23 April 2026, Volume 39 Issue 2
    

  • Select all
    |
  • SONG Yirun, WU Shujing, WANG Dazhong, WU Yibo, CHEN Feiyang, GUO Guoqiang
    China Surface Engineering. 2026, 39(2): 3-19. https://doi.org/10.11933/CSE2026307
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Nano minimal quantity lubrication (NMQL) has become a research hotspot in the field of green manufacturing, which significantly improves the cooling, lubrication, and friction reduction properties of bio-lubricants. However, the stability of nanofluids, multi-field coupling mechanism and industrial applicability are still the key challenges limiting its wide application. This paper systematically reviews the latest research progress in NMQL, focusing on the preparation methods, physicochemical properties, and tribological behavior of nanofluids, along with their performance enhancement mechanisms under the coupling of electric, cryogenic, and magnetic fields. It is demonstrated that nanoparticles (e.g., MoS₂, graphene, Al₂O₃) contribute to reduced grinding temperatures and improved workpiece surface quality owing to their high thermal conductivity, extreme pressure anti-wear properties. Hybrid nanofluids further optimize the load-bearing capacity and thermal conductivity of the lubricating film through synergistic mechanisms. In addition, the introduction of multi-physical fields, such as magnetic field induced directional alignment of nanoparticles and regulation of fluid viscosity, electric and ultrasonic fields for enhanced droplet wettability, and cryogenic fields for suppressing grinding thermal damage provides new pathways for the precise regulation of NMQL performance. This paper also discusses challenges related to the sustainability, cost-effectiveness, and scalable application of NMQL, and proposes future research directions, including optimizing the long-term stability of nanofluids, developing intelligent adaptive lubrication systems, and elucidating multi-field coupling mechanisms. This review aims to provide theoretical support and technical reference for the engineering application of NMQL in efficient and green machining. Currently, most reviews on NMQL focus primarily on the physicochemical properties and mechanisms of nanofluids. There remains a lack of systematic analysis of the coupling mechanisms involving different physicochemical properties such as viscosity, surface tension, nanoparticle size, and shape of various nanojets under multi-field conditions, which hinders further development and application of NMQL technology. Current research in nanofluid minimal quantity lubrication is evolved from single-particle systems toward hybrid formulations and multi-field regulation strategies. In terms of nanoparticle selection, materials such as molybdenum disulfide, graphene, and aluminum oxide are demonstrated to be effective in reducing grinding temperatures and improving workpiece surface quality due to their high thermal conductivity and extreme-pressure anti-wear properties. These nanoparticles are widely recognized for their ability to form protective tribofilms on friction surfaces, thereby enhancing lubrication efficiency and wear resistance. Hybrid nanofluids, through synergistic interactions between different particle types, are employed to further enhance the load-bearing capacity and thermal conductivity of the lubricating film. The combination of different nanoparticles is often designed to leverage their complementary physical and chemical characteristics for optimal performance. Regarding performance modulation, multi-field intervention is shown to offer distinct advantages: magnetic fields are utilized to enable directional alignment of nanoparticles and viscosity regulation, electric and ultrasonic fields are applied to improve droplet wettability, while cryogenic fields are used to help mitigate grinding thermal damage. These approaches are regarded as new strategies for precisely controlling nanofluid performance. Nevertheless, key challenges are still required to be addressed, including ensuring long-term nanofluid stability, developing intelligent adaptive lubrication systems, and clarifying multi-field coupling mechanisms. These aspects are discussed in this review to provide theoretical guidance and technical support for the engineering application of NMQL in efficient and sustainable machining processes.
  • ZHENG Zhongpeng, WANG Yan, LI Wenhui, YIN Xiaoming, DONG Yinghuai, ZHAO Jingnan, WANG Shunan, CHENG Lijun, XU Min
    China Surface Engineering. 2026, 39(2): 20-45. https://doi.org/10.11933/CSE2026312
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Owing to their remarkable combination of high strength and superior corrosion resistance, titanium alloys have found extensive applications across a diverse range of industries, including aerospace and biomedicine. However, the difficult-to-machine nature of titanium alloys leads to poor surface quality and low material removal rates during conventional grinding. To overcome the limitations of conventional titanium alloy grinding processes, energy field-assisted machining has become a research hotspot. Ultrasonic-assisted grinding (UAG) couples high-frequency, low-amplitude vibrations with conventional grinding motions to create a periodic “contact-separation-contact” machining pattern between the workpiece and tool. This alters the material removal mechanism, significantly reduces grinding forces and temperatures, and improves the surface integrity of the workpiece. This paper first analyzes the coupled motion characteristics of ultrasonic vibrations, covering one-dimensional vibration modes such as axial, radial, and tangential modes, as well as two-dimensional and three-dimensional composite vibrations. These vibration modes can alter the trajectory of abrasive grains, shorten the effective contact arc, enhance chip removal, and promote material removal dominated by intermittent shearing. This paper summarizes numerical simulation and analytical modeling methods to explain the evolution of undeformed chip thickness, local plastic deformation, and thermo-mechanical interactions under ultrasonic assistance. Furthermore, it reviews various grinding force models developed for different vibration modes to elucidate how ultrasonic vibration affects deformation forces, plowing resistance, and frictional behavior. Experimental observations consistently demonstrate that ultrasonic-assisted grinding improves surface integrity and reduces tool wear. Previous research has shown that ultrasonic-assisted grinding can improve surface quality by 30%-50% and reduce tool wear by up to 40%. In addition, this paper discusses tool wear mechanisms such as abrasive microcracks, bond degradation, and adhesive wear, focusing on the role of ultrasonic vibration in maintaining cutting edge sharpness and enhancing self-sharpening. Surface morphology prediction and subsurface damage modeling further demonstrate that ultrasonic vibration can improve surface finish, suppress surface defects, and contribute to a more favorable residual stress state in titanium alloy parts. Besides single-field ultrasonic grinding, this paper also explores the rapid development of multi-energy-field ultrasonic grinding technology. Representative methods include ultrasonic-plasma oxidation, ultrasonic-electrochemical grinding, ultrasonic-micro-lubrication, ultrasonic-jet-assisted grinding, and ultrasonic-mechanical-chemical coupling. These hybrid methods utilize the synergistic effect of ultrasonic vibration and additional physical or chemical energy fields to enhance lubrication, reduce friction, promote material removal, and stabilize temperature rise during grinding. This hybrid approach also helps improve surface integrity and more effectively control the grinding interface. Combining multiple energy fields with ultrasonic vibration opens up new possibilities for further improving machining performance, especially for difficult-to-machine materials such as titanium alloys. This paper reviews the current research progress, theoretical framework, and mechanistic insights into ultrasonic-assisted grinding and multi-energy field grinding of titanium alloys. The research results provide valuable guidance for advancing efficient, high-precision, and low-damage grinding technologies.
  • GAO Teng, LIU Jixin, SUN Xiaofeng, FANG Xuyang, XU Liandi, ZHANG Bo, XUE Rui, XU Wenhao, LIU Dewei, LI Changhe
    China Surface Engineering. 2026, 39(2): 46-69. https://doi.org/10.11933/CSE2026037
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    High-grade ceramics and their composite materials, optical glass, and other brittle materials exhibit excellent properties such as high hardness, low density, high heat resistance, wear resistance, and high chemical stability. They are widely used in aerospace, rail transit, medical devices, national defense, and other industries. Particularly in the aerospace sector, thermal structural components and hot end components must withstand extreme temperatures, mechanical loads, and oxidizing environments. Hard and brittle material components often require very high surface integrity and dimensional accuracy, and efficient precision grinding is an important step. In addition, the surface integrity of high-temperature components made of hard and brittle materials directly affects their properties and fatigue performance. The traditional grinding process still has limitations such as surface damage, tool wear, and low machining efficiency. Therefore, the realization of efficient and precise machining of such materials has become a key problem that must be urgently addressed in the advanced manufacturing field. As a state-of-the-art technology in the precision machining field, ultrasonic vibration-assisted grinding (UVAG) provides a new method for the efficient and low-damage machining of high-temperature structural parts made of hard and brittle materials through the combined action of high-frequency vibration and grinding. In particular, the unique advantages of UVAG in handling flat, deep hole, thin-walled, and complex hard-brittle material surfaces make it the preferred solution for solving these bottlenecks. A systematic study of material removal mechanisms and surface formation is required. However, existing research has mostly focused on macroscopic ultrasonic machining, lacking of targeted analysis of the ductile-brittle transition mechanism of hard-brittle materials. The relationship between the mechanical properties of abrasive materials and the material removal mechanism has been extensively studied. In this study, the brittle transition mechanism of hard-brittle materials was revealed, and the brittle fracture and ductile deformation removal behaviors of different hard-brittle materials were analyzed. The nucleation and propagation rules of radial and transverse cracks were studied, and ductile removal models characterized by different parameters of different hard-brittle materials were studied. The mechanisms of grinding removal and damage to hard and brittle fiber composites by UVAG were analyzed. Then, by analyzing the mechanical behavior and response characteristics of UVAG hard-brittle materials, a grinding force analysis model of different hard and brittle materials was studied under different UVAG vibration modes, and an error comparison was conducted. The relationships between the grinding and ultrasonic vibration parameters and the grinding mechanics and surface integrity were elucidated. Furthermore, the generation mechanism of hard and brittle material surfaces under the influence of dynamic and nonlinear characteristics of high-frequency and low-amplitude ultrasonic vibration is explained, and the positive influence of ultrasonic vibration on grinding wheel wear was analyzed. Next, a prediction model for the surface evaluation parameters of UVAG hard-brittle materials was studied. Multi-parameter control strategies for surface integrity, such as grinding damage, subsurface damage, surface roughness, and residual stress, were studied. The performance advantages and multi-parameter optimization of UVAG hard-brittle materials were analyzed. The influences of different grinding and ultrasonic parameters on the parameters of ultrasonic-assisted end and peripheral grinding are summarized. The reduction effects of grinding force and surface integrity under different ultrasonic amplitudes were compared. Finally, the existing technical bottlenecks of hard-brittle material grinding were analyzed, including the dynamic fracture behavior of hard-brittle materials under ultrasonic vibration and the formation mechanism of the surface / SSD layer, and there is no intelligent parameter co-optimization method based on material characteristics and grinding objectives. In addition, the development directions of theory, technology, equipment, and applications are expected to provide technical support and theoretical guidance for industry and academia.
  • LING Li, CAO Huajun, WANG Yahui, YE Zhengmao, ZHAO Zizhao
    China Surface Engineering. 2026, 39(2): 70-83. https://doi.org/10.11933/CSE2026038
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Ceramic matrix composites, characterized by high hardness, high brittleness, and poor material consistency, are widely used in the manufacture of key components, such as radomes in the aerospace industry. During machining, material properties lead to high cutting temperatures and significant vibrations, which can easily cause tool wear and undermine the processing quality and production efficiency of the products. Current research has primarily focused on metal material processing, and there has been relatively little research on tool wear prediction in composite material processing, particularly in ceramic matrix composite material machining. This study focuses on special ceramic matrix composites, collecting and analyzing tool cutting vibration signals during machining, and establishing models to predict tool wear. First, a ceramic matrix composite cutting tool wear prediction framework based on the cutting vibration was designed. Under this framework, cutting vibration data processing and tool wear prediction are at the core and receive data from machine tools and smart tool holders. Time-frequency domain feature extraction, correlation analysis, and feature extraction processing of the cutting vibration data were performed. Furthermore, a gated recurrent neural network was used to train a tool wear prediction transfer function model, thereby achieving tool wear prediction and analysis. Based on the prediction and analysis results, control of the tool change and machine start-stop was implemented. Second, through Spearman’s correlation coefficient analysis of the time-frequency domain feature data, the time-domain average and minimum values showed no significant correlation with tool wear, whereas the center of gravity frequency showed a significant negative correlation with tool wear, indicating that as tool wear intensifies, the low-frequency vibration induced by spindle rotation becomes more severe, and the remaining data showed a significant correlation with tool wear, with significance levels above 99%. It can be concluded that there is a significant correlation between the cutting vibration and tool wear data. Utilizing the time-frequency domain characteristics of the cutting vibration data can effectively guide tool wear prediction and cutting parameter optimization. Ceramic matrix composite samples were then used as test objects for the research. Orthogonal experiments were conducted to elucidate the influence of various factors on the cutting force and vibration, determine the main influencing factors, and select the optimal parameter combination. Through orthogonal experiments and range analysis, the optimal parameter combination for balancing tool life and processing vibration was determined: cutting width of 1.0 mm, cutting depth of 1.0 mm, spindle speed of 1 600 r / min, and feed rate of 2 400 mm / min. Single-factor experiments were conducted with the optimal cutting parameter combination to provide data support for the subsequent tool wear prediction analysis. Subsequently, a prediction model for tool wear was established based on a gated recurrent unit network. The model was trained using cutting data, and a real-time prediction evaluation of tool wear was conducted based on the measured operating condition data and mean squared error (MSE). Finally, the optimal validation MSE of the model was 68.528 2, and the prediction error conformed to a normal distribution with a mean of 0. The regression value R approached 1, indicating the effectiveness of the prediction model. Another set of tools was used to conduct cutting experiments with the same process parameters, obtaining 83 sets of time-frequency domain feature data. These 83 datasets were used as validation data for input into the tool wear prediction model, outputting the predicted tool wear values. The curves of the predicted and actual values were plotted, and the predicted curve aligned well with the actual curve. The prediction error range was -39.652 4 to 66.974 6 μm, indicating the model’s effectiveness under real data. In summary, the proposed method provides a theoretical and technical foundation for improving the processing quality and reliability of ceramic matrix composite products.
  • YU Mengqiu, YIN Zhen, AN Qinglong, LI Changping, LIANG Zehui, KOU Yue
    China Surface Engineering. 2026, 39(2): 84-96. https://doi.org/10.11933/CSE2026301
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Cf / SiC composites are characterized by high hardness, high brittleness, anisotropy, and heterogeneity, which induce machining defects such as matrix cracking and fiber pull-out during conventional mechanical processing, severely undermining the service performance and lifespan of components. To address this challenge, a novel single-excitation longitudinal-torsional ultrasonic elliptical vibration turning (LTUVT) device was designed and developed in this study. The primary objective was to achieve stable elliptical tool-tip motion through a simplified vibration system, thereby improving the machinability of the Cf / SiC composites. This study was conducted systematically, encompassing structural design, theoretical analysis, simulation verification, performance testing, and machining experiments. First, based on the principle of longitudinal-torsional vibration coupling, the core components of the device—the transducer and the horn—were structurally designed. Spiral grooves with the defined parameters were machined onto the horn surface. This design decomposes the longitudinal vibration generated by a single piezoelectric ceramic excitation into longitudinal and torsional vibration components with a specific phase difference. The three-dimensional elliptical trajectory of the tool tip, superimposed with the workpiece rotation, tool feed, and ultrasonic vibration, was analyzed through kinematic modeling. Motion equations were derived to elucidate the conditions for intermittent cutting and the friction reduction mechanism. Second, the dynamic characteristics of the designed transducer were investigated via finite element analysis using the COMSOL software. Modal analysis identifies an ideal longitudinal-torsional coupled vibration mode near 21 830 Hz, with the maximum amplitude concentrated at the output end and nearly zero amplitude at the flange, validating the structural rationality. Harmonic response analysis further shows that the longitudinal and torsional amplitudes at the output end at the target frequency are approximately 15 and 10.5 μm, respectively, with a ratio of about 0.7, falling within the preset range of 2-15 μm. Subsequently, the vibrational performance of the fabricated turning device was experimentally tested. The impedance analysis shows that the actual resonant frequency is 21 061 Hz, with a deviation of 5.3% from the preset frequency of 20 000 Hz. The admittance circle is well-formed, indicating good resonant characteristics. Amplitude testing using a laser Doppler vibrometer demonstrates that both longitudinal and torsional amplitudes increase synchronously with the ultrasonic power supply’s output power, reaching maximum values of 12.84 and 11.2 μm, respectively, with an average ratio of about 0.9. These results are consistent with the simulation and design expectations, confirming the capability of the device to deliver stable and controllable elliptical vibrations. Finally, systematic comparative turning experiments were performed on the prepared Cf / SiC composite workpieces using polycrystalline diamond (PCD) tools. The influence of ultrasonic amplitude on the cutting forces, workpiece surface morphology, and tool wear was comprehensively investigated. The results indicate that the LTUVT significantly reduces the cutting forces. Compared with the CT, under the optimal parameters, the radial force, main cutting force, and feed force are reduced by an average of 25.8%, 23.9%, and 26.4%, respectively. Cutting forces decrease continuously with increasing ultrasonic amplitude, reaching minimum values (Fx=3.3 N, Fy=8.8 N, Fz=4.9 N) at a longitudinal amplitude of 9 μm. The LTUVT effectively suppresses the machining damage. Compared to the significant fiber pull-out, matrix cracking, and chip adhesion observed in CT, LTUVT promotes material removal modes dominated by fiber shear and brittle fractures. The fewest defects, such as fiber pull-out and pits, and maximum surface integrity are achieved at a longitudinal amplitude of 6 μm. LTUVT substantially mitigates tool wear. In contrast to the deep and continuous wear-land formed on the tool flank face in CT, LTUVT results in shallower wear grooves and a smaller wear-land area. The tool flank wear area first decreases and then increases with increasing amplitude, reaching a minimum average value of 50 150 μm2 at a longitudinal amplitude of 6 μm, representing a reduction of approximately 79.95% compared to CT. However, excessive amplitude (9 μm) leads to aggravated micro-chipping of the cutting edge. The optimal process parameter identified is a longitudinal amplitude of 6 μm (corresponding to a torsional amplitude of approximately 5.4 μm), which balances superior surface quality with minimal tool wear. This study provides an effective ultrasonic vibration-assisted machining solution for the precise and efficient processing of difficult-to-machine composites, such as Cf / SiC, with significant theoretical and practical engineering value.
