引用本文:周志祥,肖旭贤,孙超远,汪伟,王玉江,魏世丞.改性聚苯胺在防腐涂层中的研究进展*[J].中国表面工程,2022,35(1):86~96
ZHOU Zhixiang,XIAO Xuxian,SUN Chaoyuan,WANG Wei,WANG Yujiang,WEI Shicheng.Research Progress of Modified Polyaniline in Anticorrosive Coatings[J].China Surface Engineering,2022,35(1):86~96
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改性聚苯胺在防腐涂层中的研究进展*
周志祥1, 肖旭贤1, 孙超远1, 汪伟1, 王玉江2, 魏世丞2
1.中南大学化学化工学院 长沙 410083;2.陆军装甲兵学院装备再制造技术国防科技重点实验室 北京 100072
摘要:
聚苯胺因其可逆的氧化还原特性在金属腐蚀与防护领域具有广阔的应用前景，目前有关改性聚苯胺对涂层附着力、阻隔性能以及钝化机理的研究比较零散，缺乏系统总结。通过对单一聚苯胺分散性差、疏水性弱等缺陷的分析，报道近年来改性聚苯胺在防腐涂料领域中的研究思路和研究进展，比较不同条件下改性策略的优劣，归纳聚苯胺结构与涂层耐腐蚀性之间存在的联系。进一步论证柔性、疏水基团取代聚苯胺有利于提升涂层抗渗性，改变掺杂剂以及与纳米氧化物、石墨烯等原位聚合制备复合填料也是提升涂层防腐性能的有效途径。展望该行业未来研究和发展的趋势，可为今后聚苯胺的改性工作提供理论指导。
关键词:  聚苯胺衍生物  复合材料  石墨烯  防腐涂层  研究进展
DOI：10.11933/j.issn.1007-9289.20210811004
分类号:TG156;TB114
基金项目:国家重点研发计划(2019YFC1908100)；中南大学中央高校基础研究基金(1053320212627)资助项目
Research Progress of Modified Polyaniline in Anticorrosive Coatings
ZHOU Zhixiang1, XIAO Xuxian1, SUN Chaoyuan1, WANG Wei1, WANG Yujiang2, WEI Shicheng2
1.College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 , China;2.National Defense Key Laboratory for Equipment Remanufacturing, Academy of Armored Force Engineering,Beijing 100072 , China
Abstract:
Polyaniline has promising prospects in the field of metal corrosion protection due to its reversible redox properties. Investigation on the adhesion, barrier properties and passivation mechanism of modified polyaniline composite coatings is relatively scattered, which needs to be summarized logically. Through the analysis of defects such as poor dispersion and weak hydrophobicity of ordinary polyaniline, this paper reports the research ideas and advances of anticorrosive coatings incorporated polyaniline and its derivative in recent years. The merits of modification strategies under different condition are compared and the relevance between the structure of polyaniline and the corrosion resistance is concluded, further demonstrating that flexible or hydrophobic substituents are conducive to the impermeability of organic coatings. There is also other polyaniline modification approach from the aspects of altering dopant and in-situ polymerization with nano-oxides or graphene for improving anticorrosion performance. The future development trends of the industry are prospected, providing theoretical guidance for the future study.
Key words:  polyaniline derivatives  composite materials  graphene  anticorrosive coating  research progress
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