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喷射电沉积技术制备Co-Cr3C2复合镀层的工艺优化
王猛1, 谭俊1,2, 吴迪1, 兰龙3
1.装甲兵工程学院再制造技术重点实验室, 北京 100072;2.装甲兵工程学院表面工程重点实验室, 北京 100072;3.中国西安卫星测控中心三亚航天测控站, 海南 三亚 572427
摘要:
为提高微米级硬质陶瓷颗粒在金属基复合镀层的含量,制备性能优异的防护性镀层,采用喷射电沉积的方法在直流电压下制备了Co-Cr3C2复合镀层,利用控制变量法探讨了电流密度、固体颗粒用量、镀液流量以及喷枪移动速度等对镀层中颗粒含量及镀层性能的影响,并分析了各因素的影响机理。同时,分别采用能谱仪、显微硬度计和摩擦磨损试验机对复合镀层的成分、硬度和摩擦因数进行分析,最终确定了制备该复合镀层的较优工艺参数。结果显示:喷头移动速度对颗粒复合量的影响最为显著;颗粒复合量越大,复合镀层硬度越高、摩擦因数越低;在较优工艺参数下制备的Co-Cr3C2复合镀层的Cr3C2颗粒含量高达23.6%。
关键词:  喷射电沉积  钴基镀层  碳化铬  复合镀层
DOI:10.11933/j.issn.1007-9289.2016.04.010
分类号:
基金项目:装备预研基金(9140C850202100C85)
Process Optimization of Preparing Co-Cr3C2 Composite Coatings by Jet-electrodeposition
WANG Meng1, TAN Jun1,2, WU Di1, LAN Long3
1.Science and Technology on Remanufacturing Laboratory, Academy of Armored Forces Engineering, Beijing 100072;2.Key Laboratory for Surface Engineering, Academy of Armored Forces Engineering, Beijing 100072;3.Sanya Space Observation, China Xi'an Satellite Control Center, Sanya 572427, Hainan
Abstract:
In order to improve the content of micro-sized ceramic particles in metal matrix composite coating, and to enhance the performance of protective coatings, the Co-Cr3C2 composite coatings were prepared by jet-electrodeposition using DC voltage. The influences of the current density, the concentration of particles in solution, the flow of solutions and spray gun speed on the particle content as well as coating properties were investigated, respectively. The mechanism of the influence of various factors was also discussed. The composition, hardness and friction coefficient of composite coatings were analyzed by EDS, a microhardness tester and a friction and wear testing machine. Then the optimal parameters for preparing the composite coating was determined. The results show that the gun movement speed is the most significant influence on the mass fraction of Cr3C2 in the coating. Moreover, the hardness is higher and the friction coefficient is lower with higher content of particles in composite coating. The content of Cr3C2 particles reaches 23.6% in composite coating which is obtained with the optimal parameters.
Key words:  jet-electrodeposition  Co-based coatings  chromium carbide  composite coating