  • GUO Xipeng, XU Linhui, YANG Rui, ZHAO Xin’an, YIN Shaohui
    China Surface Engineering. 2026, 39(2): 97-105. https://doi.org/10.11933/CSE2026302
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Ultra-precision grinding technology is critical for the fabrication of aspheric molds from hard and brittle materials. Its machining accuracy directly determines the performance and imaging quality of the final optical components. In current high-precision aspheric mold grinding, wheel-related errors—specifically, wheel-centering deviation and positional misalignment relative to the B-axis rotary center—constitute a major bottleneck that limits form accuracy. These errors induce systematic deviations on the workpiece surface that are difficult to eliminate using conventional compensation methods, severely compromising the final quality of the optical molds. Consequently, the effective identification and compensation of such wheel errors represent a core scientific problem that must be urgently addressed to achieve sub-micrometer or even higher precision in aspheric mold manufacturing. This study provides a systematic solution for this problem. The core research unfolds through several key phases. First, based on the XZB three-axis linkage machining configuration, a rigorous analysis was conducted on the generation mechanisms of two specific error types: wheel-centering error and positional error between the grinding wheel and B-axis rotational center. This detailed analysis reveals how inaccuracies in the wheel installation and deviations in the rotary center setup translate into geometric errors in the machined workpiece. Second, the laws influencing the identified errors on the ground aspheric surface profile were investigated in depth. Theoretical models establish a quantitative relationship between the magnitude of errors and the characteristic form deviations observed on the workpiece, thereby providing a predictive understanding of their impact. Building on this theoretical foundation, the third phase involved the construction of a precise error identification model. This model serves as a critical bridge, enabling the reverse calculation of specific wheel error parameters from the measured form data of a machined workpiece. The development of this model makes a significant contribution by shifting the error compensation process from an empirical trial-and-error approach to a model-based quantitative methodology. A two-stage compensation strategy is also proposed. The first stage involves the independent correction of the identified Z-direction center error and X-direction centering error based on the model output. This step aims to eliminate the dominant systematic geometric errors. Acknowledging that residual errors arising from thermal effects, environmental influences, and other complex factors may persist, a second stage of comprehensive shape error compensation is required. This stage leverages the actual measured profile after the first compensation to generate a direct corrective tool path, targeting the remaining non-geometric systematic errors. To validate the methodology, a series of grinding and compensation experiments were conducted using a self-developed UPN-200G5 multi-axis ultra-precision machine tool. The tungsten steel convex aspherical workpiece was ground under precisely controlled conditions. The initial grinding without compensation yielded a workpiece with a form error of PV 2.612 µm. Application of the first-stage geometric error compensation, guided by the identification model, significantly improved the form accuracy to PV 0.286 µm. The subsequent second-stage comprehensive form error compensation further refined the profile, ultimately achieving a final form accuracy of PV 0.096 µm. This represents a cumulative improvement of 96% compared to the initial state. The experimental results verify the correctness of the established wheel error identification model and the high efficiency of the proposed two-stage compensation strategy. In summary, this study not only successfully addresses a specific precision-limiting issue in aspheric mold grinding but also provides a generalizable model-based framework for error control in ultra-precision machining. This method offers a reliable technical pathway for achieving and stabilizing sub-micrometer-level form accuracy and holds significant engineering application value for enhancing the manufacturing capability of high-end optical components.
  • SONG Yuxiang, DONG Lan, XU Liandi, BIE Qingfeng, YIN Xianxin, XIN Haiyuan, CHEN Shouhai, LI Guanqun, LIU Dewei, XU Wenhao, WANG Xiaoming, YANG Min, LI Changhe
    China Surface Engineering. 2026, 39(2): 106-121. https://doi.org/10.11933/CSE2026039
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    The significant increase in global vehicle fleet annually calls for solutions to address petroleum resource depletion and environmental pollution caused by automobiles. Lightweight technology is crucial for achieving decarbonization and emission reduction. Thin-walled components, which are characterized by their low weight, ease of formation, high aerodynamic efficiency, and resource utilization, demonstrate broad application potential in the aerospace, automotive, and related industries. As a lightweight yet high-strength metallic material, 6061 aluminum alloy has been widely adopted in manufacturing complex thin-walled structures because of its exceptional advantages in terms of weight reduction, ductility, formability, weldability, corrosion resistance, machinability, and cost-effectiveness. Milling, as a core forming process in the manufacturing of thin-walled lightweight components, directly determines the assembly accuracy and service reliability of key components. The low elastic modulus and geometric characteristics of thin-walled structures synergistically endow them with significantly reduced dynamic stiffness, thus rendering them highly susceptible to regenerative chatter during machining. This issue results in dimensional deviations and surface-morphology degradation, thereby severely constraining the lightweight progress and service safety of critical components. Ultrasonic-assisted milling based on interrupted cutting effects and tool-geometry optimization is an effective solution for machining stability control. However, compared with ferrous alloys such as steel, aluminum alloys feature high plasticity, which suppresses the chip-breaking capability of conventional milling tools under high-frequency ultrasonic vibration, thus severely constraining the lightweight advancement and in-service reliability of critical components. The implementation of variable helix angle milling cutters for achieving chip fracture through multi-edge cutting is promising for overcoming this technical bottleneck. However, the universal principles governing instantaneous milling forces under the coupled effect of ultrasonic vibrations and tool structure remain insufficiently understood, thus hindering the efficient theoretical prediction of milling forces. Hence, an instantaneous milling force model was developed for thin-walled workpiece machining using two distinct milling cutters with ultrasonic assistance. Machining experiments were conducted to compare the cutting-force performance of conventional milling, conventional cutters with ultrasonic vibration, and unequal helix angle milling cutters with ultrasonic vibration under identical machining parameters, which validated the accuracy of the milling force model. First, using a discretization approach, an instantaneous milling force model was established by incorporating thin-walled workpiece deformation, stiffness enhancement from ultrasonic effects, interrupted cutting mechanisms, and the structural features of an unequal helix milling cutter. Subsequently, numerical analysis was performed, which revealed the influence mechanisms of variable helix angle ultrasonic milling on the cutting forces. Next, milling experiments were conducted under diverse conditions to investigate the performance of conventional and variable helix angle cutters at different ultrasonic frequencies. Additionally, considering the unique structural design of the unequal helix angle milling cutter, the instantaneous milling force model was further optimized. The cutting-force coefficients of the unequal helix angle milling cutter were determined using the milling slope transformation method. The results showed that the unequal helix angle milling cutter did not significantly reduce the cutting forces as the ultrasonic frequency increased further. Even without ultrasonic assistance, the milling forces reduced significantly and the surface quality improved. Compared with conventional milling cutters, the unequal helix angle milling cutter reduced Fx, Fy, and Fz forces by 11.92%, 9.31%, and 6.53%, respectively, with a total force reduction of 10.22%. Ultrasonic-assisted milling performed using an unequal helix angle milling cutter significantly reduced the cutting forces and improved the surface quality. Compared with conventional milling, at an ultrasonic frequency of 40 kHz, reductions of 45.63%, 42.13%, and 32.87% in Fx, Fy, and Fz forces were achieved, respectively. Based on the instantaneous milling force models of both tools under ultrasonic assistance, numerical analysis was performed using Matlab. Comparative results with experimental data showed prediction errors of 7.32% , 16.54%, and 11.46% for Fx, Fy, and Fz, respectively, relative to conventional ultrasonic-assisted milling, whereas the unequal helix angle milling cutter and ultrasonic-assisted milling exhibited errors of 6.67% for Fx. The strong agreement between the experimental and predicted results validates the effectiveness of the model, thus providing theoretical and technical support for the actual machining and production of lightweight thin-walled automotive components.
  • LIU Can, ZHU Lida, HU Naitao, QIN Shaoqing, YANG Zhichao, HE Wentao, LI Changhe
    China Surface Engineering. 2026, 39(2): 122-135. https://doi.org/10.11933/CSE2026040
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Titanium alloys are widely used in high-end manufacturing fields such as the aerospace, automotive, and medical industries owing to their excellent specific strength, corrosion resistance, high-temperature performance, and biocompatibility. They are particularly critical in key load-bearing rotating components such as integrally bladed rotors and blades of aeroengines. Machining titanium (Ti) alloys remains challenging, largely because of their inherently low thermal conductivity, high affinity for chemical reactions, and pronounced work-hardening characteristics. These characteristics often result in high cutting forces, severe tool wear, and poor surface quality during machining. Ultrasonic vibration-assisted machining has shown promising advantages in theprocessing of Ti alloys. By superimposing high-frequency, low-amplitude longitudinal, or compound vibrations onto conventional grinding, ultrasonic vibration-assisted grinding enhances material removal efficiency, improves surface quality, minimizes surface damage, and effectively mitigates grinding wheel clogging. However, the intricate interactions between the abrasive grains and workpiece make it difficult to fully elucidate the material removal mechanism in ultrasonic vibration-assisted grinding. To gain deeper insight, a kinematic model was developed to simulate and compare the motion trajectories of abrasive particles under both conventional and ultrasonic-assisted grinding conditions. The effects of the machining parameters and frequency ratio between vibration and rotation on the surface texture and material removal were also explored. A theoretical model of the tool surface morphology was developed by constructing a relative motion relationship between the abrasive particles and the workpiece, considering the abrasive surface characteristics and influence of ultrasonic vibration. To further explore the surface formation mechanisms, numerical simulations were performed to model the surface topography produced by ultrasonic vibration-assisted grinding, with particular attention paid to the influence of key process parameters on the surface quality. The simulation results revealed that ultrasonic vibration induces significant grain interference and self-interference, which are the primary mechanisms behind the formation of periodic microtextures and a denser surface morphology in ultrasonic vibration-assisted grinding than in conventional grinding. The surface roughness first decreased and then increased with the spindle speed, whereas it decreased continuously with increasing ultrasonic amplitude. The simulation method was validated through a detailed comparison with the experimental results, confirming its predictive capability. Furthermore, to address the conflict between the surface quality and machining efficiency in ultrasonic vibration-assisted grinding, response surface methodology experiments based on a Central Composite Design were conducted. By selecting the spindle speed, feed rate, ultrasonic amplitude, and grinding depth as input parameters and the surface roughness as the output parameter, a quadratic regression model was established to predict the surface roughness in ultrasonic vibration-assisted grinding. An analysis of variance confirmed the statistical significance and reliability of the model. The results indicated that the spindle speed had the most significant influence on the surface roughness, followed by the feed rate, grinding depth, and ultrasonic amplitude. Analysis of the parameter effects revealed a nonlinear relationship with the spindle speed: as the spindle speed increased, the surface roughness decreased initially and then increased. Meanwhile, an increased feed rate and grinding depth led to a higher surface roughness. Specifically, when the spindle speed was low, the surface roughness steadily decreased with increasing ultrasonic amplitude. At higher spindle speeds, the surface roughness initially decreased and then increased as the ultrasonic amplitude increased. To optimize both the surface roughness and material removal rate (MRR), multi-objective optimization was performed using a genetic algorithm. When the weighting ratio between roughness and material removal rate was set to 1∶2, the optimized surface roughness reached 0.566 μm, a 7.97% reduction compared to the center point value, and the material removal rate reached 8.25 mm3 / min, indicating a 37.5% increase. Different weight settings yielded different optimal outcomes for the roughness and MRR, indicating that selecting appropriate process parameters can maximize the machining efficiency while controlling the surface quality. Finally, experimental validations were performed using three different weight ratios, and the corresponding relative errors between the predicted and measured surface roughness values were 4.39%, 3.92%, and 5.94%. The low prediction errors demonstrated the accuracy and reliability of the developed model.
  • GUO Ce, LI Xiuhong, YANG Shengqiang, LIU Jia, WANG Jiaming, BAI Yu, SU Wenhao, WANG Xingyu
    China Surface Engineering. 2026, 39(2): 136-146. https://doi.org/10.11933/CSE2026304
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Micro-holes in nickel-based superalloys such as Inconel 625 are commonly precision machined using electrical discharge or laser drilling, processes that frequently induce a remelted layer on the hole wall. This remelted layer severely compromises surface integrity, mechanical performance, and service life of high-value components, such as turbine blades, combustion chamber flame tubes, and fuel injection nozzles used in aerospace and energy applications. Existing post-processing techniques, including abrasive flow machining, electrochemical polishing, and magnetic abrasive finishing, face persistent challenges, such as nonuniform material removal, geometrical limitations, high operational costs, and environmental concerns. Therefore, there is a clear need for a more efficient, controllable, and sustainable finishing method. In this study, an innovative ultrasonic cavitation abrasive polishing system combined with chemical pretreatment is proposed to address these limitations systematically. A comprehensive multiphysics acoustic model is developed based on pressure acoustics and acoustic-structure interaction theories. The abrasive-laden polishing fluid is modeled as a porous medium to accurately simulate the complex ultrasonic field distribution within microscale holes. The local enhancement mechanism of ultrasonic cavitation abrasives in micro-holes is elucidated, capturing the localized intensification of acoustic energy, particularly near the hole entrance. This enhancement arises from wave superposition and standing-wave formation. The model further provides mechanistic insights into the cavitation-assisted removal of the remelted layer. Subsequently, experimental validation is performed on ϕ1 mm micro-holes machined in Inconel 625 substrates. Chemical pretreatment is conducted using an HF / HNO₃ solution with a volume ratio of 1∶6 for 75 min to remove the remelted layer from the micro-holes. The effects of key processing parameters, including ultrasonic power (550-1 000 W), SiC abrasive concentration (1%-9%), and processing time (10-50 min), on the final surface quality are systematically investigated. Post-polishing surface characterization is carried out using scanning electron microscopy and surface profilometry. The results demonstrate that the optimized parameter set yields significant performance improvements. The optimal conditions include a machining gap of 1 mm between the horn tip and the micro-hole, a horn immersion depth of 10 mm in the polishing liquid, an ultrasonic power of 850 W, an abrasive concentration of 5%, and a processing time of 30 min. Under these conditions, a maximum surface roughness reduction of 75.68% is achieved. The remelted layer is completely removed from the hole entrance, inner wall, and exit, accompanied by a marked improvement in surface morphology. The processed surfaces are free of microcracks, molten droplets, and surface voids. Notably, the entrance region exhibits superior finishing quality compared with the exit, consistent with the predicted acoustic intensity distribution and field-modeling results. However, deviations between model predictions and experimental results are observed under certain conditions, particularly at low abrasive concentrations (1%-5%) and high ultrasonic power (1 000 W). These discrepancies are attributed to complex interactions, including heterogeneous cavitation nucleation, acoustic shielding effects, and particle aggregation. Future work should incorporate multiphase flow and bubble dynamics to further improve model accuracy. Overall, the hybrid approach combining chemical preconditioning with ultrasonic cavitation abrasive polishing enhances material removal efficiency and significantly reduces surface defects. This method provides a scalable and economically viable solution for precision finishing of micro-hole structures in industrial applications. It can be applied either in conjunction with chemical pretreatment or as a standalone process, depending on the initial surface condition of the micro-holes. When the surface quality produced by prior micro-hole machining is relatively high, ultrasonic cavitation abrasive polishing can be directly employed to further improve surface quality. This study provides valuable insights into the local enhancement mechanism of ultrasonic cavitation abrasives in micro-holes, establishes scientifically grounded process guidelines, and proposes an advanced manufacturing strategy for achieving high-integrity surfaces in safety-critical components for aerospace, energy, and defense applications.
