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沉积时间对钼薄膜结构和热疲劳性能的影响
朱晓岗, 王波, 张丽霞, 于敦波, 杨远飞1,2,3
1. 北京工业大学 薄膜材料与技术研究室, 北京 100124;2. 航天科工防御技术研究试验中心 三室, 北京 100854;3. 北京有色金属研究总院 稀土材料国家工程研究中心, 北京100088
摘要:
研究了等离子喷枪采用3个送粉位置时距离喷嘴90 mm处YSZ粒子的熔化状态(包括粒子温度及速度、粒子粒度分布、粒子撞击基体后的扁平形貌),其中送粉位置1和2为枪外送粉,送粉孔轴线距离喷嘴端面分别为9 mm和3.5 mm,送粉位置3为枪内送粉,送粉孔轴线距离喷嘴端面5 mm。结果表明,送粉位置沿等离子射流逆流方向移动时(分别对应送粉位置1、2和3),粒子熔化效果明显增强,粒子扁平化程度提高;涂层中未熔颗粒和孔隙百分比由33.25%减小至10.13%,涂层结合强度由16.25 MPa增加至37.25 MPa,涂层表面剥落20%时经历的热震次数由35次增加至130次;采用送粉位置3时,喷涂功率33.60 kW,低于其他送粉位置的电弧功率(46.75 kW),实现了低功率制备高性能YSZ涂层。
关键词:  等离子喷涂  送粉位置  氧化钇稳定氧化锆(YSZ)  熔化状态
DOI:10.3969/j.issn.1007-9289.2014.03.002
分类号:
基金项目:
Influence of Deposition Time on Structure and Thermal Fatigue Property of Molybdenum Film
ZHU Xiaogang, WANG Bo, ZHANG Lixia, YU Dunbo, YANG Yuanfei1,2,3
1. Thin Films Materials and Technology Laboratory, Beijing University of Technology, Beijing 100124;2. The Third Laboratory, Research and Test Center, Hangtiankegong Corporation, Beijing 100854;3. Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals, Beijing 100088
Abstract:
This paper analyzed different melting states of yttriastabilized(YSZ) zirconia particles sprayed at 3 different powder injection positions. Powder injecting position 1 and 2 were located outside the nozzle. However, position 3 was located inside the nozzle. Particles states including particles average temperature, fly velocity, size distribution and splats patterns were measured at the distance of 90 mm from the nozzle exit. The results show that when the powder injection position removed along the downstream of a plasma jet (from position 1 to position 3), the particle heating effect was enhanced. The particle flattening degree increased and deposited coating became denser with fewer amounts of unmelted particles and pores. The average adhesion strength of YSZ coatings increased from 16.25 MPa to 37.25 MPa. Bend performance and thermal shock resistance of the coatings also increased. At powder injection position 3, high performance coatings were obtained with less power consumption of 33.60 kW in comparison with other positions of 46.75 kW.
Key words:  plasma spraying  powder injection position  yttriastabilized zirconia(YSZ)  melting condition