technology and improves the wear resistance, corrosion resistance, electrical and thermal conductivity, and biocompatibility of materials. Finally, the research status and future development trends of LACS technology are summarized and discussed. LACS technology provides highly reliable and economical surface-strengthening solutions for key components of high-end equipment by adjusting the parameters to control the damage caused by the heat input, thereby expanding the material deposition range and reducing the system cost. Current LACS systems primarily integrate cold-spray gun nozzles with laser beam delivery. However, the existing equipment varies widely in type and cost, and comparative data on material deposition efficiency are lacking. Therefore, the design and development of cost-effective equipment needs to be continuously explored. In addition, LACS has successfully prepared single-function coatings (e.g., wear-resistant, corrosion-resistant, oxidation-resistant, and conductive). However, multifunctional composite coatings remain to be developed. The deposition mechanism of LACS remains to be further explored and can be verified by numerical simulations. Finally, the regulation of the significant temporal discrepancy between the laser action duration and cold-spray particle deposition timing and laser reflection effect of in-flight particles also constitutes critical focus areas. This detailed discussion of LACS technology aims to promote its application and provide guidance for protecting parts operating in harsh service environments in the high-end equipment field.
  • YAO Xinyu, ZHANG Zhiqiang, ZHU Lina, DU Yin, YU Ziming, LU Xuecheng, ZHANG Tiangang
    China Surface Engineering. 2026, 39(1): 313-325. https://doi.org/10.11933/CSE2026025
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    The service performance of laser-cladded coatings on titanium alloy surfaces is often compromised by high residual stresses and defects such as cracks. Ti6Al4V (TC4 titanium alloy) is widely recognized for its exceptional strength-to-weight ratio and corrosion resistance, which make it a critical material for aerospace, biomedical, and marine applications. However, its relatively low surface hardness and poor wear resistance often lead to premature failure in tribological environments, significantly limiting the service life of critical components such as aircraft landing gears, engine parts, and biomedical implants. To address these limitations, laser cladding has emerged as an advanced surface-modification technique that enables the deposition of metallurgically bonded coatings with superior mechanical and tribological properties. Recent studies have demonstrated that incorporating rare-earth oxides, particularly Y2O3, can further enhance the coating quality by refining the microstructure, reducing defects, and improving wear and corrosion resistance. These improvements are crucial for extending component durability under extreme operational conditions such as high-temperature and high-stress aerospace environments. Despite these advancements, the influence of Y2O3 addition on the microstructure and performance of Ti6Al4V / NiCr-Cr3C2 / Ni-MoS2 composite coatings remains insufficiently explored, particularly regarding the interplay between the Y2O3 content and coating integrity. This study systematically investigated the effects of varying Y2O3 content (0 wt.%, 2 wt.%, 4 wt.%, and 6 wt.%) on the formation quality, microstructure, mechanical properties, and corrosion behavior of laser-clad coatings. The coatings were fabricated on Ti6Al4V substrates using coaxial powder-feeding laser cladding with fixed ratios of NiCr-Cr3C2 (20 wt.%), Ni-MoS2 (30 wt.%), and Ti6Al4V (balance). The optimized laser cladding parameters were a laser power of 1 500 W, scanning speed of 6 mm / s, spot diameter of 3 mm, and powder feed rate of 0.6 r / min. These parameters were selected based on preliminary trials to ensure optimal melting and bonding while minimizing thermal distortion. Coating characterization involved penetrant testing for crack detection, X-ray diffraction (XRD) for phase analysis, scanning electron microscopy (SEM) for microstructure evaluation, and electron probe microanalysis (EPMA) for elemental distribution. The mechanical properties were assessed via microhardness testing, dry friction-wear experiments, and electrochemical corrosion tests in a 3.56 wt.% NaCl solution to simulate harsh marine and aerospace environments. The results indicated that the optimal Y2O3 addition (4 wt.%) significantly improved coating formation quality, achieving complete crack elimination and minimal porosity (0.23%). This enhancement is attributed to the role of Y2O3 in optimizing the energy absorption of the molten pool, regulating the solidification behavior, and reducing the residual stress. Furthermore, Y2O3 refines the grain structure, producing a gradient microstructure with coarse dendrites in the upper regions and fine dendrites mixed with spherical phases in the lower regions, along with a more uniform distribution of TiC-reinforcing phases. Although the 4 wt.% Y2O3 coating exhibited a slightly lower average microhardness (420 HV10) compared with the Y2O3-free coating (540 HV10), it demonstrated superior wear resistance, with a reduced friction coefficient (0.41) and significantly lower wear rate (7.04 × 10-4 g / (N·h)). Electrochemical testing verified that the 4 wt.% Y2O3 coating possesses optimal corrosion resistance, demonstrating a corrosion potential of - 0.201 V and corrosion current density of 1.229×10-9 A. In summary, the 4 wt.% Y2O3 coating exhibits the best overall performance in terms of formation quality, microstructure, wear resistance, and corrosion resistance. This paper provides key insights into the role of Y2O3 in enhancing Ti6Al4V-based composite coatings, with the following contributions: (1) identification of the optimal Y2O3 content (4 wt.%) for achieving crack-free, low-porosity coatings; (2) demonstrating the effectiveness of Y2O3 in refining microstructure and promoting uniform TiC distribution; (3) a comprehensive evaluation of the synergistic of Y2O3 effects on wear and corrosion resistance. The findings established clear processing-structure-property relationships, confirming that 4 wt.% Y2O3 yields coatings with an optimal balance of hardness, toughness, wear resistance, and corrosion resistance. Future research should explore its long-term performance under cyclic loading and elevated temperatures to validate its industrial applicability. These results provide a scientific foundation for designing advanced surface-engineered titanium alloys with extended service lives, particularly for aerospace applications in harsh environments.