  • DU Zehui, LI Hao, HAO Yupeng, YANG Shengqiang, LI Xiuhong, DU Jiaran
    China Surface Engineering. 2026, 39(2): 147-158. https://doi.org/10.11933/CSE2026041
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Thermal barrier coatings (TBCs) are widely recognized as a critical protective technology for high-temperature components in advanced equipment such as aero-engines owing to their exceptional thermal insulation properties. By significantly reducing the substrate temperature, TBCs effectively overcome the performance limitations of conventional superalloys in extreme thermal environments, thereby extending the operating temperature limits and service life of equipment. A typical TBC system comprises a thermally insulating ceramic top coat overlying a metallic bond coat. The bond coat is crucial for adhesion and oxidation resistance; however, its initial deposition state typically exhibits high surface roughness and pronounced peak-and-valley features. These geometric defects create significant stress concentration zones under thermomechanical loading, frequently leading to premature coating failure via cracking and spalling. Consequently, optimizing the bond-coat surface morphology and understanding its impact on interfacial stress distribution are crucial for enhancing the durability of TBCs. Conventional surface modification methods frequently induce subsurface damage, whereas laser texturing techniques face challenges, such as high costs and difficult heat-affected zone control. In contrast, the widely applied vibratory finishing technique effectively eliminates microprotrusions and blunts sharp surface contours through the synergistic action of high-frequency microimpacts and rolling of the polishing media without causing significant subsurface damage. This study employed a combined experimental characterization and numerical simulation approach. The surface topography of the bond-coat specimens before and after vibratory finishing was precisely characterized using white-light interferometry. Three independent scanning measurements were performed on each selected area. Based on the acquired measurement data, a two-dimensional geometric interface model that accurately reflects the true surface morphology was constructed and applied to finite element simulations. This method enables a systematic analysis of the stress distribution characteristics at the critical thermally grown oxide (TGO) / bond coat interface under typical thermal loading conditions. To quantitatively evaluate the stress field nonuniformity and stress concentration severity, the stress concentration factor (Kt) was introduced as a key metric. A quantitative correlation model linking the surface topography parameters to interfacial stress concentration factors was established. Based on this model, an effective stress concentration factor (${{\bar{K}}_{\text{t}}}$) was defined to enable a holistic assessment of the contour profiles. Pearson’s correlation analysis revealed intrinsic correlations between the key surface topography parameters and the effective stress concentration factor, providing statistical grounds for identifying the most influential morphological features. The study found that the vibratory finishing process significantly improved the surface morphology of the bond coat by effectively reducing the roughness and flattening the sharp protrusions. Finite element analysis indicated that the stress distribution at the TGO / bond coat interface is highly dependent on the geometric characteristics of the interface profile. Under thermal loading, steep regions with large inclination angles and high undulations were identified as the primary zones of concentrated tensile and compressive stresses. As the vibratory finishing process optimized the interface morphology, the stress levels at the interface decreased significantly. In the polished state, the maximum tensile and compressive stresses were reduced by approximately 75% and 78%, respectively, compared to the initial state, indicating a marked mitigation of the stress concentration effects. Correlation analysis provided a robust quantitative validation of these findings. Both the root mean square slope (RΔq) and maximum height of profile (Rz) exhibit significant correlations with the effective stress concentration factor (${{\bar{K}}_{\text{t}}}$). The Pearson correlation coefficients between RΔq and Rz were 0.967 and 0.862 respectively, confirming their dominant influence on interfacial stress intensity. In summary, the vibratory finishing process effectively optimized the morphology of the bond coat interface, significantly reducing the local stress amplitudes and mitigating the stress concentration. Parameters RΔq and Rz were identified as key comprehensive indicators for assessing interfacial stress concentration tendencies. These findings provide crucial quantitative guidance for the precise control of surface topography in engineering practice. Targeted regulation of these parameters through processes such as vibratory finishing can substantially enhance the interfacial reliability and service life.
  • LIU Kexin, LI Wenhui, WEN Xuejie, LI Xiuhong, YIN Xiaoming
    China Surface Engineering. 2026, 39(2): 159-172. https://doi.org/10.11933/CSE2026042
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    The fatigue resistance of TC4 titanium alloys must be enhanced through concurrent stress-field optimization and surface-quality refinement under complex service conditions. This issue is directly associated to a significant extent with surface integrity, which encompasses residual stress, surface roughness, and microhardness. Furthermore, although the traditional shot-peening strengthening process effectively introduces residual compressive stress, it simultaneously causes a marked deterioration in surface roughness; conversely, vibratory finishing can improve surface morphology but exhibits limited capacity to regulate residual stress. Consequently, both the methods exhibit critical technical limitations. Accordingly, a combined shot peening-vibratory finishing process was developed, and its influence on the surface integrity of TC4 titanium alloy was systematically investigated through coupled numerical simulation and experimental validation. A discrete element finite element one-way coupling approach was employed, wherein the discrete element method in EDEM was employed to simulate the motion behavior of the vibratory finishing media under varying process parameters, and a Python-fitted velocity distribution function of the polishing media was mapped onto the finite element model. Subsequently, the simulation results of shot peening strengthening were superimposed to achieve a numerical simulation of the surface residual stress in the TC4 titanium alloy and its evolutionary process along the depth direction. This coupled method overcomes the limitations of single numerical approaches and enables the capture of the stress-strain response and evolution law of the matrix material in the simulation of the combined process. Experimentally, six comparative processing conditions were designed: single-shot peening treatment, single-vibratory finishing treatment, and four types of shot peening-vibratory finishing combined process treatments with different parameter combinations. Advanced characterization techniques were employed to test the surface integrity of TC4 titanium alloy specimens. The surface roughness, residual compressive stress, and microhardness were quantified using white-light interferometry and X-ray residual stress analysis. The results demonstrate that the combined process achieves synergistic optimization of key surface integrity metrics, and its performance is significantly superior to that of the single processes: surface roughness Ra decreased from 0.9 µm to 0.2 µm (i.e., an 82.3% reduction compared with single shot peening). The flatness of the surface topography is significantly improved. This optimization effect stems from the effective removal of surface irregularities (e.g., pits and microcracks) generated during the shot peening process by the vibratory finishing stage. Surface residual compressive stress reached a peak of -824.0 MPa (corresponding to increases of 78.4% over single vibratory finishing). The depth of the stress affected layer extended to 0.7 mm with a “scooped” distribution, which can effectively mitigate the risk of crack initiation caused by excessive stress gradients. Surface micro-hardness increased from 420.0 HV0.1 to 687.1 HV0.1, with a hardened-layer thickness of 150.0 µm, which is approximately twice that of the single vibratory finishing treatment. The above conclusions fully demonstrate that the combined process can fully leverage “the deep plastic deformation effect” of shot peening (to obtain high-magnitude residual compressive stress) and the “surface refinement effect” of vibratory finishing (to reduce surface roughness). By leveraging these two effects cooperatively, the combined process overcomes the inherent tradeoff between residual stress enhancement and roughness control. Furthermore, the coupled numerical simulation method provides a reliable predictive tool for process parameter optimization, reducing the cost of extensive trial-and-error experiments. From the perspective of engineering applications, this combined process offers a cross-scale process solution and a scalable surface-strengthening scheme for the fatigue-resistant manufacturing of aerospace titanium alloy components. This not only deepens the fundamental theoretical understanding of surface integrity regulation for titanium alloys but also provides technical support for the design and manufacturing of high-reliability aerospace components.
  • WU Yibo, WU Shujing, WANG Dazhong, CHEN Jiapeng, SONG Yirun, JIANG Feng
    China Surface Engineering. 2026, 39(2): 173-183. https://doi.org/10.11933/CSE2026303
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Silicon carbide (SiC) is a third-generation semiconductor with exceptional thermal, chemical, and electronic properties. These include high thermal conductivity, high saturated electron drift velocity, a large breakdown electric field, and excellent stability, which make SiC well-suited for use in high-frequency and high-power devices and extreme environments. However, the inherent high hardness and brittleness of SiC make it difficult to machine using conventional single-energy field techniques such as grinding and polishing. These limitations result in a low material removal efficiency, surface cracking, and subsurface damage, thereby motivating the development of efficient low-damage machining methods. Ion-implantation surface modification, which amorphizes the surface region and thereby, reduces hardness and brittleness is a promising solution. However, existing research has mainly focused on heterogeneous ion implantation, which often introduces chemical impurities and presents a tradeoff between the modification efficiency and quality. Furthermore, investigations on the micromechanisms governing this machining method are limited. Therefore, this study used molecular dynamics (MD) to develop a model for the silicon ion implantation-assisted single-abrasive grinding of 4H-SiC. It systematically examines the manner in which the implantation of substrate elements alters the microstructure of the material and influences grinding behavior. A large-scale atomic model comprising a diamond abrasive grain and 4H-SiC workpiece was constructed. Simulations were performed with LAMMPS and analyzed in OVITO using the DXA and IDS modules for defect identification and phase transformation analysis. The workflow comprised the sequential stages of ion implantation, relaxation, and nanogrinding. The Tersoff / ZBL hybrid potential was employed to accurately capture the atomic interactions, including high-energy collisions during implantation. The results showed that silicon ion implantation produced a pre-damaged amorphous layer on the 4H-SiC surface, as evidenced by the increased lattice disorder and reduced peak intensities in the radial distribution function. This modified layer substantially reduced the hardness and suppressed the brittleness of the material. During nanogrinding, the implantation-modified workpiece exhibited improved machinability. The grinding forces were significantly reduced with the average tangential and normal forces dropping by approximately 18% and 24%, respectively. The average grinding temperature decreased by approximately 6%, and the material removal efficiency increased by approximately 69%. Furthermore, the modified layer effectively inhibited crack propagation and improved the stress distribution. Dislocation evolution and amorphous atom accumulation were suppressed, and the material removal rate increased owing to the enhanced plasticity of the modified layer. In conclusion, this study provides microscopic insights into the material removal and damage evolution mechanisms during ion implantation-assisted nanogrinding of 4H-SiC. The key contributions of this study are the development of a systematic MD framework that models the full process chain from implantation to grinding, clarifying how the amorphous layer synergistically improves machinability, and emphasizes the importance of aligning the implantation-modified zone with the grinding region. These findings offer theoretical guidance and a foundation for optimizing the high-performance processing parameters for SiC and other hard-brittle materials.
  • WANG Jun, JIA Dongzhou, ZHANG Yanbin, LIU Mingzheng, WU Lan
    China Surface Engineering. 2026, 39(2): 184-195. https://doi.org/10.11933/CSE2026306
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    :Titanium alloy thin-walled parts have broad application prospects in high-end manufacturing fields such as aerospace and biomedicine due to their excellent specific strength and corrosion resistance. However, its machining process faces objective problems such as low workpiece stiffness, significant fluctuations in cutting force, and accumulation of cutting heat, which can easily lead to excessive deformation of the workpiece, seriously restricting its service performance and reliability. Based on the objective reality mentioned above, it is crucial to explore how the geometric factors of the machining system and the structural characteristics of the workpiece affect the deformation and achieve high-quality machining of thin-walled parts. Low-temperature carbon dioxide minimum quantity lubrication technology, as a green and efficient cooling and lubrication method, has shown great potential in reducing cutting temperature and lubricant consumption. However, existing research mostly focuses on the influence of cutting parameters, and the mechanism by which geometric factors directly affecting workpiece stiffness and cutting force characteristics (such as tool diameter, workpiece wall thickness) affect milling force, deformation, and surface quality is not yet clear, which limits the further development of precision machining technology for titanium alloy thin walled parts. Based on the above background, the milling process of titanium alloy thin-walled parts under cryogenic minimum quantity lubrication conditions was studied, and the influence of geometric factors of the machining system on milling force, workpiece deformation, and surface quality was deeply explored. By establishing a milling force and deformation prediction model, theoretical basis is provided for process optimization, and effective control of machining accuracy is achieved. Firstly, based on fixed cutting parameters and cryogenic minimum quantity lubrication parameters, experiments are designed with tool diameter and thin-walled part wall thickness as the main variables. A second-order milling force prediction model considering the interaction between tool diameter and wall thickness was established based on response surface methodology. Meanwhile, based on Kirchhoff's theory of thin plate deformation, the thin wall is simplified into a rectangular thin plate with three fixed sides and one free side, and solved using the Rayleigh Ritz method to establish a prediction model for workpiece deformation. The experiment was conducted on the Carver 400GA machining center, using a triaxial force gauge and strain gauge to measure milling force and workpiece deformation, respectively. Observe and analyze the surface morphology and roughness of the workpiece using a super depth of field microscope and confocal microscope. The established milling force prediction model has been verified to be significant, with good fitting accuracy, and can accurately reflect the influence of tool diameter and wall thickness on milling force within the experimental range. The overall error of the deformation prediction model is controlled within 20%, but it only considers the influence of force on deformation and fails to take into account changes in material low-temperature characteristics, dynamic changes in lubricating oil film, etc. The model can be optimized in the future. The milling force and workpiece deformation both significantly increase with the increase of tool diameter, and there is a clear positive correlation between the two. Although the increase in wall thickness has a small impact on cutting force, it can effectively suppress deformation due to its significant increase in workpiece stiffness. The surface roughness deteriorates with increasing tool diameter, but improves with increasing wall thickness. Cryogenic minimum quantity lubrication technology effectively suppresses cutting heat accumulation, stabilizes the machining process, and plays a key role in alleviating surface quality deterioration.
