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强脉冲离子束辐照GH202镍基高温合金表面改性
钟昊玟1, 梁家昌2, 赵小勇3, 张世贵3, 乐小云1
1.北京航空航天大学 物理科学与核能工程学院, 北京 100191;2.中国民航大学 理学院, 天津 300300;3.四川成发航空科技股份有限公司, 成都 610000
摘要:
为改善GH202镍基高温合金的表面性能,使用成分为Cn+和H+、加速电压为250 kV的强脉冲离子束(IPIBs)对其进行表面辐照处理。采用光学显微镜、X射线衍射仪、扫描电子显微镜和显微硬度计等分别对不同参数辐照后的试样的表面形貌及性能进行测试。结果表明:辐照后GH202合金表面产生了熔坑,熔坑的尺寸随能量密度的增加而增加,最大可至70 μm。熔坑的产生源于表层低熔点组分的喷发。表层的γ'相消失,辐照之后的试样表层产生了M23C6结构的碳化物并在辐照过程中受到压应力作用。辐照后试样表层近百微米深度内显微硬度均获得不同程度的提高。在高温氧化时,辐照后的样品表面更易于形成Cr2O3和Al2O3连续膜层氧化物,阻碍O元素向基体扩散,使得抗高温氧化性能得到改善。
关键词:  强脉冲离子束  镍基高温合金  熔坑  显微硬度  抗高温氧化性能
DOI:10.11933/j.issn.1007-9289.20170804001
分类号:
基金项目:国家自然科学基金(11175012);国家重大科技专项(2013ZX04001071-004)
Surface Modification of GH202 Nickel Based Superalloy by Intense Pulsed Ion Beam Irradiation
ZHONG Hao-wen1, LIANG Jia-chang2, ZHAO Xiao-yong3, ZHANG Shi-gui3, LE Xiao-yun1
1.School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191;2.School of Science, Civil Aviation University of China, Tianjin 300300;3.Sichuan Chengfa Aero Science & Technology Co., Ltd., Chengdu 610000
Abstract:
In order to improve the surface properties of GH202 nickel based superalloy, intense pulsed ion beams (IPIBs), composited by Cn+ and H+, accelerated by 250 kV voltage, were used to irradiate the alloy. The surface morphology and properties of the alloys were detected by optical microscopy, XRD, SEM and microhardness tester. The results show that the craters appear on the sample surface after IPIBs irradiation. The size of craters increases with the improvement of the energy density, up to 70 μm. The formation of craters is due to the eruption of low melt point components. The γ' phase on the surface layer is disappeared, the carbide with M23C6 structure formed and the residual stress existed. In depth of about 100 μm, the microhardness after irradiation increases in varying degrees. In the high temperature oxidation testing, the continuous oxidation layer consisting of Cr2O3 and Al2O3 is easier to be formed, which can prevent the diffusion of oxygen into the substrate. There-fore, high temperature oxidation resistance of the treated alloy has been improved.
Key words:  intense pulsed ion beams(IPIBs)  nickel based superalloy  craters  microhardness  high temperature oxidation resistance