  • HAN Heng, WANG Hai, WANG Rui, WANG Haidou, SUN Xiaofeng, MA Guozheng, LI Zhanming, ZHAO Haichao
    China Surface Engineering. 2026, 39(1): 326-346. https://doi.org/10.11933/CSE2026026
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    Laser surface texturing (LST) has emerged as a pivotal non-contact surface pretreatment technique that can significantly enhance the interfacial bonding strength and functional performance of coatings applied via thermal spraying and other deposition methods. Despite its advantages, including high precision, efficiency, flexibility, and environmental friendliness, the broader application of LST is hindered by the complexity of parameter selection, diversity of material responses, and a lack of comprehensive understanding of the correlation between textured morphology and interfacial reinforcement mechanisms. This review systematically addresses these challenges by collating recent advancements in LST-based surface engineering, with a focus on the modulation of surface topography and its consequent effects on coating adhesion, wettability, and tribological properties. The methodology of this review involves a critical analysis of experimental and numerical studies on laser-textured surfaces across various metallic and ceramic substrates. Key process parameters such as laser power (50-150 W), scanning speed (100-500 mm / s), pulse duration (nanosecond to femtosecond regimes), and geometric patterns (continuous vs. discrete textures) are evaluated for their influence on surface characteristics, including roughness, texture depth, and spatial distribution. Advanced characterization techniques, such as confocal microscopy, X-ray diffraction, and scratch testing, have been employed to quantify coating adhesion and performance. If surface texture technology is used to process the surface interface geometry through reasonable design, the two important factors of the surface and interface can be accurately controlled, that is, the surface interface of the coating can be textured to control the deposition behavior of the coating on the substrate surface. The stability of the macro-service performance of the coating can be controlled precisely and effectively by improving the surface roughness, bonding strength between the coating and substrate, and fatigue resistance of the coating surface. As a pretreatment method, laser texturing can improve the bonding strength of the coating on the surface of a material and can profoundly affect the friction properties, corrosion resistance, etc. of the material surface. Only a few studies have been conducted in this area. The results demonstrate that optimized laser texturing can increase surface roughness (Ra) from initial values of approximately 0.5 μm up to 4 μm, thereby providing enhanced mechanical anchoring sites for coating deposition. This leads to a remarkable improvement in the coating-substrate adhesion strength, with reported increases ranging from 40% to 80%. Furthermore, specific texture geometries, such as sinusoidal patterns and micro-dimples with optimal depth-to-diameter ratios (e.g., D / L≈1.2-1.5), significantly promote the spreading and anchoring of molten droplets during thermal spraying, reducing defects such as porosity and incomplete filling. The interplay between surface morphology and wetting behavior is also elucidated, showing that LST can tailor the surface energy and achieve superhydrophobic or superhydrophilic states, which further contribute to corrosion resistance and anti-fouling performance. In conclusion, this review establishes a multi-scale framework that links laser parameters, energy absorption, surface topography, and functional coating properties. The key innovation of this work lies in the integration of dispersed research findings into a coherent model that elucidates the underlying mechanisms, such as mechanical interlocking, interfacial stress distribution, and thermodynamic interactions, that govern coating adhesion on textured surfaces. By identifying the optimal process windows and texture design principles, this paper provides a scientific basis for the precise control of coating integrity and durability. This review fills a critical gap in the literature by offering a systematic reference for applying LST in industrial applications such as aerospace, marine, and automotive engineering, where high-performance coatings are essential. It critically examines the potential applications of laser texturing pretreatment technology in thermal spray coating processes and proposes future research directions for technological development. The analysis provides theoretical guidance and technical reference for advancing laser-based surface engineering applications in advanced manufacturing.
  • ZHU Lindan, XIAO Huaqiang, REN Lirong, ZHANG Zhengwen, MO Taiqian, LIN Bo, FU Guang
    China Surface Engineering. 2026, 39(1): 347-359. https://doi.org/10.11933/CSE2026027
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    Under extreme service conditions, the surface stability of titanium alloy moving components in high-temperature oxidizing environments—particularly in water vapor atmospheres—remains insufficient, posing a critical bottleneck to their application in aerospace hot-end components. Although surface modification is widely recognized as an effective approach to enhance high-temperature service performance, traditional single-process fabrication techniques exhibit inherent limitations. MAX-phase coatings, owing to their unique nanolayered crystal structure and the combined advantages of metallic and ceramic characteristics, demonstrate great potential for high-temperature protection. However, conventional preparation methods, such as single-step laser cladding, often encounter thermal decomposition of the MAX phase, while subsequent conventional furnace heat treatment suffers from low efficiency and a large heat-affected zone. Therefore, in this work, a two-step approach combining laser cladding and laser heat treatment is employed to fabricate Ti-Al-N MAX-phase composite coatings on Ti-6Al-4V (TC4) substrates. First, a cladding layer is fabricated using a mixture of TiAl and AlN powders as raw materials via laser cladding. Subsequently, the laser heat treatment parameters—including laser power (0.8-1.2 kW) and scanning speed (1-3 mm / s)—are precisely regulated to systematically investigate the microstructural evolution, hardness distribution, and high-temperature steam oxidation mechanisms of the coatings before and after heat treatment. Finally, the microstructure and steam oxidation morphology of both the as-cladded and heat-treated coatings are characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD), while X-ray photoelectron spectroscopy (XPS) is employed to analyze the oxidation products formed on the coating surface after steam oxidation. XRD and SEM analyses show that the laser-cladded coating (T1, 1.8 kW / 2 mm·s-1) is primarily composed of dendritic TiN reinforcement phases and a TixAly intermetallic matrix phase, with only a small amount of Ti2AlN phase present. After laser heat treatment, the coating microstructure undergoes a pronounced transformation. When the processing parameters are optimized to a laser power of 1.2 kW and a scanning speed of 2 mm·s-1 (TA4 coating), the microstructure is dominated by acicular and fine strip-like Ti2AlN phases, accompanied by a small fraction of blocky TiN phases. This transformation is attributed to a laser-induced intercalation reaction mechanism, in which the gradient diffusion of Ti and Al atoms during heat treatment promotes the evolution of TiN phase boundaries, resulting in the formation of a large amount of Ti2AlN MAX phase. The lattice evolution is primarily governed by the laser energy density, with the influence of laser power being more significant than that of scanning speed.