  • LIANG Jie, SUN Fujian, LIANG Zhiqiang, LI Xuezhi, LU Yanjun, ZHU Qianfang, XIAO Yubin, HUANG Hao, GENG Yangmo
    China Surface Engineering. 2026, 39(2): 196-206. https://doi.org/10.11933/CSE2026305
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Titanium alloys have excellent physical and mechanical properties and are widely used in many industries; however, their poor machinability not only reduces the machining efficiency but also the surface integrity, thus significantly decreasing the fatigue life. Based on the electroplastic effect and sliding electric-contact principles, electric pulse-assisted cutting can effectively reduce the workpiece strength and improve the tribological behavior between tool-chip / workpiece interfaces during cutting, thus significantly improving the machinability of metal materials to enhance the surface integrity of the workpiece. However, research on the fatigue performance of titanium alloys based on electric pulse-assisted cutting is insufficient. Considering the high-fatigue requirement of machined titanium-alloy components, this study performed electric pulse-assisted cutting on titanium alloys to investigate their surface integrity after they were subjected to electric pulse-assisted turning. A surface roughness tester, Vickers microhardness tester, scanning electron microscope, and electron backscattered diffraction system were used to characterize the workpiece surface roughness, surface morphology, surface work hardening, surface microstructure, and surface thickness of the plastic-deformation layer. Workpiece surface defects, including bonding, tearing, and tool marks, were significantly eliminated; the Vickers hardness reduced with increasing pulse-current parameters; and severe plastic deformation occurred on the workpiece surface along with significant grain refinement. Compared with the results of conventional dry turning, the surface roughness and work hardening of TC4 titanium alloy subjected to electric pulse-assisted turning decreased by 35.7% and 4.7%, respectively; the thickness of the strengthening layer increased by 2.14 times; and more α phases were changed to the β phase in the workpiece strengthening layer. The fatigue performance of the TC4 titanium alloy subjected to electric pulse-assisted turning was investigated using a fatigue-testing machine and scanning electron microscope. The fatigue life of the workpiece machined via electric pulse-assisted turning reached 528.18 × 104 cycles, whereas that achieved via conventional turning was only 35.35 × 104 cycles, thus signifying an improvement by 14.9 times. The fracture morphology of the fatigue specimen was observed using a scanning electron microscope. Fatigue cracks primarily originated from the machined workpiece surface owing to surface defects and stress concentration, whereas they were transferred from the surface to the subsurface in the machined workpiece, which resulted from the low surface roughness, smooth surface morphology, small surface work hardening, and large thickness of the plastic-deformation layer. In particular, the electroplastic effect accelerated dynamic recrystallization and reduced the dislocation density, thereby better coordinating the strain of the plastic-deformation layer on the machined-workpiece surface. Numerous fatigue striations were observed microscopically in the crack-propagation region. The fatigue striations were primarily formed by repeated sharpening and passivation of the crack tip under cyclic compressive and tensile stresses, and the direction of the fatigue striations was perpendicular to the crack-propagation direction. Each fatigue striation was equivalent to one cycle of load or strain, and the fatigue-striation width was closely related to factor such as the workpiece surface roughness, work-hardening rate, and microstructure. The fine grains, small dislocation density, and large plastic-deformation depth might have reduced the fatigue-striation width, thus hindering fatigue-crack propagation. The fatigue-striation width resulting from electric pulse-assisted turning was less than that yielded by the conventional turning. The fatigue-striation width at 50 ℃-0.4 A / mm2-500 Hz was 0.194 μm, which was 78.7% lower than that yielded by the conventional turning.
  • LIN Jieqiong, WANG Tuo, GU Yan, CHEN Jinlong, LI Shuai
    China Surface Engineering. 2026, 39(2): 207-223. https://doi.org/10.11933/CSE2026043
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    High-silicon aluminum alloy composites, with their excellent physical and chemical properties such as low density, high specific strength and stiffness, high thermal conductivity, and good corrosion resistance, are widely used in high-end equipment manufacturing fields such as the new energy vehicle industry, aerospace, and electronic packaging. However, owing to the presence of a large number of high-hardness and brittle silicon particles in the material and their uneven distribution, the contact state between the tool and workpiece during conventional machining (CC) is complex. This leads to high cutting forces and significant fluctuations in these forces, which affect the surface quality after machining. Pulsed laser-assisted turning (PLAT) of high-silicon aluminum alloys (Al-60Si) is expected to reduce cutting forces; however, the microscopic mechanism of cutting forces during the machining process is still unclear. In this study, single-factor experiments are conducted on the PLAT of Al-60Si to explore the effects of the pulsed laser parameters (power, pulse width, and frequency) on the cutting forces. The mechanism by which the pulsed laser reduces the cutting forces is analyzed by comparing the cutting forces between CC and PLAT. Additionally, the microscopic deformation mechanism of Al-60Si under pulsed laser action is investigated using molecular dynamics (LAMMPS) compression simulations. The changes in the microscopic structure and mechanical properties of the material under different pulsed laser energies are studied to reveal the variation patterns of the material temperature distribution, microscopic crystal structure types, dislocation density, stress distribution, equivalent plastic strain, and stress-strain curves. The influence of pulsed laser energy on the mechanical properties of the material during deformation is explored by comparing the changes in the microscopic structure between conventional and laser-assisted compression, and the effects of changes in the microscopic structure and mechanical properties of the material on the cutting forces are further analyzed. The results indicate that during PLAT, as the pulsed laser power increases, the heat-affected zone expands, and more material lattice structures are disrupted, making the material easier to remove and reducing the cutting forces. However, when the power is further increased, the cutting forces increase. The maximum reduction in the cutting forces is achieved at a power of 15 W. As the pulsed laser pulse width increases, the distribution of the pulsed laser energy becomes more dispersed and thermal diffusion becomes more pronounced, leading to an increase in the cutting forces. The maximum reduction in cutting forces is achieved at a pulse width of 16 ns. As the pulsed laser frequency increases, no significant linear trend in the cutting forces is observed; however, the maximum reduction in cutting forces is achieved at a frequency of 100 kHz. Compared to CC, the maximum reduction in the cutting forces for PLAT is 79.2%, which significantly reduces cutting forces and improves the machinability of the material. During the LAMMPS compression simulations, when the material is in the elastic deformation stage, the effect of the pulsed laser on the material is weak, and the microscopic structure of the material undergoes only slight changes with no significant impact on the overall mechanical properties of the material. During the plastic deformation stage, when the pulsed laser energy is 25 eV / ps, the temperature and dislocation density of the material increase, thereby enhancing the strength of the material. However, as the pulsed laser energy increases, the dislocation density decreases, and the original lattice structure of the material is disrupted with an increase in amorphization. This reduces the mechanical properties of the material, making it easier to remove and thus facilitating the reduction of cutting forces, which in turn promotes the improvement of surface quality after machining. These findings reveal the microscopic mechanism of cutting forces during PLAT and are of substantial significance for achieving high-quality machining of high-silicon aluminum alloy materials.
  • BAO Zhongyu, LIAO Xi, ZHANG Song, FANG Congfu
    China Surface Engineering. 2026, 39(2): 223-233. https://doi.org/10.11933/CSE2026044
    Abstract ( )   Knowledge map   Save
    Sapphire (α-Al2O3) is characterized by its outstanding mechanical strength, chemical inertness, and high optical transmittance. It has become a cornerstone material in high-end manufacturing applications, including optical components, electronic devices, and epitaxial substrates for semiconductor growth. However, with a Mohs hardness second only to diamonds in nature, coupled with its pronounced brittleness and exceptional wear resistance, conventional lapping processes encounter significant challenges in terms of low machining efficiency and the propensity to induce severe surface/subsurface damage. To address these challenges, this study incorporates longitudinal-torsional composite ultrasonic vibration into the sapphire lapping process. The synergistic interaction between two-dimensional micron-level high-frequency vibration and abrasive particle processing significantly enhanced the cutting capability of abrasive particles, exhibiting superior material removal characteristics. Through a combined experimental and theoretical approach, the effects of varying ultrasonic power on material removal characteristics, including the material removal rate, surface roughness, morphology, and subsurface damage, were systematically investigated. Based on the geometric kinematics principle of abrasive particles in longitudinal-torsional ultrasonic-assisted lapping, the influence of ultrasonic power on particle cutting-in behavior and planar scratch characteristics were theoretically analyzed by examining single-particle lapping trajectory features. The results revealed that the material removal rate increased with ultrasonic power, showing a strong correlation with the longitudinal amplitude enhancement. The longitudinal amplitude improved the material removal rate by increasing the instantaneous impact force and cutting depth of abrasive particles. The torsional amplitude extended the planar trajectory of particles to increase the lapping path length and complexity while enhancing the interference effect of planar trajectories. Under the combined effect of longitudinal-torsional composite vibration, a significant enhancement in material removal rate was achieved. At 60% power level, the material removal rate reached 382.42 nm/min, representing a 92.9% improvement over conventional nonultrasonic lapping processes. The surface roughness initially decreased and then increased with increasing ultrasonic power, reaching an optimal value (Ra = 82.50 nm) at 50% power with minimal surface defects. This phenomenon is attributed to the repeated impact of abrasive particles under the appropriate ultrasonic amplitude. Microcracks were generated that expanded and closed under impact, leading to localized microfracture removal that prevented large-scale cleavage spalling. Furthermore, ultrasonic vibration reduced the contact time between the workpiece and abrasive particles, reducing the lapping energy consumption and consequently decreasing the activation probability of the sapphire’s cleavage system. When the ultrasonic power exceeded 50%, an excessive vibration amplitude induced a nonlinear increase in the instantaneous impact kinetic energy of abrasive particles on the workpiece surface. Under such conditions, the impact action of abrasive particles may surpass the impact resistance threshold of the workpiece material, resulting in the formation of large brittle fracture pits and deterioration of the surface roughness. Subsurface damage analysis revealed that the damage depth initially decreased and then increased with increasing ultrasonic power. At 50% power level, the damage depth was reduced to 3.9 μm, representing an approximately 23.5% reduction compared to nonultrasonic conditions. The ultrasonic action promoted the formation of microfractures through the extension of lateral cracks toward the surface, while median cracks propagating downward were intercepted by these microfractured zones, which constitutes a significant mechanism for subsurface damage depth reduction under ultrasonic vibration. However, excessive longitudinal vibration amplitude has been demonstrated to directly induce crack propagation and extension into the material interior. Concurrently, the torsional amplitude was observed to sharpen the planar trajectories of abrasive particles, leading to the formation of extensive flake-shaped pits in surface fracture regions and aggravation of damage severity. The theoretical analysis demonstrates that abrasive particles exhibit long-contact and short-separation characteristics under longitudinal-torsional ultrasonic vibration. Torsional vibration generated zigzag particle trajectories on the workpiece surface, producing crescent-shaped scratches that became sharper with increasing power. At optimal power levels, the confined inner region of particle trajectories promoted crack interference and overlap, facilitating localized material removal through microfractures. This mechanism simultaneously reduced large pit formation and suppressed median crack propagation, thereby improving both material removal efficiency and surface quality. The study identified 50% ultrasonic power as the optimal parameter to achieve a controllable machining quality. Therefore, the integration of longitudinal-torsional ultrasonic vibration into the lapping process enhanced both the cutting performance of abrasive particles and their trajectory interference effects. This integration improves the material removal efficiency while simultaneously reducing processing-induced damage to enable high-efficiency and high-quality lapping of sapphire substrates.
  • HAN Tengfei, XIN Guangyang, WANG Kan, ZHANG Qinhe
    China Surface Engineering. 2026, 39(2): 234-243. https://doi.org/10.11933/CSE2026045
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Traditional metallic materials often fail to satisfy the ever-increasing demand for materials with superior mechanical and physical properties for modern industrial applications. Ceramic-particle-reinforced metal-matrix composites are widely used in aerospace, automotive, and other industries because of their excellent mechanical properties. However, the process of machining these composites is challenging owing to the inherent heterogeneity and anisotropy introduced by the addition of hard ceramic particles. Electrical discharge machining (EDM), a noncontact process involving high-temperature plasma for material removal, is a promising method for processing these composites. However, the effectiveness of EDM for ceramic-particle-reinforced metal-matrix composites is often limited by low material removal rates (MRR) and significant electrode wear. To overcome these challenges, the application of an external magnetic field has been proposed as an enhancement technique to improve the machining performance. This study aims to explore the mechanisms by which an external magnetic field influences the EDM process for ceramic particle-reinforced metal-matrix composites by combining mathematical modeling, finite element simulations, molecular dynamics (MD) simulations, and experimental investigations. The effect of an external magnetic field on the EDM process was analyzed using a series of models that examined the interactions between electric fields, magnetic fields, and charged particles. The results indicated that the magnetic field altered the trajectory of the charged particles, thereby increasing the discharge energy and reducing the constriction effect of the plasma. This resulted in a more uniform distribution of thermal energy and an expanded high-temperature region, which enhances the removal of ceramic particles at the matrix-ceramic-particle interface. Simulations were conducted using silicon carbide-particle-reinforced aluminum-matrix composites (SiCp/Al) as the material. Finite element simulations confirmed that the application of an external magnetic field causes the heat center at the Al-SiC interface to shift, resulting in an extended high-temperature zone that facilitates the removal of SiC particles. These changes were further corroborated by MD simulations, which showed that the depth of the discharge craters decreased under the influence of a magnetic field, whereas the crater diameter and volume increased. Experimental verification through single-pulse discharge tests demonstrated that a magnetic field with a strength of 0.2 T increased the crater volume by 34.6%, confirming the simulation predictions. Additionally, drilling experiments indicated that the application of a magnetic field improved the MRR and reduced the relative tool wear rate (RTWR), whereas also enhancing the surface quality of the workpiece. This finding highlights the potential of magnetic field-assisted EDM (MF-EDM) for optimizing machining efficiency and surface finish during the processing of ceramic-particle-reinforced metal-matrix composites. This study further examined the role of the magnetic field in modifying the discharge crater morphology. The discharge craters exhibited symmetrical shapes in the absence of a magnetic field. However, under the influence of the magnetic field, the craters became asymmetrical, with the deepest part shifting laterally. This asymmetry is attributed to the altered energy distribution within the plasma channel caused by the magnetic field. The increase in crater diameter and volume and the decrease in crater depth, suggests that the magnetic field significantly affects energy transfer and particle collision frequency during discharge. Furthermore, drilling experiments demonstrated that the influence of the magnetic field on the MRR follows a nonlinear pattern, with the optimal MRR achieved at a magnetic field strength of 0.2 T. Higher magnetic induction intensities led to excessive deflection of charged particles, resulting in energy loss and a decrease in MRR. Additionally, the magnetic field improved the surface quality by promoting the removal of debris from the discharge zone, which mitigated abnormal discharges and reduced the surface roughness. This study elucidates the mechanisms by which an external magnetic field enhances the EDM process for ceramic-particle-reinforced metal-matrix composites. By influencing the trajectories of the charged particles and modifying the plasma energy distribution, the magnetic field improves the MRR, reduces the tool wear, and enhances the surface quality. These findings offer a feasible strategy for optimizing the EDM of high-performance composites and provide valuable insights into the potential applications of MF-EDM in advanced manufacturing processes.
  • YU Anhui, GUO Zhiguang
    China Surface Engineering. 2026, 39(2): 244-262. https://doi.org/10.11933/CSE2026308
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Efficient and precise droplet manipulation technology is crucial in many frontier fields, including microfluidics, corrosion resistance -, and biomedicine. Owing to their unique properties, smart bionic slippery surfaces represent a key research direction for achieving controlled droplet manipulation. In nature, organisms such as lotus leaves, nepenthes, and cacti have evolved surface structures capable of efficiently manipulate liquid droplets, providing rich inspiration for the artificial design of smart bionic slippery surfaces. Meanwhile, slippery liquid-infused porous surfaces (SLIPS) can be fabricated by infusing a porous structure with low surface energy liquid, which replaces the gas film within the porous solid and forms a more stable “solid / liquid composite film layer”. SLIPS address limitations such as poor stability existing on the “solid / gas” surface of superhydrophobic structures. The lubrication layer isolates the substrate micro / nanostructure from the external environment, substantially reduces the resistance to droplet movement, and shows excellent stability and self-recovery ability, creating favorable conditions for non-destructive, efficient, and high-throughput droplet manipulation. Synergistic physical field modulation provides a more flexible and precise method for droplet manipulation. Electric field regulation achieves directional transport and splitting of droplets by applying an electric field to the slippery surface, using principles such as electric wetting. However, in non-contact droplet manipulation, the magnitude of the electrostatic force must be precisely controlled to overcome the adhesive force of the droplets on the sliding surface without being excessively large to cause instability or droplet splashing. Light-field modulation can be achieved using light-induced chemical reactions or photothermal / photoelectric effects of materials to change the surface properties and achieve droplet manipulation. For example, near-infrared light irradiation can heat specific materials and generate Marangoni flow which, combined with surface energy changes, can achieve directional transport and splitting of droplets. However, light manipulation relies on high-power light sources and complex optical systems, which are expensive. Magnetic field control is achieved by adding magnetic substances to the droplets, using magnetically responsive materials to construct slippery surfaces, or changing the direction and strength of the magnetic field to achieve noncontact manipulation of the droplets, including the manipulation and splitting of droplets in three-dimensional space. However, the addition of magnetic materials can alter the original properties of the droplets. In addition, surface acoustic waves can be used for droplet manipulation to achieve directional transport and mixing of droplets via acoustic wave propagation. Passive manipulation mainly relies on the predefined surface structure shape or chemical properties and drives the droplets along a specific trajectory under gravity, Laplace pressure, or capillary force, making it easy to operate but difficult to accurately control the direction and speed of droplet transport in real time. Although significant progress has been made in the study of droplet manipulation on smart bionic slippery surfaces under synergistic regulation of physical fields, the systematic resolution of challenges such as the complexity of physical field coupling, lubricant stability, and preparation cost remains necessary through theoretical innovations, material design, and process optimization. For example, in practical applications, accurate control of the strength and direction of the magnetic field to achieve precise control of droplet and bubble position and motion speed is an issue that requires further investigation. The stability of the lubrication layer in dynamic environments must be addressed, as the effective propulsion of low-surface-tension liquids and damage to the material during use limit its widespread application. Future research should develop more stable lubrication layer materials and explore methods to integrate multiple intelligent response factors into slippery surfaces to enhance their adaptability to complex environments, simplify the surface manufacturing process, reduce costs, improve equipment operability and economy, and promote the practical application of smart bionic slippery surfaces in multiple fields.
