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钛合金及其表面沉积Ti/TiN/Zr/ZrN多层膜的冲蚀行为
蓝恩辉,代明江,胡芳,林松盛,侯惠君1,2
1. 广东工业大学 材料与能源学院, 广州 510006;2. 广州有色金属研究院 新材料研究所, 广州 510651
摘要:
采用多弧离子镀技术在TC11钛合金表面制备了厚度为18.7 μm 的Ti/TiN/Zr/ZrN多层膜,用45 μm白刚玉通过微喷砂试验机评价TC11钛合金及Ti/TiN/Zr/ZrN多层膜在30°和90°攻角下的抗冲蚀性能,并分析其冲蚀机理。结果表明:30°攻角下, 冲蚀砂量为70 g时,Ti/TiN/Zr/ZrN多层膜被冲破,此时该多层膜的冲蚀坑深度为21.88 μm,TC11钛合金基材为269.9 μm。90°攻角下,冲蚀砂量为20 g时,Ti/TiN/Zr/ZrN多层膜被冲破,此时该多层膜的冲蚀坑深度为8.95 μm,TC11钛合金基材为46.96 μm。30°攻角下,钛合金的冲蚀以微切削为主,多层膜以微切削和微断裂为主。在90°攻角下,钛合金的冲蚀以点坑冲蚀为主,多层膜以裂纹萌生扩展和点坑冲蚀的混合冲蚀为主。
关键词:  TC11钛合金  Ti/TiN/Zr/ZrN多层膜  冲蚀机理
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Erosion Behaviors of Titanium Alloy and Ti/TiN/Zr/ZrN Multilayer Coatings Deposited on Titanium Alloy
LAN En–hui, DAI Ming–jiang, HU Fang, LIN Song–sheng, HOU Hui–jun1,2
1. Faculty of Materials and Energy, Guangdong University of Technology, Guangzhou 510081;2. Institute of Surface Engineering, Guangzhou Research Institute of Nonferrous Metals, Guangzhou 510651
Abstract:
Ti/TiN/Zr/ZrN coating with a thickness of 18.7 μm was deposited on TC11 substrate by multiarc ion plating. Erosion resistance of titanium alloy and Ti/TiN/Zr/ZrN coating was evaluated using white alundum abrasive of 45 μm by microblasting equipment at the impact angle of 30° and 90°, and the erosion mechanism was also analysed.The results show that the multilayer coatings are broken when the erosion sand weight is 70 g at the impact angle of 30°, and the erosion depth of the coating is 21.88 μm while titanium alloy is 269.9 μm. The multilayer coatings are broken when the erosion sand weight is 20 g at the impact angle of 90°, and the erosion depth of the coatings is 8.95 μm while titanium alloy is 46.96 μm.The erosion mechanism of titanium alloy is microcutting at the impact angle of 30°and pitting at the impact angle of 90°, while multilayer coatings is microcutting and microcracks at the impact angle of 30°and microcrack fracture at the impact angle of 90°.
Key words:  TC11 titanium alloy  Ti/TiN/Zr/ZrN multilayer coatings  erosion mechanism