    Microhardness measurements show that the surface hardness of all coatings is significantly higher than that of the substrate. However, due to the layered microstructure, hardness exhibits fluctuations, ranging from 521.27 HV to 701 HV. In particular, the heat-treated coating displays a gradient in hardness (521.27-701 HV) due to the coexistence of the softer Ti2AlN phase (521.27 HV) and a small amount of hard TiN phase (692.2 HV), yet its average hardness remains 1.47 times that of the substrate. High-temperature steam oxidation tests are conducted with the TC4 substrate as a control to evaluate the oxidation behavior of both the as-cladded T1 coating and the heat-treated TA4 coating, which possess a more uniform microstructure enriched with Ti2AlN. The tests involve continuous oxidation at 900 °C for 50 hours, and the resulting surface morphology and cross-sectional structure of the oxide scale are analyzed. SEM and XRD analyses show that the oxide film formed on the TC4 substrate is primarily composed of porous TiO2 with a thickness of 161.16 μm, whereas the T1 and TA4 coatings develop TiO2 / Al2O3 bilayer oxide films, with thicknesses reduced to 35.66 μm and 29.01 μm, respectively (the TA4 oxide film thickness is only 18% that of the substrate). Notably, the TA4 coating, enriched in the Ti2AlN phase, continuously releases Al at high temperatures to form a dense Al2O3 oxide layer (XPS binding energy 74.50 eV), which effectively inhibits inward diffusion of oxygen ions and outward diffusion of Ti, thereby significantly enhancing the oxidation resistance. Cross-sectional SEM and EDS analyses of the oxide films on the substrate, T1, and TA4 coatings show that in a steam environment, hydroxyl ions—acting as the dominant defect species—accelerate the initial oxidation due to their small size and high diffusivity, promoting the growth of the oxide layer. However, the continuous dense Al2O3 oxide film facilitated by the Ti2AlN phase effectively blocks further diffusion of H2O into the coating interior, markedly reducing the oxide film thickness and significantly enhancing the high-temperature steam oxidation resistance of the coating-substrate system.
    This study elucidates the regulatory mechanism of laser energy density on the in situ synthesis of the MAX phase and demonstrates that laser heat treatment effectively increases the Ti2AlN content in the coating. SEM and XRD analyses show that the highest Ti2AlN phase content is achieved at a laser power of 1.2 kW and a scanning speed of 2 mm·s-1. Moreover, after steam oxidation, the oxide film thickness of the TC4 substrate is found to be 4.53 and 5.56 times greater than those of the T1 and TA4 coatings, respectively, thereby highlighting the enhanced high-temperature steam oxidation resistance of the TC4 substrate. Consequently, these findings provide a theoretical basis for the high-temperature protection of titanium alloy components in aerospace power systems.
  • HUANG Kening, WANG Rui, ZHANG Qing, ZHAO Haichao, QIAO Yulin, MA Guozheng, WANG Haidou
    China Surface Engineering. 2026, 39(1): 360-374. https://doi.org/10.11933/CSE2026028
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    During the service life of materials, protective paint layers inevitably undergo degradation processes such as weathering, aging, and crack formation. These phenomena significantly reduce the corrosion resistance and functional performance of the coating system, necessitating periodic removal and recoating operations. Traditional paint-stripping technologies, including chemical solvents, mechanical abrasion, and thermal methods, face critical limitations in modern industrial contexts. Chemical agents often generate hazardous waste streams containing volatile organic compounds and heavy metals, while mechanical approaches like sandblasting can cause substrate deformation and microstructural damage. Thermal techniques introduce risks of heat-induced material degradation. These shortcomings highlight the urgent need for innovative solutions that balance environmental sustainability with technical performance.Laser cleaning technology has emerged as a transformative solution, offering inherent advantages in precision, safety, and environmental compatibility. The core principle involves directing focused laser radiation onto the coating-substrate interface, where energy absorption triggers physical-chemical interactions. This non-contact process enables selective removal of contaminants without compromising the underlying material. Over the past three decades, significant advancements have been made in optimizing laser parameters to achieve industrial-scale implementation. Key operational parameters(laser power, pulse width, and wavelength)have interconnected effects that critically influence cleaning efficiency and surface integrity. The interaction mechanisms during laser cleaning involve multiple physical phenomena. At the micro-scale level, rapid heating induces differential thermal expansion between the coating and substrate, generating interfacial stress that facilitates delamination. Simultaneously, photothermal effects cause localized vaporization of organic binders, creating gas bubbles that assist in mechanical detachment. In high-power regimes, plasma formation at the irradiation spot generates shock waves that propagate through the coating layer, enhancing the cleaning efficiency through acoustic cavitation. Real-time monitoring systems play a crucial role in ensuring process stability and quality control. Advanced techniques include in-situ optical emission spectroscopy for plasma diagnostics, high-speed imaging to track ablation dynamics, and infrared thermography for temperature gradient analysis. These monitoring tools enable dynamic adjustment of laser parameters, maintaining consistent cleaning performance across varying material conditions. The impact of laser treatment on the substrate requires careful characterization. While laser cleaning avoids the abrasive wear associated with traditional methods, improper parameter selection can still lead to surface roughening or microstructural changes. The technology has found widespread applications across critical industrial sectors. In aerospace engineering, it enables precise removal of anti-icing coatings from aircraft surfaces without damaging composite structures. Marine industries utilize laser cleaning for hull maintenance, effectively eliminating biofouling and corrosion products from ship exteriors. Cultural heritage conservation has also benefited from this technology, with successful applications in the restoration of historical monuments and archaeological artifacts. Emerging applications include semiconductor manufacturing for photoresist removal and biomedical device processing for sterilization of implantable devices. Furthermore, it highlights current applications of laser paint removal in fields such as aerospace, marine vessels, and daily life. Finally, future development directions for laser paint removal technologies are proposed.