  • HU Haodong, BAI Ziheng, XU Xinyue, WANG Huaiyuan
    China Surface Engineering. 2026, 39(2): 263-277. https://doi.org/10.11933/CSE2026046
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Bio-based materials have received considerable attention from researchers and industries owing to their prominent advantages, including the wide availability of raw materials, excellent safety, and environmental friendliness. However, a notable drawback of such materials is their surface properties; they usually contain a large number of polar groups, resulting in relatively poor environmental stability. This inherent feature not only imposes significant restrictions on their practical applications across a wide range of scenarios but also adversely affects the comprehensive performance and overall service life of the materials. Therefore, targeted functional modification of bio-based materials surfaces is widely acknowledged to have significant academic and practical implications. Recently, diverse methods for constructing hydrophilic/hydrophobic surfaces, such as the template method, plasma modification, and grafting modification, have received extensive attention from the academic community. Specifically, the template method leverages the "structural and chemical guiding effect" of prefabricated templates to precisely construct specific micro/nano morphologies (including columnar, porous, and grid-like structures) on bio-based material substrates. This precise construction allows the modified surface coating to achieve desired properties, such as superhydrophilicity, antifouling capability, and antibacterial activity, demonstrating significant application advantages in specialized fields, such as freshwater collection and directional drainage systems. In addition to these physical preparation methods, a series of chemical modification techniques have been extensively studied, with grafting and copolymerization reactions serving as typical representatives. Grafting is a sophisticated modification technology that introduces functional side chains onto the main chains of polymers through stable chemical bonding. Researchers can endow modified materials with various new functional characteristics, such as hydrophilicity, electrical conductivity, and other desired performances, by elaborately designing the chemical structure and inherent properties of these side chains. As a crucial means of material functionalization, grafting technology can achieve the directional regulation of material properties and microscopic morphology by precisely controlling the composition and structural relationships of the main and side chains. In essence, all of these modification methods regulate the surface morphology or chemical composition of materials at the micro-nano scale, resulting in stable and controllable wettability and effectively expanding their functional applications in antibacterial treatment, anti-fouling protection, and water-oil adsorption. Such advancements undoubtedly have a positive and far-reaching impact on promoting the application and development of bio-based materials. According to a systematic overview of the fundamental characteristics of bio-based materials, this study comprehensively reviews the research progress made in the construction of bio-based hydrophilic/hydrophobic surfaces. It focuses on comparatively analyzing the process features, applicable conditions, and existing challenges of different modification methods; systematically summarizing the application prospects of the modified materials; and proposing prospects for future development trends in this field, with the aim of providing valuable references for the design and preparation of bio-based hydrophilic/hydrophobic surfaces.
  • QIN Hongling, LIU Siyuan, MA Guozheng, LIU Yunfan, LU Yang, JIANG Jinzhe, HUANG Yanfei, LIU Ming, WANG Haidou
    China Surface Engineering. 2026, 39(2): 278-293. https://doi.org/10.11933/CSE2026047
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Nickel-based composite coatings fabricated via thermal spraying play a crucial role in enhancing the wear and corrosion resistance of workpieces, thereby effectively mitigating the safety hazards and economic losses caused by engineering equipment failure. However, the inherent challenges in manufacturing metal-ceramic coatings—stemming from thermophysical property mismatches between the metallic and ceramic phases, nonuniform particle melting states, and process limitations such as rapid solidification—inevitably lead to microstructural defects like pores and cracks. These defects degrade the coating performance by reducing the density, inducing a stress concentration, and accelerating corrosive medium penetration, which ultimately compromise the mechanical properties and service longevity. The formation mechanism of pores and cracks in the forming process of thermal-sprayed nickel-based composite coatings is summarized, including the difference in the solidification and shrinkage of the metal/ceramic phase, primary pores of the powder, and droplets containing gas-forming pores. Thermal stress concentration, brittle particle impact, and insufficient interfacial bonding force lead to cracks. The effects of microdefects on coating properties are analyzed; pores increase the surface roughness, promote crack propagation, and reduce the wear resistance. Cracks and pores become connected to form corrosion channels, which accelerate the corrosion failure of the coating and matrix interface. To solve the above problems, defect optimization strategies are summarized from the aspects of raw powder materials (such as high-energy ball milling, plasma spheroidization, and coating structure design), process optimization (magnetic field-assisted spraying, heat treatment, and multilayer structure design), and ceramic particle size/content control. The formation mechanisms of porosity in nickel-based composite coatings are multifaceted: differential solidification shrinkage between the metal and ceramic phases, inherited porosity from the raw powders, and gas entrapment within molten droplets. Concurrently, crack initiation arises from thermal stress accumulation during rapid cooling, brittle fracture of ceramic particles under impact loading, and insufficient interfacial bonding strength. These defects synergistically deteriorate the coating functionality. Pores increase the surface roughness, promote crack propagation, and weaken the wear resistance, whereas interconnected cracks and pores form corrosive channels that accelerate interfacial failure between the coating and substrate. For instance, studies have revealed that coatings with porosity exceeding 5% exhibit a 40-60% reduction in the wear resistance under abrasive conditions and that crack networks can shorten corrosion-resistant lifetimes by over 50% in marine environments. To address these challenges, comprehensive defect mitigation strategies have been developed in three dimensions. Powder engineering innovations, such as high-energy ball milling to homogenize particle size distributions, plasma spheroidization to enhance powder flowability, and core-shell designs, effectively buffer thermal stresses and improve deposition uniformity. Process optimization techniques, including magnetic field-assisted spraying, post-spray annealing, and multilayer design, significantly suppress defects. Ceramic phase regulation further optimizes performance: Al2O3 particles sized 15-45 μm balance mechanical interlocking and melting efficiency, whereas maintaining ceramic content below 30 vol.% prevents interfacial debonding. Experimental data indicate that optimizing these parameters can improve coating adhesion strength and corrosion. Finally, future performance optimization of nickel-based composite coatings will require synergistic research on multiscale structural control and process mechanisms. In terms of microstructural regulation, although multicomponent materials achieve uniform ceramic phase distribution and reinforcement through bimodal structures constructed with dual-scale particles or in situ reactions, their dynamic thermal reaction processes are prone to side reactions. This necessitates precise control of critical phase transition temperatures during spraying and establishment of quantitative correlation models linking composition, structure, and defects. Regarding process optimization, novel techniques can mitigate melting discrepancies in heterogeneous materials and reduce defects; however, an in-depth analysis of droplet deposition dynamics is required, particularly of the influence of droplet velocity and substrate temperature on interfacial bonding strength. Recent studies have attempted to map process parameters (gas flow rate, spray power, and stand-off distance) to coating quality using deep learning models; however, challenges remain in terms of dataset completeness and model generalization capabilities. Industrial applications must overcome three critical bottlenecks. These are optimization of metal/ceramic ratios to reduce noble metal consumption, development of high-precision feeders and adaptive nozzles for equipment upgrades, and implementation of digital twin technology for dynamic spray trajectory planning to enhance bonding rates while shortening process cycles. These technical pathways require establishing engineering specifications through multiphysics coupling simulations and experimental validation.
  • CHEN Hongyu, CHEN Yiyang, YANG Yujie, QI Huan, LÜ Binghai
    China Surface Engineering. 2026, 39(2): 294-309. https://doi.org/10.11933/CSE2026309
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Polycrystalline hard and brittle materials, characterized by high melting points, superior hardness, and excellent thermal conductivity, are extensively utilized in critical high-tech sectors, such as national defense, aerospace, nuclear energy, and high-end medical equipment. Representative materials, including refractory metals, superalloys, and polycrystalline ceramics, are essential components that require extreme durability and thermal stability. However, the inherent physical properties of these materials, particularly their high hardness and brittleness, pose substantial challenges during manufacturing. Traditional machining processes, such as cutting and grinding, often fail to meet stringent surface quality requirements and frequently induce surface defects and deep subsurface damage. Consequently, ultra-precision polishing serves as the final and most critical procedure for eliminating machining errors, reducing the surface roughness, and ensuring the surface integrity required for optimal functional performance and service life. A systematic review was conducted on the current status and advancements in ultra-precision polishing technologies tailored for hard and brittle polycrystalline materials. This study focused on high-efficiency, high-quality, and low-damage processing strategies, classifying techniques into contact and non-contact categories. Among contact-based methods, chemical mechanical polishing (CMP) was examined because of its ability to achieve global planarization through synergistic chemical corrosion and mechanical abrasion. This mechanism involves formation of a chemically-induced soft passivation layer, which is subsequently removed via mechanical action. Although CMP is widely adopted owing to its maturity, the direct mechanical interaction often induces subsurface damage, such as micro-cracks and lattice distortions. To address environmental and efficiency concerns, recent advancements in eco-friendly slurries and Fenton-like reaction catalysis for materials like polycrystalline diamond and tungsten are highlighted. Electrochemical polishing (ECP) was examined as a stress-free alternative that relies on anodic dissolution. By leveraging the “viscous film theory,” ECP aids the dissolution of microscopic peaks, thereby smoothing the surface without introducing mechanical stress or work hardening. However, this technique is limited by uneven dissolution rates caused by the anisotropic nature of polycrystalline grains and preferential corrosion at grain boundaries. Magnetorheological polishing is discussed as a deterministic sub-aperture polishing technique. By controlling the rheological state of the fluid with a magnetic field, a flexible “semi-solid” polishing tool is formed. This method demonstrates superior adaptability to complex shapes and varying grain orientations, effectively suppressing surface / subsurface damage. However, it requires complex equipment and precise control of the magnetic field distribution. Special emphasis is placed on shear thickening polishing (STP). By utilizing the non-linear rheological properties of non-Newtonian fluids, this technique creates a flexible “fixed” abrasive tool under shear stress. To address the challenges of nonuniform removal in polycrystalline materials, a novel approach, termed liquid film shear polishing, was introduced. It utilizes high-speed fluid shear to remove material, primarily through a tangential force, significantly reducing the normal force and preventing the preferential removal of grain boundaries. This mechanism enhances surface uniformity and minimizes subsurface damage. Furthermore, non-contact beam technologies, specifically ion beam polishing and electron beam polishing, were reviewed. These methods achieve atomic-level material removal and surface modification via physical sputtering or melting, offering the highest precision but at a higher cost and lower efficiency. A multidimensional comparative analysis was performed to evaluate these methods based on manufacturing cost, processing efficiency, subsurface damage control, and surface roughness. Although beam-based methods offer the highest precision and CMP provides excellent planarity, STP has been identified as a promising technique that balances cost, efficiency, and surface integrity. Finally, future development trends are projected accordingly. Specifically, to establish STP as a core high-end manufacturing technology, future research must focus on optimizing the process parameters and exploring multi-energy field-assisted mechanisms to effectively handle grain anisotropy. Simultaneously, the incorporation of AI is advocated to overcome traditional trial-and-error limitations, utilizing deep data analysis and real-time closed-loop control to ensure “zero-defect” manufacturing. The ultimate trajectory is identified as progressing towards atomic-level manufacturing, wherein breakthroughs in atomic layer removal and high-precision in situ metrology are essential for achieving sub-angstrom roughness for next-generation optical and electronic components.
  • DING Hanliang, NIU Shichao, HAN Zhiwu
    China Surface Engineering. 2026, 39(2): 310-325. https://doi.org/10.11933/CSE2026048
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Owing to the excessive consumption of fossil fuels and other non-renewable energy sources such as coal and oil, the world is facing a significant energy crisis. In this context, renewable clean energy, particularly solar energy, has garnered unprecedented attention, making efficient solar energy the primary objective of energy researchers. Concurrently, the rapid advancement of information technology and the proliferation of personalized electronic devices have resulted in a significant increase in screen usage. The glare produced by LCD screens has emerged as a prominent contributor to visual impairment, and strong light reflection from glass curtain walls also contributes to light pollution. Consequently, investigating the application of antireflection technologies in these domains is critical for improving quality of life and optimizing energy structures. Over the last century, antireflection surface technology has advanced significantly to address the challenges posed by excessive reflection on optical surfaces. According to recent research, antireflective surfaces can be categorized into three main types based on their functions: traditional antireflective, light-trap antireflective, and diffuse reflective surfaces. The fundamental principle of antireflection involves minimizing the reflected light at the interface between air and the coating substrate. Early antireflection surfaces relied predominantly on the half-wave optical path difference principle. Although this technology has advanced, its limitations, including low efficiency, narrow operational bandwidth, and inadequate mechanical stability, limit the widespread use of antireflective surfaces in high-end applications. Antireflective structures have attracted significant interest because of their superior performance. These structures can be engineered using various methods to modify the substrate surface or introduce additional materials, resulting in the formation of micro- and nano-sized structures. By using a gradient change in the structural morphology from top to bottom, these surfaces can create a composite layer with a gradually varying refractive index, effectively mitigating the abrupt refractive index discontinuity at the interface and reducing reflection. Compared to conventional antireflection films, antireflection structures exhibit broader operational bandwidths, greater incidence angles, and improved transmission and trapping abilities. However, designing and fabricating antireflection structures with specific functionalities remains a significant challenge that hinders the advancement of contemporary antireflection technologies. Moreover, theories surrounding these structures and their functions have not been fully developed. The design and optimization of their structural parameters are complex, complicating systematic advancements in this field. Nature provides exemplary solutions to these challenges. Throughout millions of years of evolution and natural selection, various organisms have developed structures and functions with remarkable antireflective properties. The study of the antireflection principles of specific biological tissues and their architectures provides a promising avenue for overcoming the current limitations of antireflection technology and paving the way for innovative advancements. In the context of digital transformation and sustainable development, the exploration of bionic antireflective functional surfaces has garnered significant attention and has emerged as a critical research avenue in the field of optical materials. By capitalizing on the benefits of enhanced optical performance and minimized reflection loss, bionic antireflective surfaces have substantial application potential across a range of domains, including photovoltaics, displays, and optical communications. However, comprehensive and systematic research into bionic antireflective functional surfaces is limited. This study aims to provide a thorough review of various functional antireflective surfaces in recent years, encompassing diverse structural designs and material compositions, both domestic and international. These antireflective strategies allow for precise control over the propagation and reflection of light on functional surfaces. In addition, we provide an overview of the fabrication methods, optical mechanisms, and performance characteristics associated with the aforementioned antireflective surfaces, critically evaluating the advantages and disadvantages of each approach while delineating future research trajectories. The incorporation of multi-strategy methods for bionic antireflective functional surfaces is expected to represent a prominent trend in optical material advancement. This review aims to address a significant gap in the existing literature by presenting guiding insights into the synergistic interactions between bionic and intelligent antireflective strategies, providing valuable references for antireflective applications in industries such as optoelectronic technology, communication devices, and renewable energy.
