引用本文:杨大祥,肖平,赵晓峰,宋永才.静电纺丝制备连续SiC亚微米/纳米纤维[J].中国表面工程,2010,(1):39~44
YANG Da−xiang, (UK) XIAO Ping, ZHAO Xiao−feng, SONG Yong−cai.Processing Continuous Submicro/Nano SiC Fibers by Electrospinning[J].China Surface Engineering,2010,(1):39~44
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静电纺丝制备连续SiC亚微米/纳米纤维
杨大祥,肖平,赵晓峰,宋永才1,2,3
1. 装甲兵工程学院 装备再制造技术国防科技重点实验室,北京,100072;2. 曼彻斯特大学 材料学院 材料工程中心,英国曼彻斯特,M1 7HS;3. 国防科技大学 新型陶瓷纤维及其复合材料国防防科技重点实验室,长沙,410073
摘要:
高性能SiC纤维在耐高温、抗氧化领域有着重要的应用前景,而纤维直径是影响纤维力学性能的主要因素之一。随着纤维直径降低,纤维强度显著升高。利用静电纺丝工艺,结合先驱体热解转化法制备SiC,探索了一种简单、易行的制备亚微米/纳米SiC纤维的方法。由聚碳硅烷(PCS)出发,研究了PCS溶液静电纺丝的工艺参数对纺丝性的影响,PCS原纤维经不熔化、N2中1200℃热处理1h,成功的制备了纤维直径在0.5~2mm之间分布均匀的SiC纤维。
关键词:  聚碳硅烷  静电纺丝  碳化硅纤维  纳米纤维
DOI:
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Processing Continuous Submicro/Nano SiC Fibers by Electrospinning
YANG Da−xiang, (UK) XIAO Ping, ZHAO Xiao−feng, SONG Yong−cai1,2,3
1. National Laboratory for Remanufacturing, The Academy of Armored Forces Engineering, Beijing 100072;2. Manchester Materials Science Center, University of Manchester, Grosvenor Street, Manchester M1 7HS, UK;3. Key Laboratory of Advanced Ceramic Fibers and Composite, National University of Defense Technology, Changsha 410073
Abstract:
High performace SiC fibers have many promoting applications in the high temperature and oxidation resistance environment and the diameter of fiber is one of the main influence factors on the mechanical properties, especially, the tensile strength increases evidently with the diameter decreases. Combining with the polymer?derived ceramic method, an easy and feasible method has been developed to produce the sub?micro/nano SiC fibers by electrospinning. Started from polycarbosilicon (PCS), the main parameters which affected the electrospinning spinnability were studied and the sub?micro/nano SiC fibers with the diameter of 0.5~2 μm were produced successfully after curing and heat treatment of PCS green fibers in N2 at 1200 ℃ for 1h.
Key words:  polycarbosilane(PCS)  electrospinning  silicon carbide fiber  nano fiber
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