  • DONG Yueze, ZHANG Zhiqiang, WANG Wenyu, LU Xuecheng, ZHUO Shuai, ZHANG Ziyan
    China Surface Engineering. 2026, 39(1): 375-392. https://doi.org/10.11933/CSE2026029
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    Porosity is regarded as one of the most prevalent and challenging metallurgical defects encountered in the wire arc additive manufacturing of aluminum alloys. It is primarily induced by gas entrapment, such as hydrogen inclusions, or by solidification shrinkage occurring during the complex thermal cycles of the layer-by-layer deposition process. Macroscopically, porosity is manifested as small voids located either within the bulk material or on the surface of the fabricated parts. These voids compromise structural density and lead to a notable reduction in mechanical strength, corrosion resistance, and fatigue life. Consequently, the presence of porosity restricts the broader engineering application of WAAM-fabricated aluminum components, particularly in aerospace, automotive, and marine industries, where structural integrity and performance reliability are critical. A comprehensive understanding of porosity in aluminum alloy WAAM is established by addressing four main aspects: the mechanisms of pore formation and evolution, process parameters used for porosity regulation, auxiliary field-assisted inhibition strategies, and the effects of porosity on final component performance. The mechanisms of porosity evolution are categorized into hydrogen-induced pores and shrinkage pores. Hydrogen pores are typically formed through a dynamic sequence comprising nucleation, growth, detachment from the molten pool, and either escape or entrapment in the solidifying metal. Sources of hydrogen include moisture in the atmosphere, contamination on the feedstock wire, and residual water vapor in the shielding gas. Due to rapid solidification, hydrogen is often retained in the metal matrix. Shrinkage pores, in contrast, result from insufficient feeding of liquid metal during the terminal stages of solidification, especially under geometric restrictions or high thermal gradients. These mechanisms are driven by differences in hydrogen solubility between solid and liquid phases and are influenced by melt pool dynamics, surface tension gradients, and thermal distribution within the deposition layers. Porosity regulation is achieved through adjustments in multiple process variables. Alloy composition is optimized through the incorporation of nanoparticles, rare-earth elements, or fine-tuned element ratios, which reduce hydrogen solubility and promote melt pool stability. Arc modes such as Cold Metal Transfer (CMT), CMT+P (pulsed), and CMT-ADV (advanced) are selected to improve droplet transfer control and stabilize heat input, thereby minimizing melt pool disturbance. Heat input is further regulated by altering the wire feed rate, travel speed, or implementing hot wire techniques, all of which contribute to consistent energy input and refined solidification behavior. Protective gas composition, including binary or ternary mixtures, is also adjusted to influence hydrogen pickup and arc behavior, ultimately affecting pore formation. Porosity suppression is further enhanced through the application of auxiliary physical fields. Magnetic field-assisted techniques modify arc shape and improve fluid flow in the melt pool, contributing to better gas bubble transport and elimination. Ultrasound-assisted WAAM promotes hydrogen degassing and improves metal wetting, facilitating the escape of gas before solidification. Laser-assisted hybrid processes offer localized thermal input, facilitating defect healing and reducing pore retention. Additional post-deposition and in-situ methods such as stirred friction machining, interlayer friction stirring, synchronized hammer forging, hot isostatic pressing (HIP), and composite field-assisted technologies are employed to refine the microstructure, improve interlayer bonding, and encourage gas escape, thus minimizing porosity. Porosity significantly degrades the performance of WAAM components. Internal voids act as stress concentrators and initiation sites for cracks, lowering tensile strength and fatigue resistance. Furthermore, exposure of internal surfaces accelerates corrosion by enabling pathways for environmental penetration. Synergistic regulation strategies, which integrate multiple control approaches, are increasingly adopted to suppress porosity more effectively. Nevertheless, technical challenges remain, including the absence of real-time control mechanisms, limited understanding of interlayer remelting phenomena, and the complex interactions between process parameters and metallurgical responses. Future development is expected to focus on intelligent process control using real-time molten pool monitoring, artificial intelligence-driven feedback systems, and functional porosity design to customize material performance for specific engineering requirements.
  • GAO Chong, DONG Lihong, LIU Bin, JIN Xin
    China Surface Engineering. 2026, 39(1): 393-401. https://doi.org/10.11933/CSE2026030
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    Thin-walled stiffened structures have been widely adopted in the aerospace field as key airtight components in high-end carrier equipment. With the increasing demand for reduced structural weight and increased lifespan in aerospace equipment, the development of methods and processes to improve the fatigue life of thin-walled stiffened structures has posed a considerable challenge. To that end, ultrasonic impact treatment (UIT) improves fatigue life by introducing a gradient structure and a residual compressive stress field. Although this approach has been applied in the field of complex structural engineering, to the best of our knowledge, no previous methods have been developed to apply it to strengthen thin-walled stiffened structures. In this study, we investigated a thin-walled stiffened structure of 5B70-H32 aluminum alloy to explore processes and parameters to improve the fatigue life of the structure. Thus, we conducted fatigue tests of samples that were untreated as well as samples with 300%, 400%, and 500% ultrasonic impact coverage. The results showed that the fatigue life of the sample treated at the 400% level increased the most, and was approximately 45% higher than that of an untreated sample. The morphology of fractures caused by ultrasonic impact coverages of 300% and 400% was characterized by the initiation of subsurface cracks caused by the residual compressive stress as well as a gradient microstructure. When the coverage was increased to 500%, the fractures exhibited an obvious layered morphology due to the cumulative effects of ultrasonic impacts. The ultrasonic treatment destroyed the subsurface structure, which also led to a large dispersion in fatigue life and a decrease in the average life. The cracks significantly bypassed the boundaries of the second-phase particles during the propagation process, with cracks exhibiting a typical bypassing morphology. This phenomenon demonstrates that the second-phase particles hindered the process of crack propagation, that is, there was a second-phase pinning effect. The dimple morphology of the instantaneous fracture zone was obvious, and the size of the dimples was up to nearly 40 μm. The broken second-phase particles were observed in the local dimples. We analyzed the roughness of the crack initiation, propagation, and instantaneous fracture zones of the specimens before and after strengthening by using an