  • ZHAO Yonglin, ZHOU Chenglong, LI Guang, LI Han, YANG Jun, HAN Bingyuan
    China Surface Engineering. 2026, 39(2): 326-343. https://doi.org/10.11933/CSE2026049
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Laser cleaning is an advanced surface-treatment technology. Cleaning is achieved by irradiating the substrate surface with high-energy light beams, which vaporizes contaminants on the substrate surface. Compared to traditional cleaning methods, laser cleaning is environmentally friendly, highly precise, and requires no contact. These advantages have led to their extensive application in various fields such as aerospace, automotive transportation, and cultural relic protection, as contaminants such as oil stains, oxides, and carbon deposits are formed on the surface of the substrate material. These contaminants affect the appearance of the substrate and considerably undermine its integrity. Laser cleaning can effectively remove contaminants without damaging the substrate, thereby ensuring its integrity. Although the relevant content and research methods within this field are constantly being enriched and improved, literature on this topic is limited. These studies guide the development of the entire industry and field; therefore, this study first summarizes the development history of laser-cleaning technology, briefly outlining the research significance and development status of its cleaning methods and mechanisms. On this basis, it further explores laser-cleaning equipment, including the development process and research status of lasers, and laser-cleaning process monitoring technology. Subsequently, the impact of laser-cleaning on the substrate surface integrity is elaborated. The substrate integrity encompasses surface morphology, micro-organizational structure, mechanical properties, and chemical properties. This study reveals that by rationally adjusting laser process parameters, such as laser power, scanning speed, pulse frequency, and spot size, the surface roughness of the substrate can be effectively improved, the surface finish can be enhanced, and surface defects like cracks and pores can be removed, ensuring that the substrate has a good surface appearance. During cleaning, the interaction between the laser and the substrate may cause changes in the microstructure of the substrate surface or near-surface area. These changes include grain refinement, grain boundary migration and reconstruction, formation of sub-grains, twinning deformation, and dislocation entanglement. Such micro-structural changes affect the mechanical and chemical properties of the substrates. Research has indicated that the microhardness, yield strength, tensile strength, and wear resistance of a substrate can be effectively increased by reasonably adjusting the laser energy density and cleaning speed. Reasonable adjustment of the laser power and cleaning frequency can improve the corrosion resistance and wettability of the substrate. This study further analyzes the impact of laser cleaning as a pre-treatment method on the subsequent welding and spraying process performance of the substrate. Experimental studies showed that after laser cleaning, the surface defects of the substrate gradually disappeared, and the surface quality increased the welding performance and bonding strength of the future development direction of substrate. Laser cleaning technology will develop towards greater intelligence, efficiency, and environmental friendliness. With the continuous advancement of science and technology, the performance of laser-cleaning equipment will be continuously upgraded, operation will become more convenient, and costs will be further reduced. Simultaneously, the application of laser cleaning technology will be expanded to more fields, making more contributions to the development of various industries. Consequently, this study fills the gap in the systematic review of the optimization of substrate integrity and its processing performance by laser cleaning within the industry. It not only provides a reference for research in related technical fields but also offers guidance for the further development of the industry.
  • GUO Yuhao, ZHAO Jingmao
    China Surface Engineering. 2026, 39(2): 344-353. https://doi.org/10.11933/CSE2026055
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Magnesium alloy, recognized as the most promising functional structure integration material, has good ductility, machinability, electrical and thermal conductivity, and structural strength, and a low density. It has a wide range of potential applications in fields such as aerospace, national defense and military, transportation vehicles, 3C products, biomedicine. However, its poor corrosion resistance has become the main problem hindering its application. In this study, a two-dimensional layered double hydroxide (LDH) chemical conversion coating is prepared on the surface of a magnesium alloy, which has the characteristics of easy operation, low cost, environmental protection, and strong adhesion to the matrix, and can effectively prevent corrosion. Due to the unique anionic intercalation structure of LDH, studies have focused on the insertion of corrosion inhibitors into the interlayer to protect them from the displacement of corrosive media, such as Cl-. After the intercalation of the corrosion inhibitor, the morphology of the LDH can be changed, the barrier and shielding effects of the LDH coating can be improved, and the migration of aggressive ions can be hindered. The results show that, in addition to loading corrosion inhibitors in LDH, some corrosion inhibitors, such as benzothiazole, can be used as specific types of corrosion inhibitors, offer unique corrosion protection of AZ31B magnesium alloys. Furthermore, a dense bimetallic LDH coating on the surface of a AZ31B magnesium alloy without the addition of exogenous Mg2+ and Al3+ after hydrothermal treatment in an aqueous solution containing benzothiazole can provide effective corrosion protection. After the LDH coating is stripped off the surface of the magnesium alloy by mechanical bending, its crystal structure is characterized by X-ray diffraction (XRD), its functional group structure is characterized by Fourier transform-infrared spectroscopy (FT-IR), and its composition and structural morphology are characterized by scanning electron microscopy (SEM). Electrochemical tests are performed to confirm the excellent corrosion resistance of the prepared LDH coating. The results show that the sample supplemented with both C7H5NS and Na2CO3 is more uniform and denser than the sample supplemented with only C7H5NS. After adding benzothiazole and sodium carbonate to the aqueous solution, the corrosion current density is 1.23×10-7 A cm-2, which is significantly lower than that of the blank sample. Furthermore, the corrosion inhibition efficiency is 90.5%, and the low-frequency impedance value is still higher than 105 Ω cm2 after immersion in 3.5wt.% NaCl solution for 14 days. Benzothiazole has a significant inhibitory effect on the cathodic hydrogen evolution corrosion reaction, and the potentiodynamic polarization (PDP) results show that the cathode current density decreases more significantly. This indicates that the adsorption film formed in the cathode region is denser than that in the anode region. However, there are certain defects in the corrosion inhibitor adsorption film or precipitation film in the anode. As a result, the anode metal dissolution reaction further promotes the release of Mg2+, which reacts with the OH- produced by the cathode reaction and in the solution to form magnesium hydroxide precipitation. then reacts with Al3+ to form LDH, which is deposited on the surface of the AZ31 magnesium alloy. Compared with the blank sample, there is a difference in the surface coverage of the cathode and anode, which can further promote the dissolution of Mg2+ in the anode region. The release of a greater proportion of Mg2+ is more conducive to the formation of LDH, and the generated LDH layer is denser, which provides effective protection for the AZ31 magnesium alloy. After adding the Na2CO3 solution, the pH is approximately 10.5, which is conducive to the binding of Mg2+ and OH- and promotes the precipitation and formation of LDH. This corrosion inhibition mechanism not only improves the corrosion resistance and durability of the protective film but also provides a new perspective for corrosion inhibitors to improve the protection technology of magnesium alloys.
  • YU Jianguo, LI Zhengyang, NING Chuangming, YU Shijia, CAI Zhenbing
    China Surface Engineering. 2026, 39(2): 354-364. https://doi.org/10.11933/CSE2026056
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    In pressurized water reactors (PWRs), the fuel cladding is in service for a long time under extreme environments, such as high temperature, high pressure, high flow rate, and strong radiation. Flow-induced vibration (FIV) is caused by the high-speed flow of coolant through fuel rods, which subsequently leads to grid-to-rod fretting (GTRF). GTRF is the primary cause of fuel cladding failure in PWRs worldwide and may lead to a series of major accidents, such as radioactive material leakage. Effectively reducing or preventing GTRF is an important issue that must be urgently addressed in the field of nuclear energy research. Cr-based coatings are among the most promising candidate materials for accident-tolerant fuel (ATF) cladding, and studying their fretting wear resistance is crucial for enhancing the safety and durability of nuclear reactors. Four types of Cr-based coatings—Cr, CrN, CrAlN, and CrAlSiN—were deposited on the surface of the zirconium (Zr) alloy using magnetron sputtering technology, and their microstructures and phase compositions were analyzed. Fretting wear tests in a B-Li water (3.5 mg / L Li+1 000 mg / L B) environment were conducted to explore the fretting wear behavior and wear mechanisms of the Zr alloy and different coatings. The ball-plane point contact configuration was utilized in the fretting wear test, with the friction pair consisting of an Si3N4 ceramic ball. The test parameters were set as follows: displacement amplitude of 100 μm, load of 10 N, frequency of 10 Hz, and 105 cycles. The results show that different coatings have particles formed by metal droplets on their surfaces, which are typical features of coating surfaces prepared using magnetron sputtering technology. The different coatings have dense surface structure and higher hardness than the Zr alloy; the hardness of the CrAlN coating is the highest at approximately 550 HV0.2, while that of the Zr alloy is the lowest at approximately 200 HV0.2. The CrN coating has the smoothest surface, with a roughness of only 0.10 μm, while the roughness of the Cr coating is the highest at 0.25 μm. The Cr coating is mainly composed of the Cr phase, whereas the CrN, CrAlN, and CrAlSiN coatings are mainly composed of the CrN phase. The wear resistance of the Zr alloy is significantly improved by different coatings, and their wear depth and rate are evidently reduced compared with those of the Zr alloy. The generated oxide wear debris plays a crucial role. The hardness of the chromium oxide produced by the different coatings is higher than that of zirconia produced by the Zr alloy. In addition, the hardness of the coatings is significantly higher than that of the Zr alloy, making the different coatings more wear resistant. The wear degrees of the CrN and CrAlSiN coatings are similar and the lowest, with a wear rate of approximately 1 / 7 that of the Zr alloy and a wear depth of approximately 1 / 5 that of the Zr alloy. The wear mechanisms of Zr alloy are mainly adhesive, abrasive, and corrosion wear, whereas those of the different coatings are mainly abrasive and corrosion wear. The accumulation of wear debris from different coatings is mainly concentrated at the edge of the wear scar, with a large number of furrows and sparse distribution of wear debris in the center area of the wear scar, and no adhesive wear occurring. Based on its smoothest surface morphology, lowest roughness, higher coating thickness under the same preparation process, lowest average friction coefficient in fretting wear test, and best wear resistance, the CrN coating is a better choice than the CrAlSiN coating. By adjusting the proportions of various elements in Cr-based coatings, incorporating alloying elements, optimizing the preparation process, and employing other methods, the performance of Cr-based coatings, including their hardness and wear resistance, can be significantly enhanced. This topic has profound research significance. The aforementioned research findings play a pivotal role in improving the performance of ATF materials, elucidating wear mechanisms, and fostering technological advancements and practical applications.
  • YANG Dongjie, AN Xiaokai, LIU Yaoyao, LÜ Wei, LUO Wanli, YU Qinfang, WU Min, CUI Suihan, LIU Liangliang, WU Zhongzhen
    China Surface Engineering. 2026, 39(2): 365-373. https://doi.org/10.11933/CSE2026057
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Aluminum oxide films have outstanding optical, mechanical, and corrosion resistance properties. Thus, aluminum oxide films have extensive applications in the field of electronic devices and display panels. HiPIMS achieves high ionization rate of sputtered particles through high peak power, enabling the deposited films to exhibit higher density and mechanical properties. However, the high-power discharge of HiPIMS makes it more prone to target poisoning when depositing insulating films. And it will be difficult to recover from a poisoning state under HiPIMS discharge. Therefore, when applied to the deposition of alumina films, HiPIMS exhibits strong sensitivity to reactive gases. The sensitivity of HiPIMS to reactive gases will lead to lower efficiency and increased difficulty of aluminum oxide films. In the deposition of alumina film layers, the oxygen flow rate is usually controlled at a critical value of target poisoning to obtain aluminum oxide films with high degree of oxidation. For HiPIMS technology, the critical oxygen flow rate is not conducive to stable discharge, while low oxygen flow rate will significantly deviate the composition of aluminum oxide films from the stoichiometric ratio. Deviation from the stoichiometric ratio will significantly decrease the optical transmittance and insulation properties of aluminum oxide films. To address this, the experiment utilized an anode layer ion source to generate ionized oxygen and directly transport it to the substrate. These oxygen particles react with aluminum particles to form films. The anode layer ion source allows the Al particles deposited on the substrate to be fully oxidized at a lower oxygen flow rate. Therefore, the anode layer ion source can significantly reduce the oxygen content in the target discharge area. Low oxygen flow rate also improves the stability of HiPIMS discharge. The experimental results show that, since HiPIMS operates under the condition far from target poisoning, the coverage rate of the insulating film on the target surface is low. Low insulation film coverage enables HiPIMS to achieve high-stability discharge and efficient deposition. Through SEM observation of the cross-sectional morphology, it is found that even at a target-to-substrate distance of 40 cm, the deposition rate of the alumina film can still reach 3 μm / h. At a lower oxygen flow rate, the ion source acts as an auxiliary oxygen ionization agent. Ionized oxygen generated from ion source has stronger chemical reactivity, enabling the alumina film to be more fully oxidized. Therefore, EDS results show that the prepared aluminum oxide films have high oxygen content. At oxygen flow rate of 40 mL / min, far below the critical value for target poisoning, the Al / O ratio in aluminum oxide film can reach 0.69. The Al / O ratio means aluminum oxide film with near stoichiometric ratio is obtained. Since the film deposition is performed within the range of oxygen flow rates below the critical point of target poisoning, HiPIMS discharge exhibits good stability. The optical properties of the aluminum oxide films are not affected by arcing. The average optical transmittance of the aluminum oxide film can reach 95.2%. The high-energy characteristics of stable discharge by HiPIMS enable sputtered particles to have stronger migration ability, resulting in aluminum oxide films with high density and flatness. The dense structure endows the aluminum oxide films good mechanical properties, and the aluminum oxide film obtained at oxygen flow rate of 40 mL / min had a hardness of up to 945 HV. The dense structure also enables the alumina film to exhibit corrosion potential of -0.44 V and corrosion current of 10-6.88 A in electrochemical testing. With the assistance of a high-power ion source, the free electrons in the aluminum oxide film almost disappear, significantly improving the surface resistance and insulation properties. The surface resistance of the alumina film layer prepared at a flow rate of 40 mL / min reaches 109.51 Ω / sq, and the insulation strength reaches 62 V / μm.
  • ZHANG Panpan, XIA Xuan, YU Peijiong, JIANG Shengyu, XIE Tian, YAO Zhehe, ZHANG Qunli, YAO Jianhua
    China Surface Engineering. 2026, 39(2): 374-387. https://doi.org/10.11933/CSE2026058
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Advancements in aviation and aerospace technology have led to increased utilization of high-temperature alloys in more extreme environments. Thermal barrier coatings (TBCs) are commonly used for the surface protection of high-temperature alloys, which are often subjected to thermal corrosion erosion during service. This places higher requirements on the performance of TBCs, and the conventional atmospheric plasma spraying process can no longer meet these requirements. Laser surface modification technology can be employed to enhance the stability and corrosion resistance of TBCs at elevated temperatures, thereby satisfying the demands of extreme service conditions. Furthermore, investigating the impact of pre-oxidation time on the thermal corrosion performance of laser alloying-modified yttria-stabilized zirconia (YSZ) TBCs is of paramount importance. Atmospheric plasma spraying was employed to prepare NiCrAlY and YSZ coatings on the surface of Inconel 718, a nickel-based superalloy, following sandblasting to create a double-layered TBCs. The prepared TBCs were placed on a bench. A layer of 0.1 mm of 10% TiC and 90% CYSZ powder was then spread on the surface of the coating. Finally, the self-healing material TiC was fused to the coating using a 1 kW fiber-coupled laser fabrication system. The parameters were laser power of 130 W, scanning speed of 5 mm / s, and scanning spacing of 2 mm. The samples were then placed in a high-temperature chamber furnace at 600 ℃ after ultrasonic cleaning. Subsequently, the samples were placed in a high-temperature chamber furnace at 600 ℃ for 4 and 8 h to undergo a pre-oxidation treatment. They were then subjected to a hot corrosion test in a corrosive salt mixture comprising 25% NaCl and 75% Na2SO4 at 900 ℃ for 4 h. A comparative study of the effect of pre-oxidation time on the microstructure, phase composition, and thermal corrosion behavior of the coating was conducted. The surface of the laser-alloyed TBCs were more smoother and denser than that of the plasma-sprayed TBCs. Following the pre-oxidation treatment, the self-healing agent TiC was oxidized to TiO2 by exposure to O atoms in air. This resulted in volume expansion caused by the increase in TiO2 content, which allowed the cracks to be repaired. This made it difficult for corrosive salts to penetrate the coating and reduced the products of hot corrosion, such as Y2(SO4)3 and m-ZrO2. Pre-oxidation treatment can improve the hot corrosion resistance of the laser surface-modified TBCs; an increase in the pre-oxidation time improves the hot corrosion resistance: the laser surface-modified TBCs with a pre-oxidation treatment of 8 h showed the best hot corrosion resistance. Pre-oxidation heat treatment can promote the TiC self-healing material oxidation reaction in advance to fill part of the cracks to achieve crack self-healing, inhibit corrosive salt penetration into the coating, and reduce the occurrence of hot corrosion reaction. This study proposes the use of a laser to melt TiC as a self-healing material in TBCs. This approach differs from previous methods of testing high-temperature oxidation performance, that have employed high-temperature oxidation to evaluate coating durability. The pre-oxidation process represents a significant strengthening mechanism for laser surface-modified YSZ TBCs and is therefore a highly beneficial technique for the future development of excellent hot corrosion-resistant TBCs. The proposed innovation entails the utilization of pre-high-temperature oxidation to replace the coating with self-healing materials, thereby facilitating the absorption of oxygen, expansion of volume to fill cracks, reduction of corrosion infiltration, and consequently, enhancement of the hot corrosion resistance of high-temperature alloys.
