调制周期对CrAl/CrAlN多层薄膜结构及耐腐蚀性能的影响

吕艳红, 吉利, 刘流, 李红轩, 刘晓红, 陈建敏, 周惠娣

中国表面工程 ›› 2013, Vol. 26 ›› Issue (5) : 18-23.

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中国表面工程 ›› 2013, Vol. 26 ›› Issue (5) : 18-23. DOI: 10.3969/j.issn.1007-9289.2013.05.004
表面工程

调制周期对CrAl/CrAlN多层薄膜结构及耐腐蚀性能的影响

  • 吕艳红, 吉利, 刘流, 李红轩, 刘晓红, 陈建敏, 周惠娣
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Influence of Modulation Periodicities on Structure and Corrosion Properties of CrAl/CrAlN Multilayer Films

  • LV Yanhong, JI Li, LIU Liu, LI Hongxuan, LIU Xiaohong, CHEN Jianmin, ZHOU Huidi
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摘要

采用中频非平衡磁控溅射技术制备CrAl/CrAlN多层薄膜,研究了调制周期对CrAl/CrAlN 多层薄膜的微观结构、机械性能和耐腐蚀性能的影响。研究表明:CrAl/CrAlN多层薄膜具有致密的层状结构。随着调制周期的增大,薄膜应力由拉应力转变为压应力,当调制周期为285.7 nm时,CrAl/CrAlN多层薄膜的硬度出现了极大值。此外,调制周期对薄膜的耐腐蚀性能有显著的影响。经过96 h 盐雾(3.5%NaCl)试验,调制周期为142.8 nm的CrAl/CrAlN多层薄膜依然没有发生腐蚀现象,表明此条件下CrAl/CrAlN薄膜具有优异的耐腐蚀性能。

Abstract

CrAl/CrAlN multilayer films were deposited by midfrequency unbalanced magnetron sputtering. The structure, mechanical features and corrosion resistance as a function of modulation periodicity of the films were also studied. The results show that all of the CrAl/CrAlN multilayer films have denser layered structure. The internal stress of the CrAl/CrAlN multilayer films becomes the compressive stress as the modulation periodicity increases, and the hardness of the films attains a maximum value when the modulation periodicity is 285.7 nm. Moreover,the modulation periodicity has a great effect on the corrosion resistance of the CrAl/CrAlN multilayer films. After 96 h salt spray corrosion test (3.5% NaCl), the CrAl/CrAlN multilayer films at the modulation periodicity of 142.8 nm are not corrosive at all, which show that the films have excellent corrosion resistance.

关键词

磁控溅射; CrAl/CrAlN; 多层薄膜; 微观结构; 耐腐蚀性能

Key words

magnetron sputtering; CrAl/CrAlN; multilayer films; microstructure; corrosion resistance

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吕艳红, 吉利, 刘流, 李红轩, 刘晓红, 陈建敏, 周惠娣. 调制周期对CrAl/CrAlN多层薄膜结构及耐腐蚀性能的影响[J]. 中国表面工程, 2013, 26(5): 18-23 https://doi.org/10.3969/j.issn.1007-9289.2013.05.004
LV Yanhong, JI Li, LIU Liu, LI Hongxuan, LIU Xiaohong, CHEN Jianmin, ZHOU Huidi. Influence of Modulation Periodicities on Structure and Corrosion Properties of CrAl/CrAlN Multilayer Films[J]. China Surface Engineering, 2013, 26(5): 18-23 https://doi.org/10.3969/j.issn.1007-9289.2013.05.004
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