Olympus LEXT OLS4000 three-dimensional laser confocal microscope. The results show that roughness increased from 55.7 µm (base metal) to 69.8 µm (UIT) within 500m of the source area of the cracks. The distance from the point where a crack was initiated was 1 000 μm (stable propagation zone), the fluctuation of base metal was approximately 54.9 μm, and the fluctuation of ultrasonic impact fracture was approximately 83.6 μm. The roughness increased significantly in the rapid expansion zone due to its proximity to the tear zone while the fluctuation of the base metal increased to 89.7 μm and the fluctuation of the ultrasonic impact fracture increased to 142.3 μm. The influence of ultrasonic impact on the crack propagation path was evident from the varying roughness of the cracks. According to the theory of roughness-induced closure, the repeated grain-boundary interactions increase the roughness of the crack section during the propagation process, which reduces the speed of propagation and improves fatigue life. Electron backscatter diffraction (EBSD) was used to characterize the grains at the tip of the crack in the strengthened layer, and we found that the fracture mode was primarily transgranular. The average grain size of the gradient fine-grained layer introduced by UIT was refined from 1.74 μm to 1.23 μm through ultrasonic strengthening to promote grain refinement between the surface layer and the rolled grains. The observed crack deflection and crack branch morphology were caused by the interaction between the tip of the crack and the nonuniform grain structure, which was caused by the gradient refinement of the nonuniform grain structure produced by UIT to provide more paths for crack deflection and branching. These microstructures can effectively improve the fracture toughness of materials by preventing crack propagation and reducing the driving force of crack propagation. Crack turning in the grains occurred mainly at the low-angle grain boundaries. The dense low-angle grain boundaries were introduced by ultrasonic impact, and turning and branching of the propagating cracks were primarily caused by different turning of the cells on both sides of low-angle grain boundaries. A large plastic field appeared in front of the tip of the cracks, which is attributed to the residual compressive stress field introduced by UIT. The residual compressive stress field enhanced the plastic deformation field in the strengthening layer, which resulted in grain rearrangement in the crack-tip region and the formation of high-angle grain boundaries. Ultrasonic impact strengthening promotes grain refinement, dislocations, grain boundaries, and second phases and increases adjacent grains of different orientations, which promotes crack deflection and branching while delaying propagation. Thus, our findings demonstrate the applicability of ultrasonic impact strengthening to thin-walled reinforced structures and lay a theoretical and experimental foundation for the large-scale implementation of ultrasonic impact strengthening of such structures.
  • MA Biao, FANG Jinxiang, HE Haotian, HOU Yujie, WANG Yanli, HE Peng
    China Surface Engineering. 2026, 39(1): 402-416. https://doi.org/10.11933/CSE2026031
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    Ultra-high strength steels are typically characterised by high strength, high toughness and high hardenability. Due to their excellent comprehensive mechanical properties, they are often used in high-strength structural components such as aircraft engine crankshafts, landing gears, and rocket shells. They are also used in the manufacture of key important components that withstand harsh loads in heavy machinery, including torsion shafts, and gearbox shafts. Ultra-high strength steels usually have low damage tolerance and high surface defect sensitivity, and their service conditions are harsh. So, many components belong to low-cycle fatigue parts, and their service reliability and life are worse than those of low strength materials. For example, 45CrNiMoVA ultra-high strength steel torsion shaft, which is subjected to cyclical torsional loads during service, the maximum load is located on the surface of the material. Therefore, fatigue cracks can easily initiate on the surface, resulting in fatigue failure. Ultrasonic Surface rolling treatment can improve the fatigue performance of mechanical components. For conventional high-plastic materials, the fatigue life is often increased by nearly 10 times, while for ultra-high strength steel, the fatigue life is limited. Under low-cycle fatigue loading, the beneficial effects of the ultrasonic surface rolling process on ultra-high strength steel degraded. In particular, the surface roughness was seriously degraded, and stripes with the genetic characteristics of turning traces appeared, which significantly reduced the fatigue life. This study first discussed the degradation of the ultrasonic surface rolling effect under low-cycle fatigue loading. The stress and strain distribution in the near-surface region of the ultrasonic surface rolling specimen was analyzed by the finite element method. It was found that there were significant stress and strain inhomogeneities associated with turning marks on the surface of the turning sample after ultrasonic surface rolling. Under low-cycle fatigue loading, the strain and stress inhomogeneity of the surface structure would induce the appearance of surface stripes related to turning marks. The increase of surface roughness is beneficial to the initiation of fatigue crack, which is the main factor affecting the improvement of fatigue life. Then, the effect of re-apply ultrasonic surface rolling treatment on the low-cycle torsional fatigue behavior and mechanism of 45CrNiMoVA ultra-high strength steel was investigated. After ultrasonic surface rolling treatment, the roughness of the as-machined specimen decreased from Ra 937 nm to Ra 94 nm. However, under the torsional fatigue loading, micro-cracks with turning marks characteristics appeared on its surface. Compared to the as-machined specimen, the low-cycle torsional fatigue life increased approximately 5 times after ultrasonic surface rolling treatment, exceeding 200 000 cycles. After re-applying ultrasonic surface rolling treatment, the specimen did not break after 900 000 cycles, which was 19.65 times higher than that of the as-machined specimen. Compared with the USRP specimen, the life was increased by about 3.33 times. After re-applying ultrasonic surface rolling treatment, the stress / strain uniformity of the sample surface was improved, and the surface roughness showed extremely high stability under low-cycle fatigue loading without obvious roughening, which is the core mechanism of the improvement of low-cycle torsional fatigue life by re-applying ultrasonic surface rolling treatment. In addition, after re-applying ultrasonic surface rolling treatment, the strength of the gradient structure and residual compressive stress level were restored, and the relaxation rate of residual compressive stress was significantly reduced due to the improved surface stress and strain uniformity. These mechanisms also contribute to the improvement of low-cycle fatigue life. The Re-apply ultrasonic surface rolling treatment can well inhibit the deterioration of the surface roughness of the specimens during fatigue loading, and provide the specimens a prominent fatigue life. This study has reference significance for the life improvement and extension of ultra-high strength steel low-cycle fatigue parts.