  • HE Nairu, LI Kang, FAN Xiujuan, LI Shuangjian, HE Jialin, YANG Jie
    China Surface Engineering. 2026, 39(2): 388-397. https://doi.org/10.11933/CSE2026059
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    WC series coatings have become indispensable high-performance hard-coating materials across a multitude of industrial sectors because of their exceptional hardness, wear resistance, and corrosion resistance. These attributes have made WC coatings essential components in various applications where durability and reliability are paramount. In the aerospace industry, WC-based coatings are extensively utilized in critical components, such as engine parts, bearings, and bushings. The high hardness and wear resistance of these coatings significantly mitigate component wear, thereby extending service life and enhancing component longevity and reliability. Additionally, their superior corrosion resistance ensures stable performance even under the most demanding and harsh operating conditions. Beyond these applications, WC coatings are also employed in aircraft landing gear and turbine blades, where they enhance both the impact and wear resistance, contributing to the overall durability and safety of these critical components. In the automotive manufacturing sector, WC series coatings are used in brake systems, transmission gears, and piston rings. Here, their low friction coefficient and high wear resistance play a crucial role in reducing mechanical component wear. This not only improves fuel efficiency but also significantly lowers maintenance costs. However, the high friction coefficient of the WC series of coatings results in severe wear of the counterpart. To address this challenge, this study introduces an innovative modification method aimed at endowing WC-based coatings with self-lubricating properties, while retaining their inherently high wear resistance. Using advanced laser processing technology, interconnected ortho-hexagonal grooves were meticulously created on the surface of the WC-10Co4Cr coating, forming a regular surface texturing network. This structural design serves multiple purposes: it enhances the mechanical interlocking between the coating and substrate, ensuring better adhesion and durability. In addition, it provides a reservoir for lubricant storage, which is a critical feature of the self-lubricating mechanism. Subsequently, the grooves are filled with fusible polytetrafluoroethylene (PFA), renowned for its excellent lubricating properties and thermal stability, via vacuum impregnation. This technique ensures uniform distribution of PFA within the grooves, providing a stable, continuous lubricant supply during operation. The combination of surface texturing and vacuum impregnation not only introduces an additional lubricant phase to the coating but also optimizes the lubricant storage and supply mechanism through structural design. The interconnected grooves act as a reservoirs for the PFA, ensuring its availability for lubrication, even as it is consumed during operation. This design significantly enhances the ability of the coating to maintain low friction under dynamic conditions, which is a crucial factor in reducing wear and improving efficiency. The friction factor of the WC-10Co4Cr-PFA composite coating was significantly reduced to 0.17, a marked improvement over the unmodified WC-10Co4Cr coating (0.36) and the coating with surface texturing alone (0.30). This substantial reduction in the friction factor indicates that the synergistic effect of laser texturing and PFA lubricant can significantly enhance the self-lubricating performance of the coating, enabling it to operate at low friction. This improvement is attributed to the effective integration of the mechanical benefits of the WC-10Co4Cr coating with the lubricating properties of the PFA. More importantly, the WC-10Co4Cr-PFA composite coating exhibited a unique self-replenishing mechanism. When the PFA lubricating film in contact with the coating is consumed because of wear, the viscosity of the PFA in the grooves decreases under the effect of frictional heat. Under the shearing action of the mating balls, PFA redistributed and repaired the worn surface lubrication film. This self-replenishing function ensures that the coating maintains a consistently low friction factor over an extended period of operation. In a rigorous 100-hour friction and wear test, the average friction factor of the WC-10Co4Cr-PFA composite coating remained at approximately 0.17, demonstrating its excellent self-lubrication life. In this work, the surface texture and vacuum impregnation of PFA resulted in a WC-10Co4Cr coating with excellent long-life, self-lubricating performance, providing a new idea and method for improving the lubricating performance of hard-wearing, wear-resistant coatings.
  • LEI Jiaxing
    China Surface Engineering. 2026, 39(2): 398-414. https://doi.org/10.11933/CSE2026050
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    In marine environments, metallic materials are susceptible to various forms of corrosion, among which microbiologically influenced corrosion (MIC) is particularly significant. This type of corrosion is primarily induced by the activities of specific microorganisms such as sulfate-reducing bacteria (SRB). These mechanisms involve localized chemical changes caused by biological metabolic processes, such as acidification and acceleration of deoxygenation reactions. Such corrosion phenomena pose significant threats to the long-term reliability and durability of metals in marine environments, endangering critical engineering structures such as ships, offshore facilities, pipelines, and other infrastructures. Therefore, the effective inhibition of microbial corrosion and enhancement of the service life of metals in marine environments have become critical areas of research in materials science. To address this challenge, this paper troduces a novel TiC-based nanocomposite coating prepared using dual-cathode plasma sputtering deposition. The antibacterial and corrosion-resistant properties of the coatings were significantly enhanced by the incorporation of Ag nanoparticles (AgNPs). Dual-cathode plasma sputtering deposition is an efficient and controllable thin-film preparation technique capable of co-depositing multiple materials, thereby creating composite coatings with superior performance. In this study, AgNPs were uniformly distributed within the TiC nanocrystalline matrix, endowing the coating with remarkable antibacterial and microbiologically influenced corrosion resistance properties. Four representative strains were selected for experimental, evaluation: Gram-negative E. coli and S. typhi, Gram-positive S. aureus, and the fungus C. albicans. The antibacterial performance of the AgNP / TiC nanocomposite coating was assessed using the plate count method, which involves the quantification of the number of surviving bacteria after contact with the coating. The results demonstrated that the AgNP / TiC coating exhibited excellent antibacterial activity against all the tested strains, significantly reducing bacterial growth and reproduction. This effect is primarily attributed to the unique antibacterial mechanisms of AgNPs, including the release of silver ions and their interactions with the bacterial cell walls and DNA, which disrupt normal metabolic processes, ultimately leading to cell death. To further investigate the performance of the coating against SRB-induced microbial corrosion, we employed the paired reagent bottle method and most probable number dilution method. SRB strains were inoculated into artificial seawater, and changes in SRB populations in solutions exposed to the coating were analyzed. Compared with traditional TiC coatings and untreated titanium substrates, the AgNP/TiC coating significantly reduced the SRB population in the solution by three orders of magnitude. The incorporation of AgNPs effectively inhibited SRB adhesion and aggregation on the coating surface and prevented biofilm formation. Furthermore, the electrochemical corrosion behavior of the AgNP/TiC coating in SRB-inoculated artificial seawater was systematically studied using electrochemical techniques, including potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS), and Mott-Schottky analyses. Potentiodynamic polarization results indicated that the AgNP/TiC coating exhibited a higher corrosion potential and lower corrosion current density, demonstrating superior corrosion resistance. The EIS analysis further revealed that the passive film formed on the coating surface provided a high charge transfer resistance, significantly impeding the corrosion process. Mott-Schottky analysis showed that the semiconductor properties of the AgNP/TiC coating were markedly improved, which played a crucial role in enhancing its corrosion resistance. This study also revealed that the passive film formed on the coating surface exhibited unique microstructural characteristics. This passive film not only demonstrated high stability but also provided excellent isolation against corrosive media, thereby significantly enhancing the corrosion resistance of the material. The incorporation of AgNPs was pivotal in modulating the microstructure and surface chemistry of the coatings. The AgNPs enhanced the antibacterial activity of the coating by effectively suppressing microbial adhesion and proliferation. In contrast, the synergistic interaction between the AgNPs and TiC matrix improved the mechanical properties and durability of the coating. In this study, the comprehensive performance of a AgNP / TiC nanocomposite coating in a simulated marine environment was systematically investigated, highlighting its significant advantages in term of antibacterial and microbiologically influenced corrosion resistance. The findings demonstrate that the addition of AgNPs provides new insights into improving the coating performance and creates new avenues for developing coatings with efficient antibacterial and corrosion-resistant properties. This novel coating has significant application potential in shipbuilding, marine engineering, and other industries involving corrosive environments.
  • LI Lulu, GUO Xinlei, SHI Junqin
    China Surface Engineering. 2026, 39(2): 415-425. https://doi.org/10.11933/CSE2026060
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    TiAl alloys are used as moving parts in spacecraft, such as jet engine turbine blades, and typically experience friction and wear in complex working environments, which has a significant effect on working stability and service life. In recent years, with the progress of science and technology, the machining accuracy, surface quality and sub-surface properties of TiAl alloy parts have been an increased demanded for their use in aeroengines. Therefore, it is essential to determine the micromechanical behaviors of γ-TiAl in the friction process, and the surface deformation and damage mechanisms. However, traditional experimental methods have limitations in determining the microscopic mechanical behavior and deformation mechanism, whereas the molecular dynamics simulation method can perform dynamic observations of the microscopic deformation and defect evolution of materials at the atomic level. Therefore, in this study, the nano-scratching behaviors of γ-TiAl single crystals and polycrystals are investigated using molecular dynamics simulation. The differences in friction, wear performance, and plastic deformation between single crystals and polycrystals are compared, and the effects of the scratch speed and scratch depth on the friction and wear performance are elucidated. The results show that a single crystal presents greater frictional resistance with a larger friction coefficient during the nano-scratch process, and better wear resistance is also proven because of fewer removed atoms and lower stacking heights when compared with polycrystals. As a single crystal has a regular crystal structure along the scratch direction, the wear atoms at the front and both sides of the indenter are uniformly stacked. However, the randomness of the grain orientation and the existence of grain boundaries in the polycrystals lead to asymmetric atomic packing at the front and both sides of the scratch region. The movement of the indenter causes obvious deformation in the contact area; the crystal atomic structure of the contact area becomes amorphous, and many atoms removed by wear move forward with the indenter. Polycrystals and single crystals show significantly different deformation behaviors and stress-strain characteristics induced by friction action. Friction leads to high shear strains in the scratch regions of the single crystal and strip strain zones on the {111} <111> slip system, suggesting that a large plastic deformation occurs within a single crystal. Friction promotes strain and stress concentrations at the grain boundaries in the polycrystalline model, thereby reducing plastic deformation within the polycrystalline grains. Analysis of the defect evolution indicates that the impact of the indenter on the surface of a single crystal causes the nucleation and expansion of many Shockley partial dislocations, and the grain boundaries become the source of dislocation nucleation in the polycrystals, leading to the formation of stacking faults within the grains around the indenter. Simultaneously, compared with the single crystal model, the limitation of the grain size in the polycrystal causes the dislocation and stacking faults to expand in a smaller space; thus, the dislocation density is significantly smaller, and the dislocation distribution is more complex. An increase in both the scratch speed and scratch depth results in an increase in friction and wear. A higher scratch speed can facilitate the activation of dislocations, and the accumulation of dislocations induces strain hardening of the substrate, leading to an increase in friction and normal forces. The number of atoms removed also increases with the scratch speed, indicating that the surface is more worn at high speeds. A greater depth represents a larger contact area, indicating that a greater external force is required to move the indenter, thus increasing friction and normal forces. Similarly, a larger scratch depth indicates that more volume is removed by wear, and more atoms are removed. These results are important for the development and design of high-performance TiAl alloys.
  • WANG Xiaowei, WANG Ning, QI Jiantao
    China Surface Engineering. 2026, 39(2): 426-434. https://doi.org/10.11933/CSE2026061
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    The development of the electronics industry has resulted in the widespread use of electronic connectoraus as key components. However, the issue of surface corrosion, which severely affects their performance and reliability, is becoming increasingly prominent. As the main protective layer of electronic equipment, Zn-Ni alloys do not provide satisfactory wear resistance and hardness, which implies that they easily fail or generate corrosion cracks in corrosive environments. Currently, studies pertaining to the performance of Zn-Ni alloy surface passivation films are few. Therefore, the corrosion behavior of a hexavalent chromium (Cr(VI)) passivation film on the surface of Zn-Ni alloys is investigated in this study. The microstructure, elemental distribution, and corrosion resistance of passivation films on Zn-Ni-plated surfaces of electronic components are compared using high-resolution electron microscopy, surface-energy spectroscopy, and Raman spectroscopy. The aim is to compare the performances of electronic-component surface-plating and Cr(VI) passivation films under two different processes. The effects of different processes on the passivation films are elucidated to provide new ideas for investigating passivation-film properties. For Sample 1, scanning electron microscope results show relatively sparse surface cracks constituting 51% of the total area ratio, thus indicating a low surface tension, and that the cross-sectional morphology presents a clear layered structure. Results of energy-spectrum analysis show that the Zn-Ni distribution on the surface is not uniform and that Ni enrichment occurs in some areas, with the thicknesses of the Ni, Zn-Ni alloy, and Cr(VI) conversion layers being 16, 61, and 3 µm, respectively. The Ni and Zn mass fractions are 14.4% and 72%, respectively, and the corrosion resistance is reasonable. Results of Raman spectroscopy indicate an acidic environment on the surface of the samples, as well as peaks at 886, 443, and 730 cm-1 for Cr2O72-, ZnO, and CO32-, respectively, which are likely due to the presence of pollutants in the surface film-forming process or in the environment. Four typical points on the cross-section of Sample 1 are examined using Raman spectroscopy, and the results show clear Cr(VI) peaks, thus confirming the existence of a Cr(VI) passivation layer in Sample 1. For Sample 2, SEM results show that a densely cracked surface constituting 79% of the total surface area, and that the cross-sectional morphology shows a structure comprising three plating layers. The results of energy-spectrum analysis show a uniform Zn-Ni distribution on the surface without enrichment, with the thicknesses of the Ni, Zn-Ni, and Cr(VI) conversion layers being 12, 35.5, and 3 µm, respectively, and Ni and Zn mass fractions of 13.5% and 71%, respectively, thus indicating the better corrosion resistance of Sample 2. Cr(VI) shows peaks at 851, 996, and 351 cm-1 for CrO42-, SO42-, and of Ni(OH)2, respectively, which is primarily due to the concentration and acidity of the solution. Raman test results indicate a concentration difference on the surface. Additionally, Raman results of the cross-section show a peak at 846 cm-1 for Cr(VI), thus proving the presence of a Cr(VI) transformed layer in Sample 2.
  • GUO Dawei, YAO Mengtao, LIU Xiaodong, ZHAO Xing, FEI Jiyou, ZENG Xianghao
    China Surface Engineering. 2026, 39(2): 435-450. https://doi.org/10.11933/CSE2026062
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Currently, numerous challenges are faced in the detection of surface defects on hot-rolled strip steel. These include the difficulty of feature extraction caused by the complex background of crazing (Cr) defects, a weak response exhibited by small target defects such as pitted-surface (Ps), a lack of cross-scale fusion resulting from the different scales and morphologies of rolled-in-scale (Rs) defects, and the issues of a small number of samples and an uneven distribution of categories encountered. To meet the requirements for high accuracy of the surface defect detection algorithm for hot-rolled strip, a hot-rolled strip surface defect detection algorithm named RCS-YOLOv8, which is based on an improved YOLOv8, was proposed. Six surface defects, such as crazing and pitting-surface, were taken as the research objects to enhance the detection precision and robustness of surface defects in hot-rolled strip steel. To address the limitations of the original YOLOv8 in small object detection and multi-scale feature representation, improvements were made in three key areas. First, an enhanced receptive field and coordinate attention mechanism were introduced to construct the RCC (Receptive field & coordinate attention convolution) module. Feature extraction is enhanced by improved receptive field coverage and directional sensitivity; thereby, the recognition accuracy for densely packed objects is boosted. The constructed RCC module not only inherits the directional sensitivity of CA but also is enabled to extract detailed information with greater precision through enhanced receptive field adaptability provided by RFAConv (Receptive field attention convolution). Object localization capabilities are enhanced by the CA mechanism through the modeling of long-range dependencies in both horizontal and vertical directions. However, a fixed local receptive field is maintained by CA, which fails to fully optimize the flexibility of feature extraction. To address these limitations, an adaptive approach is employed by the RFAConv module to optimize feature extraction. Compared to traditional attention mechanisms, weights for different positions are learned by RFAConv to adaptively adjust the receptive field size, which effectively enhances local feature representation. Furthermore, the degree of attention paid to features across different receptive fields can be adaptively adjusted by RFAConv. Simultaneously, the CFC (Receptive field & coordinate attention cross-stage fusion) module, which integrates both RCC and C2f (Cross-stage partial fusion) architectures, enhances multi-scale feature representation capabilities while computational efficiency is maintained, enabling adaptive receptive field feature extraction. The core of the CFC module is considered to lie in the refinement of the multiple Bottleneck structural submodules that compose the C2f module. As the fundamental building block of the C2f module, structural refinement is undergone by the Bottleneck structure, where its standard convolutions are replaced with RCC modules. This modification, performed without altering the overall C2f framework, enables adaptive receptive field extraction capabilities; thereby, the feature modeling power of the C2f module is enhanced. For small targets, the P2 shallow multi-scale detection module SBA (Spatial Bi-directional attention) is proposed. The SBA module, a spatial bi-directional attention mechanism, is primarily applied to feature fusion in computer vision tasks. This module is designed to process multi-scale features, enabling effective integration between high-resolution and low-resolution features. Bidirectional pathways are established between high- and low-resolution features, while a P2 detection layer is incorporated to enhance shallow feature extraction capabilities. Through this approach, detection accuracy for objects at different scales is improved and spatial feature perception is strengthened. The RCS-YOLOv8 network was used to train and test the surface defect dataset of hot-rolled strip, and comparisons were made with the original model. Experimental results show that the average detection mean mAP and F1 score of the improved YOLOv8 algorithm on the NEU-DET dataset are 79.8% and 78%, respectively, which represent increases of 3% and 5% compared to the original model, and the floating-point operations of the improved algorithm are reduced by 2.4%. On the GC10-DET dataset, the mAP was increased by 4.2%. RCS-YOLOv8 not only achieves higher detection accuracy but also maintains a fast detection speed, which meets the requirements for both accuracy and real-time detection of industrial strip surface defects.
  • YU Yanqing, MA Tianbing, LI Yong, LI Changpeng, SHI Rui, SHEN Chen
    China Surface Engineering. 2026, 39(2): 451-461. https://doi.org/10.11933/CSE2026051
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    A mining pick is a cutting tool used in coal mining, roadway boring, and tunnel construction and consists of a carbide tip, body, and handle. With increasingly harsh mining conditions, the hardness and proportion of rock in the tunnel increase. High stress and strong impact loads cause severe wear problems in picks, making them the most consumed components in mining operations. Therefore, the rock-cutting wear degradation mechanism of a pick should be studied to conduct a suitable strengthening process. To clarify the wear degradation behavior and wear distribution law of the pick, the interactive wear evolution between the pick and granite was investigated using a custom-made pick wear tester. Changes in the tooth surface temperature, vibration acceleration, and wear characteristics at different cutting distances were systematically studied, and the wear degradation mechanism in different tooth surface regions was revealed using a thermal imager, vibration acceleration sensor, electronic balance, three-dimensional scanner, and scanning electron microscope. The results showed that wear and temperature increase occurred on the tooth surface of the pick. As the cutting distance increased, the wear loss of the pick increased almost linearly, accompanied by a gradual expansion of the wear area on the tooth surface from the tip to the entire tooth surface. Because of the friction-induced heat effect, the wear region of the tooth surface correlated well with the temperature field distribution, and the tooth surface temperature gradually increased with an increase in the wear area. A strong impact load was generated, and the vibration acceleration peak-to-peak value increased remarkably during rock cutting by the high-hardness pick tip, whereas the low-hardness pick body experienced sliding friction with the uncut/cut rock block, and the vibration acceleration peak-to-peak value was much smaller than that of the impact process. In addition, the amplitude-frequency characteristics of the impact and friction phases were different. During the impact phase, the vibration acceleration was primarily a high-amplitude oscillation signal with a relatively simple signal composition, whereas during the friction phase, the vibration acceleration consisted of low-amplitude, random, and complex frequency components. The uneven forces on both sides of the pick under asymmetric loading and a unilateral rotational moment caused the pick to rotate. Owing to the “self-sharpening” effect, the wear degree of pick tip and body was almost uniformly distributed along the circumference. The main wear mechanism of the pick tip was impact wear. Under the combined action of the impact load and high temperature, a dense rock particle accumulation layer formed on the pick tip. Owing to the high hardness and protection of the rock particle accumulation layer, the wear volume of the pick tip was much smaller than that of the pick body, despite the higher impact load. The wear volume of the pick body was 19.5 times greater than that of the pick tip. The entire pick body can be divided into severe wear and slight wear regions from top to bottom. The main wear mechanism in the severe wear region was abrasive wear, which accounted for 97% of the total pick body volume loss. The slight wear region was dominated by plastic flow, with almost no material removal. Constantly intruding rock particles mix into the pick body material, eventually leading to the formation of a mechanically mixed layer. This study clarified the wear distribution law and degradation behavior of the pick tooth surface, which will provide technical support for the high-performance strengthening and repair of picks.
  • SONG Wei, CHEN Haoxiang, LI Kaimin, XIA Chunchen, MENG Yahui
    China Surface Engineering. 2026, 39(2): 462-474. https://doi.org/10.11933/CSE2026053
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Micromotion wear is prevalent in the aerospace, marine, chemical, and nuclear energy industries. TC4 is sensitive to fretting wear due to its poor tribological properties and limited work-hardening capability. The blade is a key component of aero-engines, and the service conditions are harsh, including centrifugal force, high temperature, gas excitation, and vibration. The most prominent issue is that rotor vibration causes periodic separation and contact between the blade root and the rim surface, leading to small-amplitude relative motion and alternating stress at the contact surface. This results in severe fretting wear at the blade root, which is a typical case of tangential micromotion wear. To improve the anti-fretting wear characteristics of the TC4 alloy surface and expand its application scenarios, the surface of the TC4 alloy was treated with laser shock peening (LSP) using an Nd:YAG solid-state laser. A study of the treated surface morphology revealed that LSP had minimal effect on the phase structure of the base metal. The laser shock peening technique enhances the comprehensive mechanical properties of the base metal without introducing thermal effects. It is practical, controllable, and induces a nanocrystalline layer on the alloy surface. There have been few studies on the fretting wear behavior and mechanism of LSP-treated TC4 alloy under different displacement amplitudes. In this paper, fretting wear damage models are established under various displacement amplitudes (50 μm, 100 μm, 150 μm, 200 μm) using an SRV-IV fretting wear tester. The fretting wear performance of the TC4 alloy before and after LSP treatment at different displacement amplitudes is analyzed, as well as the effect of nanocrystalline grains on fretting wear behavior before and after LSP. A QUANTA FEG 450 field emission scanning electron microscope (SEM) with an integrated EDS spectrometer was used to characterize the microstructure, elemental composition, and distribution within the wear regions. An OLYMPUS OLS5000 laser scanning confocal microscope (LSCM) was employed to characterize the 3D morphology of wear scars, wear interface profiles, and wear volume. A D8 DISCOVER X-ray diffractometer (XRD) was used to analyze the phase composition in the wear region, enabling the study of tangential micromotion wear behavior of the nanocrystalline layer on the surface of LSP-treated TC4 alloy at room temperature. Additionally, a two-mode fretting wear model was developed to investigate the fretting behavior and material damage mechanism of LSP-treated TC4 alloy. The results showed that LSP refined the internal microstructure of the alloy, introduced a high density of dislocations, reduced surface wear, decreased the friction coefficient, and improved the friction and wear performance of the strengthened surface. It significantly reduced fatigue spalling and the formation of microcracks in the contact area, effectively inhibiting crack initiation and propagation. Compared to untreated TC4 alloy, the LSP-treated alloy exhibited less variation in wear interface damage across different displacement amplitudes. Surface grain refinement due to LSP led to oxidation of the refined grains under frictional heat, resulting in a surface oxygen content significantly higher than that of titanium, which increased progressively with displacement amplitude. LSP effectively enhances the anti-fretting wear performance of TC4 alloy across various displacement amplitudes. The refined grain layer promotes the formation of a stable third-body layer with the substrate under the influence of frictional heat, altering the wear pattern on parts of the surface and reducing overall damage.
  • LIU Yanmei, XU Mengjiao, ZHAO Jiayin, YE Jiani, GUO Yuyao, FAN Qixiang, CAO Fengting, WANG Tiegang
    China Surface Engineering. 2026, 39(2): 475-484. https://doi.org/10.11933/CSE2026054
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    TiB2 coatings are expected to have broad applications in wear-resistant fields owing to their high hardness, good wear resistance, and high thermal stability. However, these coatings are extremely brittle and prone to fracture during use. Existing research, both domestically and internationally, has introduced nitrogen into TiB2 coatings to form nc-TiN / a-BN nanocomposite structures to improve the coating toughness. However, it was found that even the introduction of a small amount of nitrogen leads to the formation of a significant amount of amorphous BN, resulting in a decrease in the coating hardness. To optimize the coating performance, this study uses high-power pulse magnetron sputtering, and the deposition temperature is varied to prepare the Ti-B-N coatings. X-ray diffraction (XRD) and scanning electron microscopy (SEM) are used to analyze the microstructure and composition of the Ti-B-N coatings. A microhardness tester, scratch tester, and friction and wear testing machine are used to measure the hardness, film / substrate adhesion strength, and friction and wear properties of the Ti-B-N coatings. The effects of the deposition temperature on the structure, friction, and wear properties of the Ti-B-N coatings, as well as their wear mechanisms, are investigated. The results indicate that, as the deposition temperature increases, the kinetic energy of the sputtered particles is enhanced, as is their diffusion ability, which compacts the already deposited particles, resulting in a smoother and denser coating surface. Boron (B) in the target material is preferentially sputtered onto the substrate surface over titanium (Ti), causing the Ti-B-N coating to have a higher percentage of B than the target material. As the deposition temperature increases from 100 to 200 ℃, the Ti content slightly decreases, and the B content slightly increases. When the deposition temperature reaches > 200 ℃, there is no significant change in the Ti and B content. When the deposition temperature varies from 100 to 300 ℃, h-TiB2 and Ti3B4 phases are detected in the coating; when the coating deposition temperature reaches 400 ℃, only the h-TiB2 phase is detected. As the deposition temperature increases, the surface of the Ti-B-N coating gradually becomes smoother and denser, the hardness of the coating increases from 2 855 to 3 994 HV0.01, and the residual stress decreases from 0.9 to 0.3 GPa. When the deposition temperature is 400 ℃, the coating is the smoothest and densest, with the highest hardness and the least residual stress. When the deposition temperature is 300 ℃, the coating has the lowest friction coefficient and wear rate, which are 0.5 and 1.1×10-3 μm3N-1μm-1, respectively, indicating the best wear resistance. This study indicates that Ti-B-N coatings deposited at 400 °C exhibit higher hardness, stronger adhesion, and lower tensile stress compared to those deposited at 300 ℃. However, the friction rate significantly increases, suggesting that in this case, the primary factors influencing the frictional performance of the coating are not the hardness, adhesion strength, or internal stress. The average friction coefficient of the Ti-B-N coating deposited at 300 ℃ is 0.5, which is significantly lower than the coefficient of 0.8 at 400 °C. This demonstrates that under certain conditions, the friction coefficient is the main determinant of the frictional performance of the Ti-B-N coatings. By optimizing process parameters, such as the deposition temperature, it is possible to control the friction coefficient of the coating, thereby enhancing its overall frictional performance.
  • HUAN Xi, WANG Wei, HU Gege, WANG Jingnan
    China Surface Engineering. 2026, 39(2): 485-491. https://doi.org/10.11933/CSE2026052
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Vacuum coating equipment, a key high-tech device, has become a dominant technology in the surface treatment industry owing to its cost-effectiveness and low environmental impact. It has been widely utilized in new-generation information technology, aerospace technology, and energy. Currently, conventional coating equipment faces limitations because the revolution, autorotation, and inclination of the workpiece cannot be independently controlled or continuously controlled in multiple directions. This has resulted in application bottlenecks for downstream emerging industries, precision, and complex workpieces. To achieve coupling control of multiple degrees of freedom, a bending-arm hybrid-driven variable-angle thin-film sputtering platform was designed. The device integrates the bending arm transmission control component with multiple independent operating revolutions, rotation, and inclination swing drive mechanisms. The synergistic movement of each mechanism realizes coupling control between the different degrees of freedom. During the coating process, the workpiece realized independent linkage and continuous variable-angle automatic control of three degrees of freedom (revolution, autorotation, and inclination swing) within 0-90°. The three movements were independently driven and controlled by three 42 series two-phase stepper motors and 256 subdivision stepper motor drivers to adjust the speed ratio and tilt angle, which can realize rotation and rotation motion control at angles of 0-90°. The overall structure contains a shell, worktop, transmission tower, bending-arm hybrid control mechanism, revolution motion mechanism, self-rotation motion mechanism, and tilt angle swing transmission mechanism. The shell supported and sealed all the internal mechanisms of the device, and the drive assembly provided power for revolution and autorotation. The self-rotation motion mechanism drives the transmission shaft to realize the autorotation of the sample, and the orbital motion mechanism drives the central transmission tower to realize the revolution of the sample. The bending-arm hybrid transmission mechanism was connected to the inclined swing transmission mechanism through the drive shaft and medium-type mechanism. The innovatively designed medium-type hybrid transmission mechanism can stably and synchronously transmit the rotational operation of autorotation and the lifting and lowering motions of the inclination swing to achieve hybrid transmission. In addition, the bottom of the sample plate was designed with a heating plate and a thermal insulation blanket, which was embedded with a plurality of ceramic heating rods and temperature sensors, which can realize the heating and temperature control within 0-700 ℃. Emergency power cutoff and stop protection functions were also designed. When the equipment is in the acceleration or constant-speed operation stage, the electromagnetic clutch is energized to directly transmit the power output of the motor to the drive gear. When the equipment was in a deceleration or emergency shutdown state, the electromagnetic clutch was de-energized, and the motor was disconnected from the drive gear. The overall structure achieves a high degree of automation, structural reliability, and easy maintenance. The device has high technical versatility, which can address issues related to traditional coating equipment, such as the small adjustment range of the tilt angle and the inability to automatically coordinate control. In addition, to meet the sputtering needs of emerging downstream industries, the as-designed hybrid drive platform can further reduce the space size, reduce the overall structural weight, and optimize the spatial layout of the three rotary motion systems, making the hybrid drive system more miniaturized and portable and reducing the production and operation costs. This technology holds substantial potential for multi-directional, continuous sputtering of intricate workpieces in advanced manufacturing.