  • QIU Xinguo, ZHOU Yu, PIAO Zhongyu, ZHOU Zhenyu
    China Surface Engineering. 2026, 39(1): 417-431. https://doi.org/10.11933/CSE2026032
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    A systematic investigation was conducted to examine the effect of rolling pretreatment on the carburizing behavior of low-carbon steel 20CrMnTi. The study is motivated by the increasing demand for high-performance materials in engineering applications and the limitations of traditional carburizing processes. Conventional methods often result in uneven surface roughness and coarse grain structures, leading to nonuniform carburized layer depths and hardness distributions, which restrict material performance in critical applications. To address these deficiencies, rolling pretreatment was applied to improve surface quality and refine grain structure, thereby increasing the density of fast diffusion channels, such as grain boundaries. This study investigates the influence of rolling pretreatment on the microstructure, surface quality, and diffusion kinetics during carburizing, and it provides a theoretical basis for optimizing carburizing processes. In this work, 20CrMnTi cold-drawn bars were normalized at 850 ℃ for 20 min and subsequently machined into cylindrical specimens with reduced diameters. The specimens then underwent rolling pretreatment using a specially designed tool mounted on a CNC lathe. The tool, equipped with a 7 mm diameter tungsten carbide ball, applied controlled compressive forces through varying feed rates and displacements. Rolling parameters were systematically adjusted, with particular emphasis on rolling displacement (Δ), identified as the key parameter influencing surface deformation, grain refinement, and microstructural evolution. Following pretreatment, all specimens were subjected to a carburizing cycle consisting of heat treatment at 930 ℃ for 120 min using a solid carburizing method (90% carbon powder and 10% barium carbonate), quenching at 850 ℃, and tempering at 180 ℃. The experiments were performed under carefully controlled conditions in a box-type electric furnace to ensure isothermal treatment. A series of characterization methods was employed to analyze the effects of rolling pretreatment on the carburized layers. Optical microscopy and scanning electron microscopy were used to observe microstructural changes, while electron backscatter diffraction quantified grain orientation and boundary distributions. Micro Vickers hardness testing and laser confocal microscopy were utilized to measure surface hardness and roughness, respectively. In addition, energy-dispersive X-ray spectroscopy was employed to assess carbon concentration profiles in the carburized layers. Results showed that rolling pretreatment significantly enhanced surface microhardness, with maximum values reaching 250 HV0.05—approximately 51.5% higher than that of conventionally turned specimens. Surface quality also improved markedly, with arithmetic mean height (Sa) reduced from approximately 6.711 μm to 1.943 μm, corresponding to a 70.89% improvement. The depth of the carburized layer increased from 500 μm to 750 μm (a 50% rise), while its overall hardness improved by 11.76% compared with the control group. To elucidate the mechanisms governing carbon absorption and diffusion during carburizing, two kinetic models were developed. First, a modified Langmuir adsorption isotherm was proposed to account for changes in surface characteristics brought about by rolling pretreatment. The maximum adsorption capacity was adjusted by a correction factor that incorporates the variations in grain boundary density and surface roughness. Second, a diffusion kinetics model was established based on Fick’s second law for one-dimensional diffusion, combined with a dual-channel diffusion mechanism that considers both lattice and grain-boundary diffusion. In conclusion, rolling pretreatment effectively refines grain structure and improves surface smoothness in 20CrMnTi steel, thereby enhancing carbon diffusion and adsorption kinetics during carburizing. The resulting improvements in carburized layer depth and microhardness provide valuable insights into process optimization. The proposed kinetic models offer a quantitative framework that links rolling parameters with diffusion behavior and interfacial reactions during carburizing. The findings of this research are of significant importance, as they provide a new theoretical foundation and a practical approach for optimizing carburizing processes, enabling the production of high-performance low-carbon steels with enhanced surface properties suitable for demanding engineering applications.
  • ZHENG Qiuyang, SHI Haohan, JIANG Zhiguo, LIN Xuanyi, LI Gengjun, ZHOU Zhenyu, PIAO Zhongyu
    China Surface Engineering. 2026, 39(1): 432-444. https://doi.org/10.11933/CSE2026033
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    The service reliability of aluminum alloy components is strongly influenced by their near-surface microstructure; however, under high-load and long-life conditions, inadequate surface performance remains a critical limiting factor. To address this issue, an ultrasonic-assisted surface burnishing process (USBP) is introduced. USBP superimposes high-frequency, low-amplitude vibration onto conventional surface burnishing (SBP) and, under the same average load, enables stronger dislocation activation and deeper gradient refinement. This work aims to compare the strengthening responses of USBP and SBP systematically and to elucidate the intrinsic advantages of USBP in terms of energy evolution, dislocation dynamics, stress-field distribution, and crystallographic reconstruction. A hybrid methodology combining molecular dynamics (MD) simulations with comparative experiments is adopted under matched loading conditions. In the simulations, representative near-surface volumes are constructed, and USBP is modeled through periodic normal and tangential vibrations superimposed on a constant contact load. Time-resolved evolution of internal energy, microstructure, and dislocation behavior is tracked, and post-processing using the Dislocation Extraction Algorithm (DXA) is employed to quantify dislocation line length, character, and spatiotemporal evolution. Experimentally, cast aluminum alloys are processed using USBP and SBP under equivalent nominal load and feed conditions. Electron Backscatter Diffraction (EBSD) is used to characterize grain-size gradients, and surface topography measurements quantify roughness and morphological uniformity. A unified statistical protocol is applied to report refined-layer thickness and gradient descriptors, ensuring consistency between simulations and experiments. The results show that the high-frequency stress waves introduced by USBP markedly increase the internal energy in the contact region, facilitating dislocation barrier crossing and significantly promoting dislocation nucleation, glide, and multiplication. As a consequence, the accessible slip pathways across grains of different orientations are broadened, the plastic deformation zone extends deeper into the subsurface, and a finer, thicker gradient nanostructure is established. Simulations further demonstrate that, within the same observation volume, both the dislocation line length and the growth rate of dislocation content remain consistently higher under USBP than under SBP, indicating a higher turnover of dislocation activity and a wider slip influence range. Experiments corroborate these findings: under the same average load, USBP produces lower, more uniform surface roughness, a thicker, more refined layer, and a deeper region of crystallographic reconstruction. Group-wise comparisons demonstrate that merely increasing the burnishing depth in SBP intensifies local plastic deformation but has a limited effect on promoting defect evolution and expanding the plastic zone, and therefore fails to reproduce the gradient refinement achieved by USBP. This contrast highlights the decisive role of high-frequency stress modulation in governing dislocation kinetics and microstructural evolution pathways, rather than relying solely on static deformation amplitude. The advantages of USBP originate from a coupled pathway of “high-frequency stress wave, dislocation activation, defect architecture evolution.” The superposition of stress / strain and velocity pulses on a constant load intermittently elevates the instantaneous resolved shear stress above static thresholds, thereby reducing the effective activation energy and activation volume required for dislocation barrier crossing. The subsequent unloading facilitates depinning and shortens the residence time of dislocations at obstacles, driving rapid cycles of generation, annihilation, and rearrangement, while intermittently activating additional slip systems in grains of various orientations. This dynamic mechanism accelerates sub-grain-boundary formation and dynamic recovery, suppresses premature work hardening, and distributes deformation over a larger subsurface volume, ultimately yielding a thicker, more continuous gradient refined layer and improved surface integrity. The principal conclusions are as follows: (i) USBP achieves deeper gradient refinement and broader plastic-zone expansion than SBP, addressing a key bottleneck in extending the service life of aluminum alloys; (ii) a multi-dimensional, simulation-experiment framework coupling energy evolution, dislocation dynamics, and crystallographic reconstruction is established, enabling mechanism inference beyond post-mortem characterization; (iii) DXA-based metrics of dislocation line length and slip influence range substantiate a dislocation-dominated, dynamically assisted mechanism, rationalizing both the expansion and surface morphology improvement; and (iv) increasing burnishing depth in SBP cannot substitute the dynamic effects of ultrasonic cycling, underscoring the necessity of high-frequency stress modulation in steering defect evolution. In summary, USBP outperforms SBP in surface refinement and gradient strengthening by dynamically assisting dislocations, lowering effective barriers, and expanding the plastic deformation region. These findings provide mechanistic insight and a practical processing route for controllable, efficient surface modification of aluminum alloys, with direct engineering relevance for achieving robust surface integrity and deep, stable gradient structures in high-reliability, lightweight components operating under long-life service conditions.
  • ZHENG Haoran, GUO Weiling, ZHU Hefa, CAI Zhihai, WANG Haidou, XING Zhiguo, LÜ Xiaoren
    China Surface Engineering. 2026, 39(1): 445-458. https://doi.org/10.11933/CSE2026034
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    Tooth pitting is a common gear failure mode that has a significant negative impact on the wear resistance and transmission efficiency, ultimately shortening gear life. In severe cases, it affects the operational efficiency and stability of the entire system. However, existing studies lack experimental data simulating pitting on the tooth surfaces of low-speed, heavy-duty gears under actual working conditions. The purpose of this study is to investigate the specific effect of tooth pitting size on the structural dynamics of low-speed heavy-duty gears made of 20Cr2Ni4A. To achieve this research goal, we first constructed an accurate model of 20Cr2Ni4A low-speed heavy-duty gears using SolidWorks 3D design software. Based on this, this study designed four pitting models of increasing sizes and severity to simulate the progressive development of tooth surface pitting. Subsequently, we imported these models into the transient dynamics analysis module of ANSYS Workbench to systematically analyze the effects of varying pitting areas on key dynamic characteristics such as tooth-face stress, meshing stiffness, and transmission error. The results revealed a close relationship between tooth pitting area and gear dynamics. Specifically, as the pitting area gradually increased, the maximum stress on the tooth surface first rose and then declined. In the case of a small pitting area, the maximum stress on the tooth face rises sharply from 473.06 MPa when there is no pitting to 916.75 MPa, and this sharp increase is primarily caused by stress concentration on the tooth face. With a further increase in the pitting area, the gradually expanding pit causes the stress distribution to become more dispersed, leading to the gradual weakening of the stress concentration, which in turn causes maximum stress on the tooth surface to decrease to 523.91 MPa. In addition to the change in tooth surface stress, the meshing stiffness of the gear shows a decreasing trend with an increase in the pitting area. Compared with the gears without pitting, the meshing stiffness of the No. 1 pitted gear decreased by only 0.35 N·mm-1·μm-1, while the meshing stiffness of the No. 3 pitted gear decreased by 1.23 N·mm-1·μm-1. This result shows that the larger the pitting area, the greater the decrease in meshing stiffness, which poses a serious threat to the transmission performance and load-carrying capacity of the gears. Without considering other influencing factors, the transmission error of the gear increases with an increase in the pitting area. When the short-axis pitting length increases to 6 mm and the long-axis pitting length increases to 15 mm, the influence of pitting extends to the entire gear meshing process, both before and after engagement, which directly affects the transmission accuracy and reliability of the gear. In summary, tooth pitting significantly affects the dynamic characteristics of 20Cr2Ni4A low-speed heavy-duty gears. With an increase in the pitting area, key performance indicators such as tooth stress, meshing stiffness, and transmission error of the gear undergo significant changes, which not only reduce the service life of the gear but also affect the stability and efficiency of the entire transmission system. Therefore, in the design and maintenance of gears, it is extremely important to control and prevent tooth pitting. By studying the relationship between tooth pitting dimensions and gear dynamics, we can better understand the impact of pitting on gear performance and take effective measures to improve gear reliability and extend service life. The above conclusions can provide a theoretical basis for the fault diagnosis and identification of low-speed heavy-duty gears affected by tooth pitting.
  • WAN Jianqiao, SHI Jie, HU Hengning, ZOU Jiali, WANG Yu, CHEN Yi, TANG Zhengqiang, DU Hao
    China Surface Engineering. 2026, 39(1): 459-471. https://doi.org/10.11933/CSE2026035
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    Variations in anion concentration (or vacancies) within multi-principal element ceramic films markedly influence their crystallinity, phase constitution, and the formation of strengthening defects, thereby governing the mechanical properties of the films. This mechanistic pathway enables the tuning of mechanical performance through controlled adjustment of the reactive gas ratio during reactive magnetron sputtering. Herein, a multi-principal element system comprising strong nitride forming elements Hf, Nb and Zr together with the weaker nitride former Mo was selected. By adjusting the fraction of the reactive gas N2 (RN = 0%, 5%, 10%, 15%, 20%, 25%, 32.5%, 42.5%, and 50%) during reactive magnetron sputtering, a series of stoichiometric (HfMoNbZr)1-xNx films were synthesised. An integrated experimental and density functional theory (DFT) approach was used to trace the evolution of crystal structure and its impact on mechanical and tribological properties. Owing to the large disparities in configurational entropy and atomic size, HfMoNbZr alloy films display an amorphous structure with short-range body-centred cubic (BCC) order. Introducing a low nitrogen content (RN=5%) drives a transition from BCC to face-centred cubic (FCC) and improves crystallinity. Increasing nitrogen further (15%≤RN≤20%) strengthens crystallinity and introduces a body-centred tetragonal (BCT) phase based on β-Mo2N, yielding a dual-phase FCC+BCT crystal structure. While at still higher RN, the dual phase collapses back to single-phase FCC. The phase structure of the thin film undergoes a change in preferred orientation, shifting from high-surface-energy (111), (200), (220), and (222) crystal planes to the low-surface-energy (200) plane. The variation in surface energy of the (200) and (111) crystal planes in the FCC crystal with nitrogen content is a key factor influencing this preferred orientation transition. For metallic and low-nitrogen-content films, the (200) plane exhibits higher surface energy, making crystal planes such as (111), (220), and (222) more readily grown. As the N content in the film increases, the concentration of N substitution atoms rises, leading to an increase in the surface energy of the (111) plane. Ultimately, the (200) crystal plane becomes the preferred orientation of the film. The hardness and elastic modulus of the HfMoNbZr alloy film are 6.82±0.33 GPa and 206.12±15.99 GPa, respectively. All nitride films surpass the alloy in hardness, primarily due to the formation of strong Me-N bonds and improved crystallinity. The sub-stoichiometric dual-phase (HfMoNbZr)1-xNx film (RN=20%) achieves optimal mechanical properties, with hardness 29.26±1.35 GPa and modulus 314.27±3.29 GPa, followed by a sharp decline at higher nitrogen contents. DFT confirms that the peak hardness at sub-stoichiometry stems from the combination of strong metal-nitrogen bonding and dual-phase strengthening. While stoichiometric and over-stoichiometric films possess higher population of Me-N bonds, the loss of the dual-phase structure and reduced crystallinity lower the hardness. Correspondingly, the high hardness together with elevated H / E* and H3 / E*2 ratios in the sub-stoichiometric films translates into superior tribological performance with reduced friction and wear. Overall, the decisive role of anion-concentration control in governing the structure, mechanical properties and tribology performance of (HfMoNbZr)1-xNx films is revealed by the combined use of experiment and DFT calculation, and the dual-phase architecture is shown to be a key contributor to enhanced mechanical strength and tribological resistance. These insights provide guidance for structural design and property tailoring in multicomponent alloy ceramic films.
  • ABUDOUWUFU Tushagu, SHU Fengyuan, FU Dejun
    China Surface Engineering. 2026, 39(1): 472-481. https://doi.org/10.11933/CSE2026036
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    Addressing issues such as the use of toxic precursors, high temperature energy consumption, and low ion beam purity in traditional chemical vapor deposition (CVD) and focused ion beam (FIB) technologies, which severely limit the green and high-precision application requirements of metal films in advanced fields such as precision electronics and micro-nano manufacturing, based on the principle of ionic transport in solid electrolytes, a green, mask-free local deposition device for metal films and its supporting process have been developed. Traditional CVD relies on toxic metal-organic precursors (e.g., Cu(hfac)₂), endangering human health and introducing carbon impurities that increase film resistivity. FIB with liquid metal ion sources (LMIS) requires high-temperature alloys (e.g., Cu63.5Ge36.5, melting point 643 ℃) and mass analyzers for ion separation, leading to low efficiency and high costs. As integrated circuits advance to 3 nm nodes, demands for sub-50 nm line width, >99.9% purity, and eco-friendliness remain unmet by current technologies.This device uses a high-purity copper conical working material as the core of the ionic source, combined with a 0.5-1 μm thick high conductivity (greater than 0.1 S / cm at room temperature) solid electrolyte film. Through a 5-15 kV high-voltage electric field to drive the metal ion field-assisted evaporation, it achieves precise focusing and deposition of nanoscale metal ion beams (purity greater than 99.9%) with high precision. Experimental results show the device fabricates uniform copper films with 50-200 nm line width and 10-50 nm thickness under 10⁻⁴ Pa vacuum. Film resistivity reaches 1.8 μΩ·cm, close to bulk copper, and XPS confirms >99.9% purity with only 0.05% oxygen impurities. Optimizing core parameters (electrode aperture 2 μm, emitter voltage 8-10 kV) achieves ion beam focusing <200 nm. The 8-10 kV voltage window balances deposition rate (2 nm / s) and low defect density, while 1×10⁻⁴ Pa vacuum ensures 87% ion transmission efficiency. The technology demonstrates strong adaptability to silicon, glass, and copper substrates. Silicon substrates yield the most uniform films (RMS 1.5 nm), copper substrates offer the highest adhesion (critical load 20 N), and glass substrates meet industrial standards despite slight aggregation. Eight-hour continuous operation shows <7% beam fluctuation and <5% resistivity variation. Thermal cycling (-55-125 ℃, 60 cycles) maintains >90% adhesion retention on silicon and copper substrates. This research innovatively resolves toxicity, high energy consumption, and low purity bottlenecks of traditional technologies. The green, mask-free scheme provides high-purity, low-resistance nanometal films for precision electronics, offering key technical support for micro-nano manufacturing innovation and promoting engineering applications of mask-free deposition in advanced high-purity metal film preparation.